Article(id=1322560009439920516, tenantId=1146029695717560320, journalId=1225396423026438145, issueId=1322559951067792299, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1745596800000, receivedDateStr=2025-04-26, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1793252478226, onlineDateStr=2026-10-29, pubDate=1777046400000, pubDateStr=2026-04-25, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793252478226, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793252478226, creator=13701087609, updateTime=1793252478226, updator=13701087609, issue=Issue{id=1322559951067792299, tenantId=1146029695717560320, journalId=1225396423026438145, year='2026', volume='46', issue='4', pageStart='1', pageEnd='294', issueExtLink='null', onlineDate='null', pubDate='1777046400000', pubDateStr='2026-04-25', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793252464310, creator='13701087609', updateTime=1793252763065, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322561204200001631, tenantId=1146029695717560320, journalId=1225396423026438145, issueId=1322559951067792299, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322561204200001632, tenantId=1146029695717560320, journalId=1225396423026438145, issueId=1322559951067792299, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=178, endPage=187, ext={EN=ArticleExt(id=1322560009620275589, articleId=1322560009439920516, tenantId=1146029695717560320, journalId=1225396423026438145, language=EN, title=Study on the Effects of Different Erosion Environments on the Durability of Modified Grouting Materials, columnId=null, journalTitle=Mining Research and Development, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Grouting materials have significant applications in mining engineering, but their poor durability in deep and highly erosive environments severely restricts the long-term safe operation of mines. Modified grouting materials were prepared by replacing a portion of the cement with rice husk ash and slag. Using compressive strength, the strength erosion coefficient, and the mass loss rate as evaluation criteria, quantified assessments were conducted to evaluate the impact of different erosion environments on the durability of modified grouting materials in karst regions. Combining scanning electron microscopy and X-ray diffraction analysis, it revealed the erosion-resistant mechanism of the modified grouting material at the microscopic level. The results show that the rice husk ash-slag-cement grouting material exhibited the highest resistance to chloride-sulfate erosion, carbonate erosion and water leaching corrosion, with strength loss rates of 13.61%, 14.42%, and 4.79%, respectively, and mass loss rates of 3.30%, 2.38%, and 1.95%, respectively. It is more resistant to environmental erosion than pure cement grouting materials. At the microscopic level, it is observed that rice husk ash and slag form dense hydration products through hydration reactions, which can inhibit the degradation of the original hydration products caused by various corrosive environments. At the same time, the amorphous SiO2 in rice husk ash reacts with Ca(OH)2 through a pozzolanic reaction, and the secondary hydration of the slag generates more C-S-H gel, significantly enhancing the erosion resistance of the modified grouting material to chloride-sulfate, carbonate and water. The cost of grouting materials made from rice husk ash-slag-cement is 21% lower than that of pure cement, and they can extend the maintenance cycle of the project by approximately 51.41%.

, authors=Qing HAN1, Xiaoyong HAN2, Pengcheng ZHOU3, 4, authorsList=Qing HAN, Xiaoyong HAN, Pengcheng ZHOU, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322560009964208518, articleId=1322560009439920516, tenantId=1146029695717560320, journalId=1225396423026438145, language=CN, title=不同侵蚀环境对改性注浆材料耐久性的影响研究, columnId=1226462295417598973, journalTitle=矿业研究与开发, columnName=矿山安全与环保, runingTitle=null, highlight=null, articleAbstract=

注浆材料在矿业工程中具有重要应用,但其在深部高侵蚀性环境下的耐久性不足严重制约矿山长效安全运营。采用稻壳灰和矿渣替代部分水泥制备改性注浆材料,以抗压强度、强度侵蚀系数和质量损失率为评价指标,定量评估了不同侵蚀环境对岩溶区改性注浆材料耐久性的影响,并结合扫描电镜与X射线衍射测试,从微观尺度揭示了改性注浆材料的抗侵蚀作用机理。结果表明:稻壳灰-矿渣-水泥注浆材料的抗氯盐-硫酸盐侵蚀性能、抗碳酸盐侵蚀性能和抗水溶蚀性能最高,强度损失率分别为13.61%、14.42%和4.79%,质量损失率分别为3.30%、2.38%和1.95%,比纯水泥注浆材料更能抵抗各种环境的侵蚀;从微观角度发现稻壳灰和矿渣通过水化反应生成了致密水化产物,可抑制各种侵蚀环境对原有水化产物的破坏;同时,稻壳灰中无定形SiO2与Ca(OH)2发生火山灰反应,矿渣二次水化生成更多的C-S-H凝胶,显著提升了改性注浆材料对氯盐-硫酸盐、碳酸盐及水的抗侵蚀能力;稻壳灰-矿渣-水泥注浆材料成本较纯水泥降低21%,可延长工程维护周期约51.41%。

, authors=韩庆1, 韩晓勇2, 周鹏成3, 4, authorsList=韩庆, 韩晓勇, 周鹏成, authorCompany=null, correspAuthors=null, authorNote=

韩庆(1982—),男,河南商丘人,硕士,副教授,主要从事建筑材料力学性能研究。E-mail:

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韩庆(1982—),男,河南商丘人,硕士,副教授,主要从事建筑材料力学性能研究。E-mail:

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韩庆(1982—),男,河南商丘人,硕士,副教授,主要从事建筑材料力学性能研究。E-mail:

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不同侵蚀环境对改性注浆材料耐久性的影响研究
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韩庆 1 , 韩晓勇 2 , 周鹏成 3, 4
矿业研究与开发 | 矿山安全与环保 2026,46(4): 178-187
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矿业研究与开发 |矿山安全与环保 2026 , 46 (4) : 178 -187
不同侵蚀环境对改性注浆材料耐久性的影响研究
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韩庆1 , 韩晓勇2, 周鹏成3, 4
作者信息
  • 1.商丘职业技术学院,河南 商丘市 476100
  • 2.河南大学 濮阳工学院,河南 濮阳市 457000
  • 3.同济大学 土木工程学院,上海 200092
  • 4.中交第一公路勘察设计研究院有限公司,陕西 西安 710075
作者简介:

韩庆(1982—),男,河南商丘人,硕士,副教授,主要从事建筑材料力学性能研究。E-mail:

Study on the Effects of Different Erosion Environments on the Durability of Modified Grouting Materials
Qing HAN1 , Xiaoyong HAN2, Pengcheng ZHOU3, 4
Affiliations
  • 1.Shangqiu Polytechnic, Shangqiu, Henan 476100, China
  • 2.Puyang Institute of Technology, Henan University, Puyang, Henan 457000, China
  • 3.College of Civil Engineering, Tongji University, Shanghai 200092, China
  • 4.CCCC First Highway Consultants Co., Ltd., Xi'an, Shaanxi 710075, China
出版时间: 2026-04-25
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注浆材料在矿业工程中具有重要应用,但其在深部高侵蚀性环境下的耐久性不足严重制约矿山长效安全运营。采用稻壳灰和矿渣替代部分水泥制备改性注浆材料,以抗压强度、强度侵蚀系数和质量损失率为评价指标,定量评估了不同侵蚀环境对岩溶区改性注浆材料耐久性的影响,并结合扫描电镜与X射线衍射测试,从微观尺度揭示了改性注浆材料的抗侵蚀作用机理。结果表明:稻壳灰-矿渣-水泥注浆材料的抗氯盐-硫酸盐侵蚀性能、抗碳酸盐侵蚀性能和抗水溶蚀性能最高,强度损失率分别为13.61%、14.42%和4.79%,质量损失率分别为3.30%、2.38%和1.95%,比纯水泥注浆材料更能抵抗各种环境的侵蚀;从微观角度发现稻壳灰和矿渣通过水化反应生成了致密水化产物,可抑制各种侵蚀环境对原有水化产物的破坏;同时,稻壳灰中无定形SiO2与Ca(OH)2发生火山灰反应,矿渣二次水化生成更多的C-S-H凝胶,显著提升了改性注浆材料对氯盐-硫酸盐、碳酸盐及水的抗侵蚀能力;稻壳灰-矿渣-水泥注浆材料成本较纯水泥降低21%,可延长工程维护周期约51.41%。

改性注浆材料  /  侵蚀环境  /  耐久性  /  抗侵蚀机理

Grouting materials have significant applications in mining engineering, but their poor durability in deep and highly erosive environments severely restricts the long-term safe operation of mines. Modified grouting materials were prepared by replacing a portion of the cement with rice husk ash and slag. Using compressive strength, the strength erosion coefficient, and the mass loss rate as evaluation criteria, quantified assessments were conducted to evaluate the impact of different erosion environments on the durability of modified grouting materials in karst regions. Combining scanning electron microscopy and X-ray diffraction analysis, it revealed the erosion-resistant mechanism of the modified grouting material at the microscopic level. The results show that the rice husk ash-slag-cement grouting material exhibited the highest resistance to chloride-sulfate erosion, carbonate erosion and water leaching corrosion, with strength loss rates of 13.61%, 14.42%, and 4.79%, respectively, and mass loss rates of 3.30%, 2.38%, and 1.95%, respectively. It is more resistant to environmental erosion than pure cement grouting materials. At the microscopic level, it is observed that rice husk ash and slag form dense hydration products through hydration reactions, which can inhibit the degradation of the original hydration products caused by various corrosive environments. At the same time, the amorphous SiO2 in rice husk ash reacts with Ca(OH)2 through a pozzolanic reaction, and the secondary hydration of the slag generates more C-S-H gel, significantly enhancing the erosion resistance of the modified grouting material to chloride-sulfate, carbonate and water. The cost of grouting materials made from rice husk ash-slag-cement is 21% lower than that of pure cement, and they can extend the maintenance cycle of the project by approximately 51.41%.

Modified grouting material  /  Erosion environment  /  Durability  /  Mechanism of erosion resistance
韩庆, 韩晓勇, 周鹏成. 不同侵蚀环境对改性注浆材料耐久性的影响研究. 矿业研究与开发, 2026 , 46 (4) : 178 -187 .
Qing HAN, Xiaoyong HAN, Pengcheng ZHOU. Study on the Effects of Different Erosion Environments on the Durability of Modified Grouting Materials[J]. Mining Research and Development, 2026 , 46 (4) : 178 -187 .
  • 国家自然科学基金项目(52208197)
  • 商丘市社科规划课题(SKG2014092)
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  • 接收时间:2025-04-26
  • 首发时间:2026-10-29
  • 出版时间:2026-04-25
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  • 收稿日期:2025-04-26
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国家自然科学基金项目(52208197)
商丘市社科规划课题(SKG2014092)
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    1.商丘职业技术学院,河南 商丘市 476100
    2.河南大学 濮阳工学院,河南 濮阳市 457000
    3.同济大学 土木工程学院,上海 200092
    4.中交第一公路勘察设计研究院有限公司,陕西 西安 710075
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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