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光电催化分解水和还原CO2研究进展
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科技导报 | 专题:太阳燃料 2020,38(23): 75-84
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光电催化分解水和还原CO2研究进展
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丁春梅, 姚婷婷, 李灿
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    中国科学院大连化学物理研究所, 催化基础国家重点实验室, 洁净能源国家实验室(筹), 大连 116023

通讯作者:

李灿(通信作者),研究员,中国科学院院士,研究方向为催化材料、催化反应和光谱表征,电子信箱:canli@dicp.ac.cn
Progress of photoelectrocatalytic water splitting and CO2 reduction
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出版时间: 2020-12-13 doi: 10.3981/j.issn.1000-7857.2020.23.008
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介绍了光电催化(PEC)分解水和还原CO2的基本原理、研究进展。探讨了提高PEC效率的关键策略,主要包括通过能带调控、形貌控制和敏化提高光吸收,通过助催化剂促进表面反应,以及通过构建局部偶极或异质电场、形貌调控和界面修饰促进电荷分离与传输等。
光电催化分解水  /  CO2还原  /  光吸收  /  电荷分离  /  助催化剂  /  界面
Photoelectrocatalytic (PEC) water splitting for H2 production and CO2 reduction for fuel production are important ways for solar energy conversion and utilization. However, the PEC efficiency is limited by problems such as poor light absorption, high overpotential and sluggish kinetics of surface reaction, and serious recombination of photogenerated carriers. Herein, we describe the principles of PEC water splitting and CO2 reduction, recent progress and strategies on increasing the PEC efficiency, including enhancing light absorption via energy band engineering, morphology control and sensitizing strategy, promoting surface reaction via loading cocatalyst, enhancing charge separation and transfer via introducing local dipole and heterojunction electric field, morphology control, interface engineering, etc.
photoelectrocatalytic water splitting  /  CO2 reduction  /  light absorption  /  charge separation  /  cocatalyst  /  interface
丁春梅, 姚婷婷, 李灿. 光电催化分解水和还原CO2研究进展. 科技导报, 2020 , 38 (23) : 75 -84 . DOI: 10.3981/j.issn.1000-7857.2020.23.008
DING Chunmei, YAO Tingting, LI Can. Progress of photoelectrocatalytic water splitting and CO2 reduction[J]. Science & Technology Review, 2020 , 38 (23) : 75 -84 . DOI: 10.3981/j.issn.1000-7857.2020.23.008
2020年第38卷第23期
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doi: 10.3981/j.issn.1000-7857.2020.23.008
  • 接收时间:2020-09-01
  • 首发时间:2021-01-14
  • 出版时间:2020-12-13
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  • 收稿日期:2020-09-01
  • 修回日期:2020-09-24
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通讯作者:

李灿(通信作者),研究员,中国科学院院士,研究方向为催化材料、催化反应和光谱表征,电子信箱:canli@dicp.ac.cn
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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