Article(id=1322559815201706141, tenantId=1146029695717560320, journalId=1225396423026438145, issueId=1322559792544072145, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1735833600000, receivedDateStr=2025-01-03, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1793252431917, onlineDateStr=2026-10-29, pubDate=1769270400000, pubDateStr=2026-01-25, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793252431917, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793252431917, creator=13701087609, updateTime=1793252431917, updator=13701087609, issue=Issue{id=1322559792544072145, tenantId=1146029695717560320, journalId=1225396423026438145, year='2026', volume='46', issue='1', pageStart='1', pageEnd='306', issueExtLink='null', onlineDate='null', pubDate='1769270400000', pubDateStr='2026-01-25', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793252426515, creator='13701087609', updateTime=1793252675339, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322560836246286849, tenantId=1146029695717560320, journalId=1225396423026438145, issueId=1322559792544072145, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322560836246286850, tenantId=1146029695717560320, journalId=1225396423026438145, issueId=1322559792544072145, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=264, endPage=272, ext={EN=ArticleExt(id=1322559815465947294, articleId=1322559815201706141, tenantId=1146029695717560320, journalId=1225396423026438145, language=EN, title=Study on the Effect of a New Room-Temperature Collector MY on the Reverse Flotation Behavior of Hematite, columnId=null, journalTitle=Mining Research and Development, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Anshan-type hematite accounts for about 55.20% of the total identified iron ore resources in China, and its flotation generally requires high temperature (about 35 ℃ or more) conditions, which increases the production cost. Therefore, the flotation behavior of hematite and quartz was studied with a self-developed MY-type collector and compared with the sodium oleate flotation system. Utilizing detection and analysis techniques such as contact angle, Zeta potential and infrared spectroscopy analysis, the action mechanism of MY on mineral surface was discussed. The results of single-mineral flotation experiments show that under the temperature range of 15-35 ℃, the pH of 11.5, and the dosage of 200 mg/L, the MY-type collector can achieve recovery rate of quartz and hematite exceeding 87.25% and 92.50% respectively. At 25 ℃, under the interaction of the three agents of starch, CaO, and collector, the maximun difference in single mineral recovery rate of quartz and hematite is 89.25 percentage points under the MY flotation system, which significantly improves the difference in the flotation of quartz and hematite compared to the sodium oleate flotation system (the maximun difference in recovery rate is 56.25 percentage points). The mechanism analysis results indicate that MY collector exhibits multifaceted synergistic adsorption effects on quartz mineral surfaces, including electrostatic adsorption, hydrogen bonding, and chemical bonding, while on hematite surfaces, it primarily involves molecular adsorption and electrostatic adsorption. Due to the presence of multiple active groups such as S=O, —NH2 and C=O in its structure, MY forms coupled synergistic interactions across multiple active sites, enhancing its quartz recovery capability. This also amplifies the floatability difference between quartz and hematite, effectively promoting the separation of hematite and quartz in the room-temperature reverse flotation system.

, authors=Fuxing YAO1, Yiwen MA1, Jie LIU2, Yang LI1, Xin SUN1, Jinghui SUN1, Mengke ZHENG1, authorsList=Fuxing YAO, Yiwen MA, Jie LIU, Yang LI, Xin SUN, Jinghui SUN, Mengke ZHENG, authorCompany=null, correspAuthors=Yiwen MA, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322559815826657439, articleId=1322559815201706141, tenantId=1146029695717560320, journalId=1225396423026438145, language=CN, title=新型常温捕收剂MY对赤铁矿反浮选行为影响研究, columnId=1226462297560892399, journalTitle=矿业研究与开发, columnName=选矿与资源综合利用, runingTitle=null, highlight=null, articleAbstract=

鞍山式赤铁矿在我国已探明的铁矿资源总储量中占比约为55.20%,其在浮选时一般需采用加温(约35 ℃以上)条件,增加了生产成本。采用自研的新型捕收剂MY进行赤铁矿、石英浮选行为研究,并与油酸钠浮选体系进行了对比,通过接触角、Zeta电位和红外光谱等检测分析手段,探讨了MY在矿物表面的作用机理。单矿物浮选结果表明:MY在15~35 ℃温度范围内,pH为11.5,捕收剂用量为200 mg/L条件下,石英、赤铁矿回收率分别可达87.25%、92.50%以上。在25 ℃时,在淀粉、CaO、捕收剂3种药剂相互作用下,MY浮选体系下,石英、赤铁矿单矿物回收率最大差值为89.25个百分点,相较于油酸钠浮选体系(回收率最大差值为56.25个百分点)明显提高。机理分析结果表明,MY捕收剂在石英矿物表面发生了静电吸附、氢键作用以及化学键合作用等多效协同吸附作用,在赤铁矿表面以分子吸附、静电吸附作用为主。MY因其结构中存在S=O、—NH2、C=O等多种活性基团,可形成多活性位点的耦合协同作用,增强其对石英的捕收能力,并增大了石英与赤铁矿间的可浮性差异,在常温反浮选体系中可有效促进赤铁矿与石英的分离。

, authors=姚富兴1, 马艺闻1, 刘杰2, 李洋1, 孙欣1, 孙竞珲1, 郑梦可1, authorsList=姚富兴, 马艺闻, 刘杰, 李洋, 孙欣, 孙竞珲, 郑梦可, authorCompany=null, correspAuthors=马艺闻, authorNote=

姚富兴(1998—),男,河南三门峡人,硕士研究生,研究方向为浮选药剂结构设计。E-mail:

, correspAuthorsNote=
马艺闻(1985—),女,辽宁鞍山人,博士,副教授,主要从事矿产资源综合利用、浮选理论与浮选药剂研发等研究。E-mail:
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姚富兴(1998—),男,河南三门峡人,硕士研究生,研究方向为浮选药剂结构设计。E-mail:

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姚富兴(1998—),男,河南三门峡人,硕士研究生,研究方向为浮选药剂结构设计。E-mail:

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新型常温捕收剂MY对赤铁矿反浮选行为影响研究
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姚富兴 1 , 马艺闻 1 , 刘杰 2 , 李洋 1 , 孙欣 1 , 孙竞珲 1 , 郑梦可 1
矿业研究与开发 | 选矿与资源综合利用 2026,46(1): 264-272
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矿业研究与开发 |选矿与资源综合利用 2026 , 46 (1) : 264 -272
新型常温捕收剂MY对赤铁矿反浮选行为影响研究
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姚富兴1 , 马艺闻1 , 刘杰2, 李洋1, 孙欣1, 孙竞珲1, 郑梦可1
作者信息
  • 1.辽宁科技大学 矿业工程学院,辽宁 鞍山市 114051
  • 2.东北大学 资源与土木工程学院,辽宁 沈阳 110819
通讯作者:
马艺闻(1985—),女,辽宁鞍山人,博士,副教授,主要从事矿产资源综合利用、浮选理论与浮选药剂研发等研究。E-mail:
作者简介:

姚富兴(1998—),男,河南三门峡人,硕士研究生,研究方向为浮选药剂结构设计。E-mail:

Study on the Effect of a New Room-Temperature Collector MY on the Reverse Flotation Behavior of Hematite
Fuxing YAO1 , Yiwen MA1 , Jie LIU2, Yang LI1, Xin SUN1, Jinghui SUN1, Mengke ZHENG1
Affiliations
  • 1.School of Mining Engineering, University of Science and Technology Liaoning, Anshan, Liaoning 114051, China
  • 2.School of Resources and Civil Engineering, Northeastern University, Shenyang, Liaoning 110819, China
出版时间: 2026-01-25
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鞍山式赤铁矿在我国已探明的铁矿资源总储量中占比约为55.20%,其在浮选时一般需采用加温(约35 ℃以上)条件,增加了生产成本。采用自研的新型捕收剂MY进行赤铁矿、石英浮选行为研究,并与油酸钠浮选体系进行了对比,通过接触角、Zeta电位和红外光谱等检测分析手段,探讨了MY在矿物表面的作用机理。单矿物浮选结果表明:MY在15~35 ℃温度范围内,pH为11.5,捕收剂用量为200 mg/L条件下,石英、赤铁矿回收率分别可达87.25%、92.50%以上。在25 ℃时,在淀粉、CaO、捕收剂3种药剂相互作用下,MY浮选体系下,石英、赤铁矿单矿物回收率最大差值为89.25个百分点,相较于油酸钠浮选体系(回收率最大差值为56.25个百分点)明显提高。机理分析结果表明,MY捕收剂在石英矿物表面发生了静电吸附、氢键作用以及化学键合作用等多效协同吸附作用,在赤铁矿表面以分子吸附、静电吸附作用为主。MY因其结构中存在S=O、—NH2、C=O等多种活性基团,可形成多活性位点的耦合协同作用,增强其对石英的捕收能力,并增大了石英与赤铁矿间的可浮性差异,在常温反浮选体系中可有效促进赤铁矿与石英的分离。

赤铁矿  /  新型常温捕收剂  /  反浮选  /  石英

Anshan-type hematite accounts for about 55.20% of the total identified iron ore resources in China, and its flotation generally requires high temperature (about 35 ℃ or more) conditions, which increases the production cost. Therefore, the flotation behavior of hematite and quartz was studied with a self-developed MY-type collector and compared with the sodium oleate flotation system. Utilizing detection and analysis techniques such as contact angle, Zeta potential and infrared spectroscopy analysis, the action mechanism of MY on mineral surface was discussed. The results of single-mineral flotation experiments show that under the temperature range of 15-35 ℃, the pH of 11.5, and the dosage of 200 mg/L, the MY-type collector can achieve recovery rate of quartz and hematite exceeding 87.25% and 92.50% respectively. At 25 ℃, under the interaction of the three agents of starch, CaO, and collector, the maximun difference in single mineral recovery rate of quartz and hematite is 89.25 percentage points under the MY flotation system, which significantly improves the difference in the flotation of quartz and hematite compared to the sodium oleate flotation system (the maximun difference in recovery rate is 56.25 percentage points). The mechanism analysis results indicate that MY collector exhibits multifaceted synergistic adsorption effects on quartz mineral surfaces, including electrostatic adsorption, hydrogen bonding, and chemical bonding, while on hematite surfaces, it primarily involves molecular adsorption and electrostatic adsorption. Due to the presence of multiple active groups such as S=O, —NH2 and C=O in its structure, MY forms coupled synergistic interactions across multiple active sites, enhancing its quartz recovery capability. This also amplifies the floatability difference between quartz and hematite, effectively promoting the separation of hematite and quartz in the room-temperature reverse flotation system.

Hematite  /  New room-temperature collector  /  Reverse flotation  /  Quartz
姚富兴, 马艺闻, 刘杰, 李洋, 孙欣, 孙竞珲, 郑梦可. 新型常温捕收剂MY对赤铁矿反浮选行为影响研究. 矿业研究与开发, 2026 , 46 (1) : 264 -272 .
Fuxing YAO, Yiwen MA, Jie LIU, Yang LI, Xin SUN, Jinghui SUN, Mengke ZHENG. Study on the Effect of a New Room-Temperature Collector MY on the Reverse Flotation Behavior of Hematite[J]. Mining Research and Development, 2026 , 46 (1) : 264 -272 .
  • 辽宁省“揭榜挂帅”科技攻关项目(2023JH1/10400011)
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  • 接收时间:2025-01-03
  • 首发时间:2026-10-29
  • 出版时间:2026-01-25
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  • 收稿日期:2025-01-03
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辽宁省“揭榜挂帅”科技攻关项目(2023JH1/10400011)
作者信息
    1.辽宁科技大学 矿业工程学院,辽宁 鞍山市 114051
    2.东北大学 资源与土木工程学院,辽宁 沈阳 110819

通讯作者:

马艺闻(1985—),女,辽宁鞍山人,博士,副教授,主要从事矿产资源综合利用、浮选理论与浮选药剂研发等研究。E-mail:
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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