Article(id=1322559917228147341, tenantId=1146029695717560320, journalId=1225396423026438145, issueId=1322559901990240737, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1745683200000, receivedDateStr=2025-04-27, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1793252456242, onlineDateStr=2026-10-29, pubDate=1774368000000, pubDateStr=2026-03-25, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793252456242, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793252456242, creator=13701087609, updateTime=1793252456242, updator=13701087609, issue=Issue{id=1322559901990240737, tenantId=1146029695717560320, journalId=1225396423026438145, year='2026', volume='46', issue='3', pageStart='1', pageEnd='330', issueExtLink='null', onlineDate='null', pubDate='1774368000000', pubDateStr='2026-03-25', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793252452609, creator='13701087609', updateTime=1793252731500, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322561071810991099, tenantId=1146029695717560320, journalId=1225396423026438145, issueId=1322559901990240737, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322561071810991100, tenantId=1146029695717560320, journalId=1225396423026438145, issueId=1322559901990240737, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=191, endPage=197, ext={EN=ArticleExt(id=1322559918880703118, articleId=1322559917228147341, tenantId=1146029695717560320, journalId=1225396423026438145, language=EN, title=Experimental Study on the Oxidation and Combustion Characteristics of Gas-Coal Under Pre-Oxidation and Water Immersion Conditions, columnId=null, journalTitle=Mining Research and Development, columnName=null, runingTitle=null, highlight=null, articleAbstract=

To investigate the combined effects of pre-oxidation and water immersion on the characteristics of coal oxidation combustion, a thermogravimetric analysis was performed on gas-coal samples subjected to various pre-oxidation temperatures and water immersion conditions. The characteristic temperature, activation energy and reaction rate of coal oxidation combustion under different conditions were analyzed, and the mechanism of the effects of pre-oxidation and water immersion on coal oxidation combustion was discussed. The results indicate that, compared to unoxidized raw coal, the characteristic temperatures of the combustion weight loss stage decreased by 2.8% and 0.2% at 150 ℃ and 240 ℃ pre-oxidation temperatures, respectively, while the activation energies decreased by 4.9% and 48.7%, respectively. Pre-oxidation increased the risk of coal spontaneous combustion, with higher pre-oxidation temperatures leading to a greater propensity for reignition. Furthermore, compared to pre-oxidized coal at 240 ℃, additional water immersion of this high-temperature pre-oxidized coal significantly lowered its oxidative combustion characteristic temperature and activation energy. The characteristic temperatures for the oxidation weight gain stage and combustion weight loss stage decreased by 65.2 ℃ and 16.3 ℃, respectively. The activation energy of the combustion mass loss stage decreases by 7.8 kJ·mol-1, indicating an increased risk of coal spontaneous combustion. The combustion reaction rate of coal decreases after water immersion. The value of pre-exponential factor(lnA) for raw coal after water immersion is reduced by 6.3% compared with raw coal, while for coal samples pre-oxidized at 240 ℃ and then treated with water immersion, lnA is decreased by 60.4%. When coal bodies undergo high-temperature oxidation, direct water injection for cooling is not recommended. Instead, other fire prevention and suppression measures such as injecting low-temperature nitrogen or liquid carbon dioxide should be prioritized.

, authors=Jianfeng HAO1, Zunguo ZHANG2, Yuezhen CHEN1, Chao TANG2, Linlin DING1, Qingxia QIAN2, Xiaolong ZHAO1, authorsList=Jianfeng HAO, Zunguo ZHANG, Yuezhen CHEN, Chao TANG, Linlin DING, Qingxia QIAN, Xiaolong ZHAO, authorCompany=null, correspAuthors=Zunguo ZHANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322559919098806927, articleId=1322559917228147341, tenantId=1146029695717560320, journalId=1225396423026438145, language=CN, title=预氧化与浸水作用下气煤氧化燃烧特征试验研究, columnId=1226462295417598973, journalTitle=矿业研究与开发, columnName=矿山安全与环保, runingTitle=null, highlight=null, articleAbstract=

为探究预氧化和浸水综合作用对煤氧化燃烧特征的影响,采用气煤开展不同预氧化温度和浸水条件下的热重分析试验,分析了不同预氧化温度和浸水条件下煤的氧化燃烧特征温度、活化能和反应速率,探讨了预氧化和浸水条件对煤氧化燃烧的作用机理。结果表明:与未氧化原煤相比,150 ℃和240 ℃预氧化作用下煤的燃烧失重阶段特征温度分别降低了2.8%、0.2%,活化能分别降低了4.9%、48.7%,预氧化增大了煤的自燃危险性,且温度越高越易复燃;与240 ℃预氧化煤相比,240 ℃高温预氧化煤再浸水会显著降低煤的氧化燃烧特征温度和活化能,氧化增重阶段和燃烧失重阶段的特征温度分别降低了65.2 ℃、16.3 ℃,燃烧失重阶段活化能降低了7.8 kJ/mol,煤自燃危险性增大。浸水处理后煤的燃烧反应速率会降低,原煤浸水煤样较原煤在燃烧阶段的指前因子(lnA)减小了6.3%,240 ℃预氧化再浸水处理煤样的lnA则降低了60.4%。当煤体发生高温氧化时,不宜直接进行注水降温,应优先采用注低温氮气、液态二氧化碳等其他防灭火措施。

, authors=郝建峰1, 张遵国2, 陈岳振1, 唐朝2, 丁林林1, 钱清侠2, 赵小龙1, authorsList=郝建峰, 张遵国, 陈岳振, 唐朝, 丁林林, 钱清侠, 赵小龙, authorCompany=null, correspAuthors=张遵国, authorNote=

郝建峰(1971—),男,山西大同人,高级工程师,主要从事矿井“一通三防”方面的技术管理和研究工作。E-mail:

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张遵国(1986—),男,重庆大足人,博士,副教授,主要从事矿井灾害防治及CO2地质封存方面的研究。E-mail:
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郝建峰(1971—),男,山西大同人,高级工程师,主要从事矿井“一通三防”方面的技术管理和研究工作。E-mail:

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郝建峰(1971—),男,山西大同人,高级工程师,主要从事矿井“一通三防”方面的技术管理和研究工作。E-mail:

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预氧化与浸水作用下气煤氧化燃烧特征试验研究
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郝建峰 1 , 张遵国 2 , 陈岳振 1 , 唐朝 2 , 丁林林 1 , 钱清侠 2 , 赵小龙 1
矿业研究与开发 | 矿山安全与环保 2026,46(3): 191-197
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矿业研究与开发 |矿山安全与环保 2026 , 46 (3) : 191 -197
预氧化与浸水作用下气煤氧化燃烧特征试验研究
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郝建峰(1971—),男,山西大同人,高级工程师,主要从事矿井“一通三防”方面的技术管理和研究工作。E-mail:

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郝建峰1 , 张遵国2 , 陈岳振1, 唐朝2, 丁林林1, 钱清侠2, 赵小龙1
作者信息
  • 1.同煤大唐塔山煤矿有限公司,山西 大同市 034400
  • 2.辽宁工程技术大学 安全科学与工程学院,辽宁 葫芦岛市 125105
通讯作者:
张遵国(1986—),男,重庆大足人,博士,副教授,主要从事矿井灾害防治及CO2地质封存方面的研究。E-mail:
作者简介:

郝建峰(1971—),男,山西大同人,高级工程师,主要从事矿井“一通三防”方面的技术管理和研究工作。E-mail:

Experimental Study on the Oxidation and Combustion Characteristics of Gas-Coal Under Pre-Oxidation and Water Immersion Conditions
Jianfeng HAO1 , Zunguo ZHANG2 , Yuezhen CHEN1, Chao TANG2, Linlin DING1, Qingxia QIAN2, Xiaolong ZHAO1
Affiliations
  • 1.Tongmei Datang Tashan Coal Mine Co., Ltd., Datong, Shanxi 034400, China
  • 2.College of Safety Science and Engineering, Liaoning Technical University, Huludao, Liaoning 125105, China
出版时间: 2026-03-25
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为探究预氧化和浸水综合作用对煤氧化燃烧特征的影响,采用气煤开展不同预氧化温度和浸水条件下的热重分析试验,分析了不同预氧化温度和浸水条件下煤的氧化燃烧特征温度、活化能和反应速率,探讨了预氧化和浸水条件对煤氧化燃烧的作用机理。结果表明:与未氧化原煤相比,150 ℃和240 ℃预氧化作用下煤的燃烧失重阶段特征温度分别降低了2.8%、0.2%,活化能分别降低了4.9%、48.7%,预氧化增大了煤的自燃危险性,且温度越高越易复燃;与240 ℃预氧化煤相比,240 ℃高温预氧化煤再浸水会显著降低煤的氧化燃烧特征温度和活化能,氧化增重阶段和燃烧失重阶段的特征温度分别降低了65.2 ℃、16.3 ℃,燃烧失重阶段活化能降低了7.8 kJ/mol,煤自燃危险性增大。浸水处理后煤的燃烧反应速率会降低,原煤浸水煤样较原煤在燃烧阶段的指前因子(lnA)减小了6.3%,240 ℃预氧化再浸水处理煤样的lnA则降低了60.4%。当煤体发生高温氧化时,不宜直接进行注水降温,应优先采用注低温氮气、液态二氧化碳等其他防灭火措施。

预氧化煤  /  浸水作用  /  热重分析  /  特征温度  /  活化能

To investigate the combined effects of pre-oxidation and water immersion on the characteristics of coal oxidation combustion, a thermogravimetric analysis was performed on gas-coal samples subjected to various pre-oxidation temperatures and water immersion conditions. The characteristic temperature, activation energy and reaction rate of coal oxidation combustion under different conditions were analyzed, and the mechanism of the effects of pre-oxidation and water immersion on coal oxidation combustion was discussed. The results indicate that, compared to unoxidized raw coal, the characteristic temperatures of the combustion weight loss stage decreased by 2.8% and 0.2% at 150 ℃ and 240 ℃ pre-oxidation temperatures, respectively, while the activation energies decreased by 4.9% and 48.7%, respectively. Pre-oxidation increased the risk of coal spontaneous combustion, with higher pre-oxidation temperatures leading to a greater propensity for reignition. Furthermore, compared to pre-oxidized coal at 240 ℃, additional water immersion of this high-temperature pre-oxidized coal significantly lowered its oxidative combustion characteristic temperature and activation energy. The characteristic temperatures for the oxidation weight gain stage and combustion weight loss stage decreased by 65.2 ℃ and 16.3 ℃, respectively. The activation energy of the combustion mass loss stage decreases by 7.8 kJ·mol-1, indicating an increased risk of coal spontaneous combustion. The combustion reaction rate of coal decreases after water immersion. The value of pre-exponential factor(lnA) for raw coal after water immersion is reduced by 6.3% compared with raw coal, while for coal samples pre-oxidized at 240 ℃ and then treated with water immersion, lnA is decreased by 60.4%. When coal bodies undergo high-temperature oxidation, direct water injection for cooling is not recommended. Instead, other fire prevention and suppression measures such as injecting low-temperature nitrogen or liquid carbon dioxide should be prioritized.

Pre-oxidized coal  /  Water immersion  /  Thermogravimetric analysis  /  Characteristic temperature  /  Activation energy
郝建峰, 张遵国, 陈岳振, 唐朝, 丁林林, 钱清侠, 赵小龙. 预氧化与浸水作用下气煤氧化燃烧特征试验研究. 矿业研究与开发, 2026 , 46 (3) : 191 -197 .
Jianfeng HAO, Zunguo ZHANG, Yuezhen CHEN, Chao TANG, Linlin DING, Qingxia QIAN, Xiaolong ZHAO. Experimental Study on the Oxidation and Combustion Characteristics of Gas-Coal Under Pre-Oxidation and Water Immersion Conditions[J]. Mining Research and Development, 2026 , 46 (3) : 191 -197 .
  • 国家自然科学基金资助项目(52304220)
  • 辽宁省教育厅高校基本科研项目(LJ242410147082)
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2026年第46卷第3期
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  • 接收时间:2025-04-27
  • 首发时间:2026-10-29
  • 出版时间:2026-03-25
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  • 收稿日期:2025-04-27
基金
国家自然科学基金资助项目(52304220)
辽宁省教育厅高校基本科研项目(LJ242410147082)
作者信息
    1.同煤大唐塔山煤矿有限公司,山西 大同市 034400
    2.辽宁工程技术大学 安全科学与工程学院,辽宁 葫芦岛市 125105

通讯作者:

张遵国(1986—),男,重庆大足人,博士,副教授,主要从事矿井灾害防治及CO2地质封存方面的研究。E-mail:
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
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