Article(id=1242141986916999300, tenantId=1146029695717560320, journalId=1146031591421210625, issueId=1242141284979257419, articleNumber=null, orderNo=null, doi=10.3981/j.issn.1000-7857.2023.11.01761, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1700582400000, receivedDateStr=2023-11-22, revisedDate=1725897600000, revisedDateStr=2024-09-10, acceptedDate=null, acceptedDateStr=null, onlineDate=1736092800000, onlineDateStr=2025-01-06, pubDate=1734019200000, pubDateStr=2024-12-13, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1736092800000, onlineIssueDateStr=2025-01-06, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1774079327560, creator=sys-migrate, updateTime=1774079327560, updator=sys-migrate, issue=Issue{id=1242141284979257419, tenantId=1146029695717560320, journalId=1146031591421210625, year='2024', volume='42', issue='23', pageStart='1', pageEnd='144', issueExtLink='null', onlineDate='null', pubDate='1734019200000', pubDateStr='2024-12-13', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=null, issueType=-1, specialIssue=null, createTime=1774079160206, creator='sys-migrate', updateTime=1774079160206, updator='sys-migrate', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=98, endPage=107, ext={EN=ArticleExt(id=1242141989618135276, articleId=1242141986916999300, tenantId=1146029695717560320, journalId=1146031591421210625, language=EN, title=New reagents of containing fluorine and sulfur-containing in organic reactions, columnId=1242116810380743325, journalTitle=Science & Technology Review, columnName=Reviews, runingTitle=null, highlight=null, articleAbstract=The research and development of new reagents are of great significance for organic synthesis. In recent years, some new reagents with universal applicability have been constantly emerging. This article introduces the latest research progress on new reagents for difluoromethylation and trifluoromethylation. Introduced some new sulfur-containing reagents. New reagents DMSO-I2 and DMSO-TsCl for sulfur methylation were introduced detailedly, The sulfur-containing reagent Na2 S2 O4 -TBHP (TBHP, t-butylhydroperoxide) is a new reagent used for selective oxidation of aromatic alcohols to aldehydes which was also known as Wang's reagent., authors=WANG Naixing, authorsList=WANG Naixing, authorCompany=Technical Institute of Physics and Chemistry CAS, Beijing 100190, China, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1242141988942848148, articleId=1242141986916999300, tenantId=1146029695717560320, journalId=1146031591421210625, language=CN, title=有机反应中的含氟与含硫新试剂, columnId=1242134377686180284, journalTitle=科技导报, columnName=综述, runingTitle=null, highlight=null, articleAbstract=新试剂的研究和开发对有机合成具有重要意义。近年来,一些具有普遍适用性的新试剂不断出现。盘点了一些含氟和硫的官能化新试剂,如氟甲基化试剂,二氟甲基化试剂和三氟甲基化试剂,介绍了用于硫甲基化的新试剂DMSO-I2 和DMSO-TsCl试剂,推介了一种用于芳香醇选择性氧化制醛的含硫新试剂Na2 S2 O4 -TBHP。, authors=王乃兴, authorsList=王乃兴, authorCompany=中国科学院理化技术研究所, 北京 100190, correspAuthors=null, authorNote=王乃兴,研究员,罗马尼亚技术科学院院士,研究方向为手性技术、绿色转换等有机合成,电子信箱:nxwang@mail.ipc.ac.cn, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=WdBPkADQIHQfZpLPdh3fvg==, pdfFileSize=2547071, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null)}, authors=[Author(id=1277714749366378946, tenantId=1146029695717560320, journalId=null, articleId=1242141986916999300, orderNo=null, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=null, email=null, emailSecond=null, emailThird=null, correspondingAuthor=null, authorType=null, ext={EN=AuthorExt(id=null, tenantId=null, journalId=1146031591421210625, articleId=1242141986916999300, authorId=1277714749366378946, language=EN, stringName=WANG Naixing, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=null, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=null, tenantId=null, journalId=1146031591421210625, articleId=1242141986916999300, authorId=1277714749366378946, language=CN, stringName=王乃兴, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=null, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=null)], keywords=[Keyword(id=1242141988322091149, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242141986916999300, language=CN, orderNo=1, keyword=新试剂), Keyword(id=1242141988410171534, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242141986916999300, language=CN, orderNo=1, keyword=含氟试剂), Keyword(id=1242141988502446224, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242141986916999300, language=CN, orderNo=1, keyword=含硫试剂), Keyword(id=1242141988619886737, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242141986916999300, language=CN, orderNo=1, keyword=二氟甲基化试剂), Keyword(id=1242141988699578514, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242141986916999300, language=CN, orderNo=1, keyword=三氟甲基化试剂), Keyword(id=1242141988783464595, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242141986916999300, language=CN, orderNo=1, keyword=选择性氧化试剂), Keyword(id=1242141989102235878, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242141986916999300, language=EN, orderNo=1, keyword=new reagents), Keyword(id=1242141989177733351, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242141986916999300, language=EN, orderNo=1, keyword=fluorine-containing reagents), Keyword(id=1242141989253230824, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242141986916999300, language=EN, orderNo=1, keyword=sulfur-containing reagents), Keyword(id=1242141989337116905, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242141986916999300, language=EN, orderNo=1, keyword=difluoromethylation reagents), Keyword(id=1242141989404225770, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242141986916999300, language=EN, orderNo=1, keyword=trifluoromethylation reagents), Keyword(id=1242141989475528939, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242141986916999300, language=EN, orderNo=1, keyword=selective oxidation reagents)], refs=null, funds=null, companyList=null, figs=null, attaches=null, journal=Journal(id=1125356956822126595, delFlag=0, nameCn=科技导报, nameEn=Science & Technology Review, nameHistory1=null, nameHistory2=null, issn=1000-7857, eissn=, cn=11-1421/N, coden=null, periodic=3, language=CN, oaType=0, ccby=null, superviseOffice=null, ownerOffice=null, pubOffice=null, editorOffice=null, officeType=null, aims=null, clcCode=null, officeProv=null, officeCity=null, officeAddr=null, officeZip=null, officeEmail=null, officePhone=null, editDirector=null, officeDirector=null, officeDirectorPhone=null, officeStaffNum=null, officeEmpNum=null, coverPicUrl=wfghvu3bhh/dKxuZ+ucVHA==, journalPrice=null, startedYear=null, abbrevIsoEn=Sci Technol Rev, journalRemark=null, publicationField=null, createdTime=null, updatedTime=1774230116083, createdBy=null, updatedBy=13041195026, firstLetterCn=S, firstLetterEn=S, subjectCode=Natural Sciences, subjectName=自然科学, subjectCodeEn=Natural Sciences, subjectNameEn=null, picCn=wfghvu3bhh/dKxuZ+ucVHA==, picEn=yjSfclmpNm7ihn9NbTZ69g==, jcr=null, cjcr=null, exts=[JournalExt(id=1242774439910290156, language=CN, name=科技导报, nameHistory1=null, nameHistory2=null, managedBy=中国科学技术协会, sponsoredBy=中国科学技术协会, publishedBy=科技导报社, editorOffice=, officeProv=null, officeCity=null, officeAddr=, officeZip=, editDirector=, officeDirector=null, officePhone=null, coverPicUrl=null, journalRemark=, submitArticleUrl=null, websiteUrl=http://www.kjdb.org/CN/home, createdTime=1774230116107, updatedTime=1774230116107, createdBy=13041195026, updatedBy=13041195026, submissionGuidelinesUrl=http://www.kjdb.org/CN/column/column7.shtml, submissionAuthorUrl=https://kjdbauthor.cast.org.cn/webm, submissionEditorUrl=https://kjdbeditor.cast.org.cn/webm/, submissionReviewUrl=https://kjdbauthor.cast.org.cn/webm, submissionCeEditorUrl=https://kjdbeditor.cast.org.cn/webm/, submissionAeEditorUrl=https://kjdbeditor.cast.org.cn/webm/, option={"copyright":""}), JournalExt(id=1242774439960621805, language=EN, name=Science & Technology Review, nameHistory1=null, nameHistory2=null, managedBy=, sponsoredBy=, publishedBy=, editorOffice=, officeProv=null, officeCity=null, officeAddr=, officeZip=, editDirector=, officeDirector=null, officePhone=null, coverPicUrl=null, journalRemark=, submitArticleUrl=null, websiteUrl=http://www.kjdb.org/EN/home, createdTime=1774230116119, updatedTime=1774230116119, createdBy=13041195026, updatedBy=13041195026, submissionGuidelinesUrl=http://www.kjdb.org/EN/column/column7.shtml, submissionAuthorUrl=https://kjdbauthor.manuscriptcloud.com/login, submissionEditorUrl=https://kjdbeditor.manuscriptcloud.com/login, submissionReviewUrl=https://kjdbauthor.manuscriptcloud.com/login, submissionCeEditorUrl=https://kjdbeditor.manuscriptcloud.com/login, submissionAeEditorUrl=https://kjdbeditor.manuscriptcloud.com/login, option={"copyright":""})], databaseList=null, tenantJournalId=1146031591421210625, websiteList=[Website(id=1146104741081231361, webName=null, webTitle=null, webDomain=null, webCopyrigh=null, webIpcNo=null, seoTitle=null, seoKeywords=null, seoDescription=null, tenantJournalId=null, journalId=1146031591421210625, journalNameCn=null, journalNameEn=null, grayFlag=null, tenantId=1146029695717560320, platformId=null, journalGroupId=null, journalGroupNameCn=null, journalGroupNameEn=null, type=1, domain=https://castjournals.cast.org.cn/joweb/kjdb/CN, language=CN, createTime=1751182263881, createBy=18614031015, updateTime=1751778001962, updateBy=18614031015, name=科技导报, tplId=1146099689490845704, title=科技导报, delFlag=0, indexPage=/home, props=[WebsiteProps(id=1148021146403992296, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146104741081231361, code=articleTextType, value=kx, createTime=1751639170504, updateTime=1751639170504, creator=18614031015, updator=18614031015), WebsiteProps(id=1148021146378826469, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146104741081231361, code=banner, value=null, createTime=1751639170498, updateTime=1751639170498, creator=18614031015, updator=18614031015), WebsiteProps(id=1148021146366243556, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146104741081231361, code=logo, value=https://castjournals.cast.org.cn/joweb/kjdb/CN/file/pic?fileId=9GHSf7eGlIPH0Tv/OOdstA==, createTime=1751639170495, updateTime=1751639170495, creator=18614031015, updator=18614031015), WebsiteProps(id=1148021146395603687, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146104741081231361, code=picServerUrl, value=https://castjournals.cast.org.cn/joweb/kjdb/CN/file/pic, createTime=1751639170502, updateTime=1751639170502, creator=18614031015, updator=18614031015), WebsiteProps(id=1148021146387215078, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146104741081231361, code=staticResourcePath, value=https://castjournals.cast.org.cn/joweb/cast_kjdb_cn_619/, createTime=1751639170500, updateTime=1751639170500, creator=18614031015, updator=18614031015)]), Website(id=1146105254833139715, webName=null, webTitle=null, webDomain=null, webCopyrigh=null, webIpcNo=null, seoTitle=null, seoKeywords=null, seoDescription=null, tenantJournalId=null, journalId=1146031591421210625, journalNameCn=null, journalNameEn=null, grayFlag=null, tenantId=1146029695717560320, platformId=null, journalGroupId=null, journalGroupNameCn=null, journalGroupNameEn=null, type=1, domain=https://castjournals.cast.org.cn/joweb/kjdb/EN, language=EN, createTime=1751182386363, createBy=18614031015, updateTime=1753500121937, updateBy=18614031015, name=科技导报, tplId=1146101810881728533, title=Science & Technology Review, delFlag=0, indexPage=/home, props=[WebsiteProps(id=1155838567709528217, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146105254833139715, code=articleTextType, value=kx, createTime=1753502988984, updateTime=1753502988984, creator=18614031015, updator=18614031015), WebsiteProps(id=1155838567692750998, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146105254833139715, code=banner, value=null, createTime=1753502988980, updateTime=1753502988980, creator=18614031015, updator=18614031015), WebsiteProps(id=1155838567688556693, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146105254833139715, code=logo, value=https://castjournals.cast.org.cn/joweb/kjdb/EN/file/pic?fileId=9GHSf7eGlIPH0Tv/OOdstA==, createTime=1753502988979, updateTime=1753502988979, creator=18614031015, updator=18614031015), WebsiteProps(id=1155838567705333912, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146105254833139715, code=picServerUrl, value=https://castjournals.cast.org.cn/joweb/kjdb/EN/file/pic, createTime=1753502988983, updateTime=1753502988983, creator=18614031015, updator=18614031015), WebsiteProps(id=1155838567701139607, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146105254833139715, code=staticResourcePath, value=https://castjournals.cast.org.cn/joweb/cast_kjdb_en_623/, createTime=1753502988982, updateTime=1753502988982, creator=18614031015, updator=18614031015)])], journalTitle=科技导报, weixinUrl=null, journalUrl=null, iacademicId=null, status=1, seqNo=null, journalTitleEn=Science & Technology Review, journalPhotoCn=wfghvu3bhh/dKxuZ+ucVHA==, journalPhotoEn=yjSfclmpNm7ihn9NbTZ69g==, journalFirstLetter=S, journalRecommend=null, journalNew=null, journalCollection=1, jcrJf=null, cjcrJf=0.91, jcrJfStr=null, cjcrJfStr=null, submissionFirstDecision=null, sciSubjectClassification=null, casSubjectClassification=null, citeScore=null, totalCitationFrequency=null, icpCode=null, psCode=null, advertisingLicenseCode=null, copyrightInformation=null, country=null, option=, provinceCode=null, provinceName=null, collectFlag=false, interPubPlatform=null, interPubPlatformUrl=null), detailUrlCn=https://castjournals.cast.org.cn/joweb/kjdb/CN/10.3981/j.issn.1000-7857.2023.11.01761, detailUrlEn=https://castjournals.cast.org.cn/joweb/kjdb/EN/10.3981/j.issn.1000-7857.2023.11.01761, pdfUrlCn=https://castjournals.cast.org.cn/joweb/kjdb/CN/PDF/10.3981/j.issn.1000-7857.2023.11.01761, pdfUrlEn=https://castjournals.cast.org.cn/joweb/kjdb/EN/PDF/10.3981/j.issn.1000-7857.2023.11.01761, aliStartDate=null, aliEndDate=null, collectionFlag=false, citedCount=null, citedUrl=null, previewStatus=0, delFlag=0, hasFullText=0, orderTime=1734019200000, fullTextJson=null, articleText=null, reference=null)
科技导报
| 综述 2024, 42(23): 98-107
有机反应中的含氟与含硫新试剂
全屏
王乃兴
作者信息
New reagents of containing fluorine and sulfur-containing in organic reactions
WANG Naixing
Affiliations
出版时间: 2024-12-13
doi: 10.3981/j.issn.1000-7857.2023.11.01761
文章导航
新试剂的研究和开发对有机合成具有重要意义。近年来,一些具有普遍适用性的新试剂不断出现。盘点了一些含氟和硫的官能化新试剂,如氟甲基化试剂,二氟甲基化试剂和三氟甲基化试剂,介绍了用于硫甲基化的新试剂DMSO-I2 和DMSO-TsCl试剂,推介了一种用于芳香醇选择性氧化制醛的含硫新试剂Na2 S2 O4 -TBHP。
新试剂
/
含氟试剂
/
含硫试剂
/
二氟甲基化试剂
/
三氟甲基化试剂
/
选择性氧化试剂
The research and development of new reagents are of great significance for organic synthesis. In recent years, some new reagents with universal applicability have been constantly emerging. This article introduces the latest research progress on new reagents for difluoromethylation and trifluoromethylation. Introduced some new sulfur-containing reagents. New reagents DMSO-I2 and DMSO-TsCl for sulfur methylation were introduced detailedly, The sulfur-containing reagent Na2 S2 O4 -TBHP (TBHP, t-butylhydroperoxide) is a new reagent used for selective oxidation of aromatic alcohols to aldehydes which was also known as Wang's reagent.
new reagents
/
fluorine-containing reagents
/
sulfur-containing reagents
/
difluoromethylation reagents
/
trifluoromethylation reagents
/
selective oxidation reagents
王乃兴.
有机反应中的含氟与含硫新试剂.
科技导报,
2024
, 42
(23)
: 98
-107
.
DOI: 10.3981/j.issn.1000-7857.2023.11.01761
WANG Naixing.
New reagents of containing fluorine and sulfur-containing in organic reactions[J].
Science & Technology Review ,
2024
, 42
(23)
: 98
-107
.
DOI: 10.3981/j.issn.1000-7857.2023.11.01761
2024年第42卷第23期
PDF下载
331
109
引用本文
BibTeX
文章信息
doi: 10.3981/j.issn.1000-7857.2023.11.01761
接收时间:2023-11-22
首发时间:2025-01-06
出版时间:2024-12-13
收稿日期:2023-11-22
修回日期:2024-09-10
https://castjournals.cast.org.cn/joweb/kjdb/CN/10.3981/j.issn.1000-7857.2023.11.01761
复制链接
引用本文
BibTeX
2种不同金属材料的力学参数
科 Family 属数 Number of genus 种数 Number of species 占总种数比例 Percentage of total species (%) 属 Genus 种数 Number of species 占总种数比例 Percentage of total species (%) 鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78 小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39 多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39 红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87 小菇属 Mycena 11 5.26 光柄菇属 Pluteus 5 2.39 红菇属 Russula 17 8.13 栓菌属 Trametes 5 2.39
关闭全屏
BibTeX
EndNote
RefWorks
TxT