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铝氢化钠储氢性能及其改进方法研究进展
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仝小刚, 李志鹏, 程军锋
科技导报 | 综述 2024,42(4): 84-90
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科技导报 | 综述 2024, 42(4): 84-90
铝氢化钠储氢性能及其改进方法研究进展
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仝小刚, 李志鹏, 程军锋
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Review on hydrogen storage properties and improvement methods of the sodium aluminum hydride
TONG Xiaogang, LI Zhipeng, CHENG Junfeng
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出版时间: 2024-02-28 doi: 10.3981/j.issn.1000-7857.2024.04.008
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配位氢化物NaAlH4具有较高的储氢密度且生产成本低廉,是一种典型的储氢材料;然而,较高的脱氢温度、较慢的氢吸放速率及较差的可逆性限制了其实际应用。作为一种很有前途的车载储氢介质,其储氢性能的改性研究长期备受关注。论述了NaAlH4储氢性能及其改进方法,阐明了添加催化剂和结构纳米化2种基本改进方法的原理,也阐述了理论模拟在研究NaAlH4储氢性能中的重要促进作用。
NaAlH4  /  化学储氢  /  储氢性能  /  催化剂  /  结构纳米化
The complex hydride NaAlH4 is a typical hydrogen-storage material with high hydrogen-storage density and low production cost. However, its practical application is limited due to the high dehydrogenation temperature, slow adsorption and release rate of hydrogen and poor reversibility. As a promising hydrogen-storage medium for automobiles, the improvement of its hydrogen-storage properties has attracted much attention for a long time. In this paper, the hydrogen storage properties of NaAlH4 and its improvement methods are discussed. The principles of two basic improvement methods, namely adding catalyst and structure nanoscaling, are expounded. The important role of theoretical simulation in the study of hydrogen-storage properties of NaAlH4 is also commented. The purpose of this paper is to provide some guidance for further research on hydrogenstorage properties of NaAlH4 and to realize its extensive commercial application in the field of hydrogen-energy economy.
NaAlH4  /  chemical hydrogen storage  /  hydrogen storage property  /  catalyst  /  structure nanoscaling
仝小刚, 李志鹏, 程军锋. 铝氢化钠储氢性能及其改进方法研究进展. 科技导报, 2024 , 42 (4) : 84 -90 . DOI: 10.3981/j.issn.1000-7857.2024.04.008
TONG Xiaogang, LI Zhipeng, CHENG Junfeng. Review on hydrogen storage properties and improvement methods of the sodium aluminum hydride[J]. Science & Technology Review, 2024 , 42 (4) : 84 -90 . DOI: 10.3981/j.issn.1000-7857.2024.04.008
2024年第42卷第4期
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doi: 10.3981/j.issn.1000-7857.2024.04.008
  • 接收时间:2023-07-19
  • 首发时间:2024-04-08
  • 出版时间:2024-02-28
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  • 收稿日期:2023-07-19
  • 修回日期:2023-11-01
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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