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In a medium-grade siliceous-calcareous phosphate ore from the Yichang region of Hubei Province, the fluorapatite is the target mineral and potash feldspar, dolomite, and quartz are the main gangue minerals, and the P2O5 grade of the raw ore is 23.27%. To enhance its utilization efficiency of the ore, a double reverse flotation process was adopted, and systematic optimization tests were conducted on grinding fineness, dosages of collectors (H-1, KM-6), and auxiliary reagents (phosphoric acid, HF-959). The flotation mechanism was revealed through measurements of contact angle, Zeta potential, and infrared spectroscopy. The results show that under the grinding fineness of 75 μm accounting for 81%, a closed-circuit flotation flowsheet consisting of one roughing and two sweeping for desilication followed by one roughing and one sweeping for demineralization, a high-quality phosphate concentrate with P2O5 grade of 32.20% and recovery rate of 81.20% can be obtained. The Al2O3 and MgO contents in the concentrate are reduced to 2.02% (a decrease of 53.35%) and 0.62% (a decrease of 60.26%), respectively, effectively achieving the separation of apatite from potash feldspar, dolomite, and other gangue minerals. Research indicates that the collector H-1 primarily adsorbs physically on the surface of potash feldspar, selectively enhancing its hydrophobicity, which is the core mechanism for the efficient removal of potash feldspar.

, authors=Baobao Liu1, Qi Zhang1, Zhiliang Huang2, Yanhong Fu1, Hui Leng3, Yongcheng Liu3, Chengtao Tian1, 4, Dongsheng He1, authorsList=Baobao Liu, Qi Zhang, Zhiliang Huang, Yanhong Fu, Hui Leng, Yongcheng Liu, Chengtao Tian, Dongsheng He, authorCompany=null, correspAuthors=Yanhong Fu, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1321893327474115413, articleId=1321893325385352019, tenantId=1146029695717560320, journalId=1225396423026438145, language=CN, title=磷矿双反浮选工艺优化与钾长石脱除机理研究, columnId=1226462297560892399, journalTitle=矿业研究与开发, columnName=选矿与资源综合利用, runingTitle=null, highlight=null, articleAbstract=

湖北宜昌地区某中品位硅钙质磷矿石以氟磷灰石为目的矿物,钾长石、白云石和石英为主要脉石矿物,原矿P2O5品位23.27%。为了提升该矿石的资源利用率,采用双反浮选工艺,系统开展了磨矿细度、捕收剂(H-1, KM-6)及辅助药剂(磷酸、HF-959)用量优化试验,结合接触角、Zeta电位与红外光谱测试揭示了浮选作用机理。结果表明:当磨矿细度-75 μm占比81%时,采用脱硅一粗两扫、脱镁一粗一扫的闭路浮选流程,可获得P2O5品位32.20%、回收率81.20%的优质磷精矿,精矿中Al2O3和MgO含量分别降至2.02%(降幅为53.35%)和0.62%(降幅为60.26%),实现了磷灰石与钾长石、白云石等脉石矿物的分离。研究表明,捕收剂H-1以物理吸附为主,选择性作用于钾长石表面,显著增强其疏水性,是实现钾长石高效脱除的核心机制。

, authors=刘宝宝1, 张琦1, 黄志亮2, 付艳红1, 冷慧3, 刘永成3, 田承涛1, 4, 何东升1, authorsList=刘宝宝, 张琦, 黄志亮, 付艳红, 冷慧, 刘永成, 田承涛, 何东升, authorCompany=null, correspAuthors=付艳红, authorNote=

刘宝宝(1996—),男,安徽阜阳人,硕士研究生,研究方向为磷矿选矿。E-mail:

, correspAuthorsNote=
付艳红(1993—),女,陕西汉中人,博士,讲师,主要从事矿物加工理论、工艺与设备研究。E-mail:
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刘宝宝(1996—),男,安徽阜阳人,硕士研究生,研究方向为磷矿选矿。E-mail:

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刘宝宝(1996—),男,安徽阜阳人,硕士研究生,研究方向为磷矿选矿。E-mail:

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磷矿双反浮选工艺优化与钾长石脱除机理研究
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刘宝宝 1 , 张琦 1 , 黄志亮 2 , 付艳红 1 , 冷慧 3 , 刘永成 3 , 田承涛 1, 4 , 何东升 1
矿业研究与开发 | 选矿与资源综合利用 2026,46(6): 264-271
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矿业研究与开发 |选矿与资源综合利用 2026 , 46 (6) : 264 -271
磷矿双反浮选工艺优化与钾长石脱除机理研究
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刘宝宝1 , 张琦1, 黄志亮2, 付艳红1 , 冷慧3, 刘永成3, 田承涛1, 4, 何东升1
作者信息
  • 1.武汉工程大学 资源与安全工程学院,湖北 武汉 430073
  • 2.湖北宜化集团有限责任公司,湖北 宜昌市 443099
  • 3.湖北宜化化工科技研发有限公司,湖北 宜昌市 443000
  • 4.湖北三宁化工股份有限公司,湖北 宜昌市 443206
通讯作者:
付艳红(1993—),女,陕西汉中人,博士,讲师,主要从事矿物加工理论、工艺与设备研究。E-mail:
作者简介:

刘宝宝(1996—),男,安徽阜阳人,硕士研究生,研究方向为磷矿选矿。E-mail:

Study on Optimization of Double Reverse Flotation Process of Phosphate Ore and Removal Mechanism of Potash Feldspar
Baobao Liu1 , Qi Zhang1, Zhiliang Huang2, Yanhong Fu1 , Hui Leng3, Yongcheng Liu3, Chengtao Tian1, 4, Dongsheng He1
Affiliations
  • 1.School of Resources and Safety Engineering, Wuhan Institute of Technology, Wuhan, Hubei 430073, China
  • 2.Hubei Yihua Group Co., Ltd., Yichang, Hubei 443099, China
  • 3.Hubei Yihua Chemical Technology Research and Development Co., Ltd., Yichang, Hubei 443000, China
  • 4.Hubei Sanning Chemical Co., Ltd., Yichang, Hubei 443206, China
出版时间: 2026-06-18
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湖北宜昌地区某中品位硅钙质磷矿石以氟磷灰石为目的矿物,钾长石、白云石和石英为主要脉石矿物,原矿P2O5品位23.27%。为了提升该矿石的资源利用率,采用双反浮选工艺,系统开展了磨矿细度、捕收剂(H-1, KM-6)及辅助药剂(磷酸、HF-959)用量优化试验,结合接触角、Zeta电位与红外光谱测试揭示了浮选作用机理。结果表明:当磨矿细度-75 μm占比81%时,采用脱硅一粗两扫、脱镁一粗一扫的闭路浮选流程,可获得P2O5品位32.20%、回收率81.20%的优质磷精矿,精矿中Al2O3和MgO含量分别降至2.02%(降幅为53.35%)和0.62%(降幅为60.26%),实现了磷灰石与钾长石、白云石等脉石矿物的分离。研究表明,捕收剂H-1以物理吸附为主,选择性作用于钾长石表面,显著增强其疏水性,是实现钾长石高效脱除的核心机制。

磷矿  /  双反浮选  /  钾长石  /  白云石  /  氟磷灰石

In a medium-grade siliceous-calcareous phosphate ore from the Yichang region of Hubei Province, the fluorapatite is the target mineral and potash feldspar, dolomite, and quartz are the main gangue minerals, and the P2O5 grade of the raw ore is 23.27%. To enhance its utilization efficiency of the ore, a double reverse flotation process was adopted, and systematic optimization tests were conducted on grinding fineness, dosages of collectors (H-1, KM-6), and auxiliary reagents (phosphoric acid, HF-959). The flotation mechanism was revealed through measurements of contact angle, Zeta potential, and infrared spectroscopy. The results show that under the grinding fineness of 75 μm accounting for 81%, a closed-circuit flotation flowsheet consisting of one roughing and two sweeping for desilication followed by one roughing and one sweeping for demineralization, a high-quality phosphate concentrate with P2O5 grade of 32.20% and recovery rate of 81.20% can be obtained. The Al2O3 and MgO contents in the concentrate are reduced to 2.02% (a decrease of 53.35%) and 0.62% (a decrease of 60.26%), respectively, effectively achieving the separation of apatite from potash feldspar, dolomite, and other gangue minerals. Research indicates that the collector H-1 primarily adsorbs physically on the surface of potash feldspar, selectively enhancing its hydrophobicity, which is the core mechanism for the efficient removal of potash feldspar.

Phosphate ore  /  Double reverse flotation  /  Potash feldspar  /  Dolomite  /  Fluorapatite
刘宝宝, 张琦, 黄志亮, 付艳红, 冷慧, 刘永成, 田承涛, 何东升. 磷矿双反浮选工艺优化与钾长石脱除机理研究. 矿业研究与开发, 2026 , 46 (6) : 264 -271 .
Baobao Liu, Qi Zhang, Zhiliang Huang, Yanhong Fu, Hui Leng, Yongcheng Liu, Chengtao Tian, Dongsheng He. Study on Optimization of Double Reverse Flotation Process of Phosphate Ore and Removal Mechanism of Potash Feldspar[J]. Mining Research and Development, 2026 , 46 (6) : 264 -271 .
  • 湖北省国际科技合作项目(2023EHA071)
  • 湖北省科技创新人才计划项目(2024DJC089)
  • 湖北省揭榜制科技项目(2024BEB004)
  • 云南省技术创新中心项目(202305AK340002)
  • 湖北省重点研发计划项目(2023BCB076)
  • 武汉工程大学科学基金项目(K2023108)
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  • 接收时间:2025-06-27
  • 首发时间:2026-10-27
  • 出版时间:2026-06-18
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  • 收稿日期:2025-06-27
基金
湖北省国际科技合作项目(2023EHA071)
湖北省科技创新人才计划项目(2024DJC089)
湖北省揭榜制科技项目(2024BEB004)
云南省技术创新中心项目(202305AK340002)
湖北省重点研发计划项目(2023BCB076)
武汉工程大学科学基金项目(K2023108)
作者信息
    1.武汉工程大学 资源与安全工程学院,湖北 武汉 430073
    2.湖北宜化集团有限责任公司,湖北 宜昌市 443099
    3.湖北宜化化工科技研发有限公司,湖北 宜昌市 443000
    4.湖北三宁化工股份有限公司,湖北 宜昌市 443206

通讯作者:

付艳红(1993—),女,陕西汉中人,博士,讲师,主要从事矿物加工理论、工艺与设备研究。E-mail:
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2种不同金属材料的力学参数
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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