Article(id=1321866341506728932, tenantId=1146029695717560320, journalId=1225396423026438145, issueId=1321866297609146910, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1758470400000, receivedDateStr=2025-09-22, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1793087094903, onlineDateStr=2026-10-27, pubDate=1779638400000, pubDateStr=2026-05-25, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793087094903, onlineIssueDateStr=2026-10-27, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793087094903, creator=13701087609, updateTime=1793087094903, updator=13701087609, issue=Issue{id=1321866297609146910, tenantId=1146029695717560320, journalId=1225396423026438145, year='2026', volume='46', issue='5', pageStart='1', pageEnd='312', issueExtLink='null', onlineDate='null', pubDate='1779638400000', pubDateStr='2026-05-25', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793087084438, creator='13701087609', updateTime=1793094562481, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1321897662853533805, tenantId=1146029695717560320, journalId=1225396423026438145, issueId=1321866297609146910, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1321897662853533806, tenantId=1146029695717560320, journalId=1225396423026438145, issueId=1321866297609146910, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=217, endPage=228, ext={EN=ArticleExt(id=1321866341733221349, articleId=1321866341506728932, tenantId=1146029695717560320, journalId=1225396423026438145, language=EN, title=Research Progress on Flotation Separation Reagents of Cassiterite, columnId=null, journalTitle=Mining Research and Development, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Flotation of cassiterite is a critical step for the efficient utilization of complex mineral resources. Based on domestic and international research, a systematic review of the research progress in the development of cassiterite flotation reagents and the mechanisms of interfacial interactions was conducted. Based on the surface anisotropy of cassiterite crystals, the distribution of active sites on the (110) (100) and (101) crystal planes was analyzed in detail. The synergistic adsorption mechanism among multiple crystal planes was elucidated, and the coordination chemistry of metal ions (such as Pb²⁺ and Fe³⁺ ) in surface activation was revealed. In terms of the pharmaceutical system, molecular design strategies for novel hydroxamic acid derivatives, phenylphosphonic acid derivatives, and environmentally friendly amino acid-based collectors were reviewed, noting that targeted functional group modification can effectively enhance chelation selectivity toward Sn sites. In terms of mechanism of action, composite agents significantly enhanced interfacial adsorption density through chelation and synergistic adsorption. For example, the combination of hydroxamic acid and fatty acids formed a multilayer adsorption structure, while cationic-anionic composite collectors reinforced both electrostatic and coordination interactions. Composite inhibitors such as polyacrylic acid-lignosulfonate achieved precise inhibition of calcium and magnesium gangue minerals through steric hindrance and selective adsorption. Future research should focus on establishing a quantitative relationship among "molecular structure, adsorption configuration and flotation performance", and combining with computational chemistry methods to advance the rational design and industrial application of green, high-efficiency reagents.

, authors=Zigang Li¹, Dandan Liu^{2, 3}, Chang Shen^{2, 3}, Zhongdui Bai¹, Yunxiao Gan¹, Hui Li¹, Qiang Song^{2, 3}, authorsList=Zigang Li, Dandan Liu, Chang Shen, Zhongdui Bai, Yunxiao Gan, Hui Li, Qiang Song, authorCompany=null, correspAuthors=Qiang Song, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1321866342005851110, articleId=1321866341506728932, tenantId=1146029695717560320, journalId=1225396423026438145, language=CN, title=锡石浮选分离药剂研究进展, columnId=1226462297560892399, journalTitle=矿业研究与开发, columnName=选矿与资源综合利用, runingTitle=null, highlight=null, articleAbstract=

锡石浮选是实现复杂矿产资源高效利用的关键环节。基于国内外研究，系统综述了锡石浮选药剂开发与界面作用机理的研究进展。基于锡石晶体表面各向异性，重点分析了（110）面、（100）面和（101）面三类晶面的活性位点分布，阐述了多晶面间的协同吸附机制，揭示了金属离子（如Pb²⁺、Fe³⁺）在界面活化中的配位化学作用。在药剂体系方面，综述了新型羟肟酸衍生物、苯基膦酸类及环境友好型氨基酸类捕收剂的分子设计策略，指出通过官能团定向修饰可有效增强与Sn位点的螯合选择性。在作用机理方面，组合药剂通过螯合与协同吸附显著提升界面吸附密度，如羟肟酸-脂肪酸复配形成多层吸附结构，阴阳离子组合捕收剂则强化静电与配位双重作用；聚丙烯酸-木质素磺酸盐等复合抑制剂通过空间位阻与特性吸附实现钙镁脉石矿物的精准抑制。未来研究应聚焦于建立“分子结构—吸附构型—浮选性能”的量化关联，结合计算化学手段推动绿色高效药剂的理性设计与工业应用。

, authors=李自刚¹, 刘丹丹^{2, 3}, 申畅^{2, 3}, 柏忠兑¹, 甘云霄¹, 李辉¹, 宋强^{2, 3}, authorsList=李自刚, 刘丹丹, 申畅, 柏忠兑, 甘云霄, 李辉, 宋强, authorCompany=null, correspAuthors=宋强, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=b852Nlf+0h1FSAKHGBrKPw==, magXml=MiDu6/CEOWIu7JPSOqHFBA==, pdfUrl=null, pdf=4esCrOs1a9y3yDvfJP3Ahg==, pdfFileSize=4930954, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=+TW8CSEwtBMkgR0lmlCELw==, mapNumber=null, fund=null)}, authors=[Author(id=1321866342605636593, tenantId=1146029695717560320, journalId=1225396423026438145, articleId=1321866341506728932, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=191886347@qq.com, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1321866344287552499, tenantId=1146029695717560320, journalId=1225396423026438145, articleId=1321866341506728932, authorId=1321866342605636593, language=EN, stringName=Zigang Li, firstName=Zigang, middleName=null, lastName=Li, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=¹, address=^1.Yunnan Hualian Zinc and Indium Co., Ltd., Maguan County, Yunnan 663701, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1321866344392410100, tenantId=1146029695717560320, journalId=1225396423026438145, articleId=1321866341506728932, authorId=1321866342605636593, language=CN, stringName=李自刚, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=¹, address=^1．云南华联锌铟股份有限公司，云南 马关县　663701, bio={"content":"

李自刚（1992—），男，云南马关人，工程师，主要研究方向为选矿工程。E-mail: 191886347@qq.com

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李自刚（1992—），男，云南马关人，工程师，主要研究方向为选矿工程。E-mail: 191886347@qq.com

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