Article(id=1296827266395304633, tenantId=1146029695717560320, journalId=1146031591421210625, issueId=1296827250129784977, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=research-article, receivedDate=null, receivedDateStr=null, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1787117314194, onlineDateStr=2026-08-19, pubDate=1785168000000, pubDateStr=2026-07-28, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1787117314194, onlineIssueDateStr=2026-08-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1787117314194, creator=13701087609, updateTime=1787117314194, updator=13701087609, issue=Issue{id=1296827250129784977, tenantId=1146029695717560320, journalId=1146031591421210625, year='2026', volume='44', issue='14', pageStart='1', pageEnd='192', issueExtLink='null', onlineDate='null', pubDate='1785168000000', pubDateStr='2026-07-28', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1787117310316, creator='13701087609', updateTime=1787117721595, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1296828975423185806, tenantId=1146029695717560320, journalId=1146031591421210625, issueId=1296827250129784977, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1296828975423185807, tenantId=1146029695717560320, journalId=1146031591421210625, issueId=1296827250129784977, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=8, endPage=8, ext={EN=ArticleExt(id=1296827266630185658, articleId=1296827266395304633, tenantId=1146029695717560320, journalId=1146031591421210625, language=EN, title=null, columnId=1157710593001177623, journalTitle=Science & Technology Review, columnName=Science and Technology News, runingTitle=null, highlight=null, articleAbstract=null, authors=null, authorsList=null, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=All rights reserved. Unauthorized reproduction is prohibited., copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1296827267158667965, articleId=1296827266395304633, tenantId=1146029695717560320, journalId=1146031591421210625, language=CN, title=一卷薄膜有望使丙烯纯化成本降低8成, columnId=1157710593177338394, journalTitle=科技导报, columnName=科技新闻, runingTitle=null, highlight=null, articleAbstract=

气体分离是石油化工、天然气处理、碳捕集和氢气纯化等工业过程中的关键环节。工业上长期主要依靠低温精馏,根据分子挥发性的细微差异完成分离,但这类过程设备庞大、能耗高。膜分离可利用分子尺寸和扩散速率的差异进行筛分,被认为是一条更节能的路线。然而,易于加工的聚合物膜往往难以达到高难度气体分离所需的性能,而分离能力出色的金属有机框架(metalorganic framework, MOF)膜又受制于复杂、敏感的结晶过程,难以无缺陷地放大到工业尺寸。

, authors=null, authorsList=null, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=版权所有,未经授权,不得转载。, copyrightOwner=《科技导报》编辑部, extLink=null, articleAbsUrl=null, sourceXml=mrgjFmluUdNDEIILvZdlLA==, magXml=xzAm0YdAR8TAT96w+4cESA==, pdfUrl=null, pdf=gkUdvEZ2etXas5Y0RuuzVA==, pdfFileSize=1055335, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=yquPauhvtdbBGRw6nc9+Eg==, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=7JtYYd/3P2yD4+9ZaJ3i4A==, mapNumber=null, fund=null)}, authors=null, keywords=null, refs=null, funds=null, companyList=null, figs=[ArticleFig(id=1296828823329337542, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1296827266395304633, language=EN, label=null, caption=null, figureFileSmall=Ugb+grokeMRO15zouZoFUA==, figureFileBig=9LOVL6lJCuMXjLWBkwBKUA==, tableContent=null), ArticleFig(id=1296828823396446407, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1296827266395304633, language=CN, label=null, caption=研究人员利用工业卷对卷设备连续制备“准纯MOF膜”,右侧为制成的紫色ZIF-67膜

(图片来源:《Nature》)

, figureFileSmall=Ugb+grokeMRO15zouZoFUA==, figureFileBig=9LOVL6lJCuMXjLWBkwBKUA==, tableContent=null)], attaches=null, journal=Journal(id=1125356956822126595, delFlag=0, nameCn=科技导报, nameEn=Science & Technology Review, nameHistory1=null, nameHistory2=null, issn=1000-7857, eissn=, cn=11-1421/N, coden=null, periodic=3, language=CN, oaType=0, ccby=null, superviseOffice=null, ownerOffice=null, pubOffice=null, editorOffice=null, officeType=null, aims=null, clcCode=null, officeProv=null, officeCity=null, officeAddr=null, officeZip=null, officeEmail=null, officePhone=null, editDirector=null, officeDirector=null, officeDirectorPhone=null, officeStaffNum=null, officeEmpNum=null, coverPicUrl=wfghvu3bhh/dKxuZ+ucVHA==, journalPrice=null, startedYear=null, abbrevIsoEn=Sci Technol Rev, journalRemark=null, publicationField=null, createdTime=null, updatedTime=1788948767789, createdBy=null, updatedBy=13041195026, firstLetterCn=K, firstLetterEn=K, subjectCode=Multidisciplinary, subjectName=自然科学, subjectCodeEn=Multidisciplinary, subjectNameEn=null, picCn=wfghvu3bhh/dKxuZ+ucVHA==, picEn=yjSfclmpNm7ihn9NbTZ69g==, jcr=null, cjcr=null, exts=[JournalExt(id=1304508939635282786, language=CN, name=科技导报, nameHistory1=null, nameHistory2=null, managedBy=中国科学技术协会, sponsoredBy=中国科学技术协会, publishedBy=科技导报社, editorOffice=, officeProv=null, officeCity=null, officeAddr=, officeZip=, editDirector=, officeDirector=null, officePhone=null, coverPicUrl=null, journalRemark=, submitArticleUrl=null, websiteUrl=http://www.kjdb.org/CN/home, createdTime=1788948767813, updatedTime=1788948767813, createdBy=13041195026, updatedBy=13041195026, submissionGuidelinesUrl=http://www.kjdb.org/CN/column/column7.shtml, submissionAuthorUrl=https://kjdbauthor.cast.org.cn/webm, submissionEditorUrl=https://kjdbeditor.cast.org.cn/webm/, submissionReviewUrl=https://kjdbauthor.cast.org.cn/webm, submissionCeEditorUrl=https://kjdbeditor.cast.org.cn/webm/, submissionAeEditorUrl=https://kjdbeditor.cast.org.cn/webm/, option={"copyright":""}), JournalExt(id=1304508939694003043, language=EN, name=Science & Technology Review, nameHistory1=null, nameHistory2=null, managedBy=, sponsoredBy=, publishedBy=, editorOffice=, officeProv=null, officeCity=null, officeAddr=, officeZip=, editDirector=, officeDirector=null, officePhone=null, coverPicUrl=null, journalRemark=, submitArticleUrl=null, websiteUrl=http://www.kjdb.org/EN/home, createdTime=1788948767827, updatedTime=1788948767827, createdBy=13041195026, updatedBy=13041195026, submissionGuidelinesUrl=http://www.kjdb.org/EN/column/column7.shtml, submissionAuthorUrl=https://kjdbauthor.manuscriptcloud.com/login, submissionEditorUrl=https://kjdbeditor.manuscriptcloud.com/login, submissionReviewUrl=https://kjdbauthor.manuscriptcloud.com/login, submissionCeEditorUrl=https://kjdbeditor.manuscriptcloud.com/login, submissionAeEditorUrl=https://kjdbeditor.manuscriptcloud.com/login, option={"copyright":""})], databaseList=null, tenantJournalId=1146031591421210625, websiteList=[Website(id=1146104741081231361, webName=null, webTitle=null, webDomain=null, webCopyrigh=null, webIpcNo=null, seoTitle=null, seoKeywords=null, seoDescription=null, tenantJournalId=null, journalId=1146031591421210625, journalNameCn=null, journalNameEn=null, grayFlag=null, tenantId=1146029695717560320, platformId=null, journalGroupId=null, journalGroupNameCn=null, journalGroupNameEn=null, type=1, domain=https://castjournals.cast.org.cn/joweb/kjdbold/CN, language=CHT, createTime=1751182263881, createBy=18614031015, updateTime=1778563538782, updateBy=18614031015, name=科技导报, tplId=1260949628132966587, title=科技导报, delFlag=0, indexPage=/home, props=[WebsiteProps(id=1148021146403992296, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146104741081231361, code=articleTextType, value=kx, createTime=1751639170504, updateTime=1751639170504, creator=18614031015, updator=18614031015), WebsiteProps(id=1148021146378826469, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146104741081231361, code=banner, value=null, createTime=1751639170498, updateTime=1751639170498, creator=18614031015, updator=18614031015), WebsiteProps(id=1148021146366243556, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146104741081231361, code=logo, value=https://castjournals.cast.org.cn/joweb/kjdb/CN/file/pic?fileId=9GHSf7eGlIPH0Tv/OOdstA==, createTime=1751639170495, updateTime=1751639170495, creator=18614031015, updator=18614031015), WebsiteProps(id=1148021146395603687, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146104741081231361, code=picServerUrl, value=https://castjournals.cast.org.cn/joweb/kjdb/CN/file/pic, createTime=1751639170502, updateTime=1751639170502, creator=18614031015, updator=18614031015), WebsiteProps(id=1148021146387215078, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146104741081231361, code=staticResourcePath, value=https://castjournals.cast.org.cn/joweb/cast_kjdb_cn_619/, createTime=1751639170500, updateTime=1751639170500, creator=18614031015, updator=18614031015)]), Website(id=1146105254833139715, webName=null, webTitle=null, webDomain=null, webCopyrigh=null, webIpcNo=null, seoTitle=null, seoKeywords=null, seoDescription=null, tenantJournalId=null, journalId=1146031591421210625, journalNameCn=null, journalNameEn=null, grayFlag=null, tenantId=1146029695717560320, platformId=null, journalGroupId=null, journalGroupNameCn=null, journalGroupNameEn=null, type=1, domain=https://castjournals.cast.org.cn/joweb/kjdbold/EN, language=CHT, createTime=1751182386363, createBy=18614031015, updateTime=1776048495217, updateBy=18614031015, name=科技导报, tplId=1146101810881728533, title=Science & Technology Review, delFlag=0, indexPage=/home, props=[WebsiteProps(id=1155838567709528217, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146105254833139715, code=articleTextType, value=kx, createTime=1753502988984, updateTime=1753502988984, creator=18614031015, updator=18614031015), WebsiteProps(id=1155838567692750998, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146105254833139715, code=banner, value=null, createTime=1753502988980, updateTime=1753502988980, creator=18614031015, updator=18614031015), WebsiteProps(id=1155838567688556693, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146105254833139715, code=logo, value=https://castjournals.cast.org.cn/joweb/kjdb/EN/file/pic?fileId=9GHSf7eGlIPH0Tv/OOdstA==, createTime=1753502988979, updateTime=1753502988979, creator=18614031015, updator=18614031015), WebsiteProps(id=1155838567705333912, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146105254833139715, code=picServerUrl, value=https://castjournals.cast.org.cn/joweb/kjdb/EN/file/pic, createTime=1753502988983, updateTime=1753502988983, creator=18614031015, updator=18614031015), WebsiteProps(id=1155838567701139607, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146105254833139715, code=staticResourcePath, value=https://castjournals.cast.org.cn/joweb/cast_kjdb_en_623/, createTime=1753502988982, updateTime=1753502988982, creator=18614031015, updator=18614031015)]), Website(id=1242135128537874442, webName=null, webTitle=null, webDomain=null, webCopyrigh=null, webIpcNo=null, seoTitle=null, seoKeywords=null, seoDescription=null, tenantJournalId=null, journalId=1146031591421210625, journalNameCn=null, journalNameEn=null, grayFlag=null, tenantId=1146029695717560320, platformId=null, journalGroupId=null, journalGroupNameCn=null, journalGroupNameEn=null, type=1, domain=https://castjournals.cast.org.cn/joweb/kjdb/CN, language=CN, createTime=1774077692406, createBy=18614031015, updateTime=1776048481053, updateBy=18614031015, name=科技导报other, tplId=1146099689490845704, title=科技导报, delFlag=0, indexPage=/home, props=[WebsiteProps(id=1242918134445884174, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242135128537874442, code=articleTextType, value=kx, createTime=1774264375554, updateTime=1774264375554, creator=18614031015, updator=18614031015), WebsiteProps(id=1242918134424912651, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242135128537874442, code=banner, value=https://castjournals.cast.org.cn/joweb/kjdb/CN/file/pic?fileId=DdYjdDiJ8taFWepWGZ5jQw==, createTime=1774264375549, updateTime=1774264375549, creator=18614031015, updator=18614031015), WebsiteProps(id=1242918134466855697, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242135128537874442, code=grayFlag, value=0, createTime=1774264375559, updateTime=1774264375559, creator=18614031015, updator=18614031015), WebsiteProps(id=1242918134412329738, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242135128537874442, code=logo, value=https://castjournals.cast.org.cn/joweb/kjdb/CN/file/pic?fileId=SJqiJew4WTXky9kn2Wushw==, createTime=1774264375546, updateTime=1774264375546, creator=18614031015, updator=18614031015), WebsiteProps(id=1242918134479438611, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242135128537874442, code=minRunFlag, value=0, createTime=1774264375562, updateTime=1774264375562, creator=18614031015, updator=18614031015), WebsiteProps(id=1242918134441689869, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242135128537874442, code=picServerUrl, value=https://castjournals.cast.org.cn/joweb/kjdb/CN/file/pic, createTime=1774264375553, updateTime=1774264375553, creator=18614031015, updator=18614031015), WebsiteProps(id=1242918134471050002, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242135128537874442, code=silenceFlag, value=0, createTime=1774264375560, updateTime=1774264375560, creator=18614031015, updator=18614031015), WebsiteProps(id=1242918134433301260, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242135128537874442, code=staticResourcePath, value=https://castjournals.cast.org.cn/joweb/cast_kjdb_cn_619/, createTime=1774264375551, updateTime=1774264375551, creator=18614031015, updator=18614031015), WebsiteProps(id=1242918134454272783, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242135128537874442, code=themeColor, value=null, createTime=1774264375556, updateTime=1774264375556, creator=18614031015, updator=18614031015), WebsiteProps(id=1242918134458467088, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242135128537874442, code=themeStyle, value=null, createTime=1774264375557, updateTime=1774264375557, creator=18614031015, updator=18614031015)]), Website(id=1242172063583088667, webName=null, webTitle=null, webDomain=null, webCopyrigh=null, webIpcNo=null, seoTitle=null, seoKeywords=null, seoDescription=null, tenantJournalId=null, journalId=1146031591421210625, journalNameCn=null, journalNameEn=null, grayFlag=null, tenantId=1146029695717560320, platformId=null, journalGroupId=null, journalGroupNameCn=null, journalGroupNameEn=null, type=1, domain=https://castjournals.cast.org.cn/joweb/kjdb/EN, language=EN, createTime=1774086498408, createBy=18614031015, updateTime=1776333765238, updateBy=18614031015, name=科技导报others, tplId=1146101810881728533, title=Science & Technology Review, delFlag=0, indexPage=/home, props=[WebsiteProps(id=1242176044736803639, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242172063583088667, code=articleTextType, value=kx, createTime=1774087447580, updateTime=1774087447580, creator=18614031015, updator=18614031015), WebsiteProps(id=1242176044715832116, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242172063583088667, code=banner, value=null, createTime=1774087447575, updateTime=1774087447575, creator=18614031015, updator=18614031015), WebsiteProps(id=1242176044766163770, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242172063583088667, code=grayFlag, value=0, createTime=1774087447587, updateTime=1774087447587, creator=18614031015, updator=18614031015), WebsiteProps(id=1242176044703249203, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242172063583088667, code=logo, value=https://castjournals.cast.org.cn/joweb/kjdb/EN/file/pic?fileId=9GHSf7eGlIPH0Tv/OOdstA==, createTime=1774087447572, updateTime=1774087447572, creator=18614031015, updator=18614031015), WebsiteProps(id=1242176044778746684, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242172063583088667, code=minRunFlag, value=0, createTime=1774087447590, updateTime=1774087447590, creator=18614031015, updator=18614031015), WebsiteProps(id=1242176044728415030, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242172063583088667, code=picServerUrl, value=https://castjournals.cast.org.cn/joweb/kjdb/EN/file/pic, createTime=1774087447578, updateTime=1774087447578, creator=18614031015, updator=18614031015), WebsiteProps(id=1242176044770358075, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242172063583088667, code=silenceFlag, value=0, createTime=1774087447588, updateTime=1774087447588, creator=18614031015, updator=18614031015), WebsiteProps(id=1242176044724220725, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242172063583088667, code=staticResourcePath, value=https://castjournals.cast.org.cn/joweb/cast_kjdb_en_623/, createTime=1774087447577, updateTime=1774087447577, creator=18614031015, updator=18614031015), WebsiteProps(id=1242176044749386552, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242172063583088667, code=themeColor, value=null, createTime=1774087447583, updateTime=1774087447583, creator=18614031015, updator=18614031015), WebsiteProps(id=1242176044757775161, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1242172063583088667, code=themeStyle, value=null, createTime=1774087447585, updateTime=1774087447585, creator=18614031015, updator=18614031015)])], journalTitle=科技导报, weixinUrl=null, journalUrl=null, iacademicId=null, status=1, seqNo=null, journalTitleEn=Science & Technology Review, journalPhotoCn=wfghvu3bhh/dKxuZ+ucVHA==, journalPhotoEn=yjSfclmpNm7ihn9NbTZ69g==, journalFirstLetter=K, journalRecommend=null, journalNew=null, journalCollection=1, jcrJf=null, cjcrJf=0.91, jcrJfStr=null, cjcrJfStr=null, submissionFirstDecision=null, sciSubjectClassification=null, casSubjectClassification=null, citeScore=null, totalCitationFrequency=null, icpCode=null, psCode=null, advertisingLicenseCode=null, copyrightInformation=null, country=null, option=, provinceCode=null, provinceName=null, collectFlag=false, interPubPlatform=, interPubPlatformUrl=null), detailUrlCn=https://castjournals.cast.org.cn/joweb/kjdb/CN/Y2026/V44/I14/8, detailUrlEn=https://castjournals.cast.org.cn/joweb/kjdb/EN/Y2026/V44/I14/8, pdfUrlCn=https://castjournals.cast.org.cn/joweb/kjdb/CN/PDF/Y2026/V44/I14/8, pdfUrlEn=https://castjournals.cast.org.cn/joweb/kjdb/EN/PDF/Y2026/V44/I14/8, aliStartDate=0, aliEndDate=0, collectionFlag=false, citedCount=null, citedUrl=null, previewStatus=0, delFlag=0, hasFullText=1, orderTime=1785168000000, fullTextJson=null, articleText=null, reference=null)
收藏切换
一卷薄膜有望使丙烯纯化成本降低8成
收藏切换
PDF下载
科技导报 | 科技新闻 2026,44(14): 8-8
收起
收藏切换
科技导报 |科技新闻 2026 , 44 (14) : 8 -8
一卷薄膜有望使丙烯纯化成本降低8成
全屏
作者信息
  • Affiliations
    出版时间: 2026-07-28
    文章导航
    收藏切换

    气体分离是石油化工、天然气处理、碳捕集和氢气纯化等工业过程中的关键环节。工业上长期主要依靠低温精馏,根据分子挥发性的细微差异完成分离,但这类过程设备庞大、能耗高。膜分离可利用分子尺寸和扩散速率的差异进行筛分,被认为是一条更节能的路线。然而,易于加工的聚合物膜往往难以达到高难度气体分离所需的性能,而分离能力出色的金属有机框架(metalorganic framework, MOF)膜又受制于复杂、敏感的结晶过程,难以无缺陷地放大到工业尺寸。

    . 一卷薄膜有望使丙烯纯化成本降低8成. 科技导报, 2026 , 44 (14) : 8 -8 .
    . Science & Technology Review, 2026 , 44 (14) : 8 -8 .
    气体分离是石油化工、天然气处理、碳捕集和氢气纯化等工业过程中的关键环节。工业上长期主要依靠低温精馏,根据分子挥发性的细微差异完成分离,但这类过程设备庞大、能耗高。膜分离可利用分子尺寸和扩散速率的差异进行筛分,被认为是一条更节能的路线。然而,易于加工的聚合物膜往往难以达到高难度气体分离所需的性能,而分离能力出色的金属有机框架(metalorganic framework, MOF)膜又受制于复杂、敏感的结晶过程,难以无缺陷地放大到工业尺寸。
    香港科技大学(广州)联合清华大学、华南理工大学等机构的研究人员提出了一种可规模化制造的“准纯MOF膜”,试图同时解决膜材料性能与加工能力难以兼得的问题。7月15日,相关研究成果发表于《Nature》。
    传统混合基质膜通常将MOF颗粒分散在聚合物中,但颗粒含量过高时容易聚集,使材料失去流动性和可加工性;聚合物比例过高,又会削弱MOF自身的分子筛分能力。研究团队首先把块状MOF材料制成具有特定晶体取向的纳米片,再利用“分子锚”将少量聚合物动态连接到纳米片表面,使MOF与聚合物形成类似单一连续相的“融合相”。聚合物在其中主要承担稳定、连接和增强韧性的作用,MOF体积分数可达92%。这种设计既抑制了高浓度MOF纳米片的团聚,也让材料能够像常见涂布液一样通过溶液工艺制成大面积薄膜。
    研究人员将这一方法用于ZIF-67、CALF-20和CuBDC 3类代表性MOF材料,并分别测试了丙烯与丙烷、乙烯与乙烷、二氧化碳与甲烷以及氢气与甲烷的分离。结果显示,准纯MOF膜的分离性能接近相应纯MOF膜,同时具有聚合物膜的柔韧性和机械稳定性,整体性能优于传统聚合物膜及常规混合基质膜。
    更重要的是,研究团队在工业生产线上采用连续卷对卷工艺,制备出长20 m、宽20 cm的ZIF-67膜卷。膜卷不同位置表现出较为一致的丙烯和丙烷分离性能,表明这一工艺不仅能在实验室制膜,也有望接入现有工业涂布设备。在分离系统中,该膜以丙烯和丙烷混合气为原料,连续运行150 d后,产出的丙烯纯度仍保持在99.5% 以上,达到聚合级要求。技术经济分析显示,与精馏相比,其丙烯纯化成本有望降低约80%。
    研究通过重新设计MOF与聚合物的界面关系,把晶态多孔材料的分子筛分能力与成熟的溶液涂布工艺结合起来。该策略还可能用于碳捕集、天然气提纯和氢气净化等高能耗分离过程。
    (综合:《Nature》、香港科技大学官网)

    参考文献 引证文献
    排序方式:
    2026年第44卷第14期
    PDF下载
    125
    75
    引用本文
    BibTeX
    文章信息
    • 首发时间:2026-08-19
    • 出版时间:2026-07-28
    补充材料
    相关文章
    文章信息
    作者
    出版历史
    基金
    作者信息
    参考文献
    分享链接
    https://castjournals.cast.org.cn/joweb/kjdb/CN/1296827266395304633
    分享至
    全文二维码

    扫描看全文

    引用本文
    BibTeX
    本文的引用情况
    2种不同金属材料的力学参数

    Family
    属数
    Number of
    genus
    种数
    Number of
    species
    占总种数比例
    Percentage of
    total species (%)

    Genus
    种数
    Number of
    species
    占总种数比例
    Percentage of total
    species (%)
    鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
    小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
    多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
    红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
    小菇属 Mycena 11 5.26
    光柄菇属 Pluteus 5 2.39
    红菇属 Russula 17 8.13
    栓菌属 Trametes 5 2.39
    关闭全屏