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复合材料结构用发泡胶的工艺验证与固化动力学
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科技导报 |专题:航空复合材料技术 2023 , 41 (9) : 58 -66
复合材料结构用发泡胶的工艺验证与固化动力学
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乔海涛1,梁滨1,李喜民2,陈舸3,张立国2
作者信息
    1. 中国航发北京航空材料研究院隐身与涂料研究所,北京 100095
    2. 航空工业第一飞机设计研究院标准材料研究所,西安 710089
    3. 西安飞机工业(集团)有限公司复合材料厂,西安 710089
作者简介:
乔海涛,高级工程师,研究方向为航空航天用结构胶黏剂,电子信箱:15611283016@wo.cn
Process validation and cure kinetics of adhesive foam for composite structural applications
  • QIAO Haitao1, LIANG Bin1, LI Ximin2, CHEN Ge3, ZHANG Liguo2
  • Affiliations
      1. Stealth Materials and Coating Lab, AECC Beijing Institute of Aeronautical Materials, Beijing 100095, China
      2. Standards & Materials Institute, AVIC The First Aircraft Design and Research Institute, Xi'an 710089, China
      3. Composites Materials Factory, AVIC Xi'an Aircraft Industry (Group) Company Ltd., Xi'an 710089, China
    出版时间: 2023-05-13 doi: 10.3981/j.issn.1000-7857.2023.09.007
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    通过动态差示扫描量热分析(DSC)研究了一种高温固化发泡胶的固化工艺和固化动力学。在DSC测试中设定升温速率β为1、2.718、7.389和20 K·min-1,则lnβ等于或近似为0、1、2、3,结合相应的 DSC曲线的峰值温度 Tp,可以简便地确定固化工艺参数并更快速地估算活化能。结合关于热固化、热分解及部分高分子材料结晶的文献数据,进一步证实了 Tp与lnβ往往存在线性关系。利用上述线性关系所获得的相关温度特性关系,可以快速求解动力学数据。
    发泡胶  /  固化工艺  /  活化能  /  Tp-lnβ外推法  /  极限法
    The curing process and cure kinetics of a high-temperature cured adhesive foam have been investigated by dynamic differential scanning calorimetry (DSC) experiments. In the DSC measurements,heating rates of 1, 2.718, 7.389 and 20 K·min-1 were used such that lnβ would be 0, 1, 2 and 3, therefore, values of T1 and ΔT could be easily and quickly determined so as to estimate the apparent activation energy more easily. Linear relationships have been proven to frequently exist between Tp with lnβ by means of a series of reference data from papers about heating cure, thermal decomposition and crystallization of some polymers. The obtained linear equation of Tp versus lnβ can be used to explain some laws for higher or lower of apparent activation energies (Ea), and the apparent activation energy (Ea) can be quickly determined.
    adhesive foam  /  curing process  /  apparent activation energy  /  Tp-lnβ extrapolation method  /  method of mathematical limit
    乔海涛,梁滨,李喜民,陈舸,张立国. 复合材料结构用发泡胶的工艺验证与固化动力学. 科技导报, 2023 , 41 (9) : 58 -66 . DOI: 10.3981/j.issn.1000-7857.2023.09.007
    QIAO Haitao, LIANG Bin, LI Ximin, CHEN Ge, ZHANG Liguo. Process validation and cure kinetics of adhesive foam for composite structural applications[J]. Science & Technology Review, 2023 , 41 (9) : 58 -66 . DOI: 10.3981/j.issn.1000-7857.2023.09.007

      国家重点研发计划项目(2018YFA0703300)

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    doi: 10.3981/j.issn.1000-7857.2023.09.007
    • 接收时间:2022-11-29
    • 首发时间:2023-06-01
    • 出版时间:2023-05-13
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    2种不同金属材料的力学参数

    Family
    属数
    Number of
    genus
    种数
    Number of
    species
    占总种数比例
    Percentage of
    total species (%)

    Genus
    种数
    Number of
    species
    占总种数比例
    Percentage of total
    species (%)
    鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
    小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
    多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
    红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
    小菇属 Mycena 11 5.26
    光柄菇属 Pluteus 5 2.39
    红菇属 Russula 17 8.13
    栓菌属 Trametes 5 2.39
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