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2. School of Chemical Engineering, Qinghai Normal University, Xining 810008, China;
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新一代环保型增塑剂柠檬酸三丁酯绿色合成进展
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科技导报 |科技引领 2019 , 37 (12) : 79 -85
新一代环保型增塑剂柠檬酸三丁酯绿色合成进展
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徐永强1, 高强1,2, 王海燕3, 商红岩1, 刘晨光1
作者信息
    1. 中国石油大学(华东)重质油国家重点实验室, CNPC催化重点实验室, 青岛 266555;
    2. 青海师范大学化学化工学院, 西宁 810008;
    3. 中国石油大学(华东)计算机与通信学院, 青岛 266555
作者简介:
徐永强,副教授,研究方向为有机合成、固体有机酸催化剂、石油馏分加氢脱硫催化剂,电子信箱:xuyq@upc.edu.cn
Research progress of the synthesis of green plasticizer tributyl citrate catalyzed by solid acid
  • XU Yongqiang1, GAO Qiang1,2, WANG Haiyan3, SHANG Hongyan1, LIU Chenguang1
  • Affiliations
      1. State Key Laboratory of Heavy Oil Processing, CNPC Key Laboratory of Catalysis, China University of Petroleum(East China), Qingdao 266555, China;
      2. School of Chemical Engineering, Qinghai Normal University, Xining 810008, China;
      3. College of Computer & Communication Engineering, China University of Petroleum(East China), Qingdao 266555, China
    出版时间: 2019-06-28 doi: 10.3981/j.issn.1000-7857.2019.12.014
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    柠檬酸三丁酯是一种无毒、绿色环保型的增塑剂,是替代目前广泛使用的有毒增塑剂的新一代环保型增塑剂之一。概述了柠檬酸三丁酯的主要性质及主要合成方法,对可用于制备柠檬酸三丁酯的固体酸催化剂进行了分类,总结了其在酯化反应中的应用。分析认为,有机固体酸催化剂是制备柠檬酸三丁酯的合适催化剂。
    柠檬酸三丁酯  /  增塑剂  /  催化剂
    The tributyl citrate is a non-toxic, green and environmentally friendly plasticizer, one of the new generation plasticizers to replace the widely used toxic plasticizers, and has become a research hotspot. The main properties of the tributyl citrate are listed in detail, and the main synthesis methods of the tributyl citrate are reviewed. The solid acid catalysts for the synthesis of the tributyl citrate are classified and their applications in the esterification are summarized. It is concluded that the organic solid acid catalyst is a suitable catalyst for the preparation of the tributyl citrate.
    tributyl citrate  /  plasticizer  /  catalyst
    徐永强, 高强, 王海燕, 商红岩, 刘晨光. 新一代环保型增塑剂柠檬酸三丁酯绿色合成进展. 科技导报, 2019 , 37 (12) : 79 -85 . DOI: 10.3981/j.issn.1000-7857.2019.12.014
    XU Yongqiang, GAO Qiang, WANG Haiyan, SHANG Hongyan, LIU Chenguang. Research progress of the synthesis of green plasticizer tributyl citrate catalyzed by solid acid[J]. Science & Technology Review, 2019 , 37 (12) : 79 -85 . DOI: 10.3981/j.issn.1000-7857.2019.12.014

      国家自然科学基金面上项目(21376267)

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    doi: 10.3981/j.issn.1000-7857.2019.12.014
    • 接收时间:2019-05-20
    • 首发时间:2019-06-24
    • 出版时间:2019-06-28
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    • 修回日期:2019-06-10
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    属数
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    Number of
    species
    占总种数比例
    Percentage of
    total species (%)

    Genus
    种数
    Number of
    species
    占总种数比例
    Percentage of total
    species (%)
    鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
    小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
    多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
    红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
    小菇属 Mycena 11 5.26
    光柄菇属 Pluteus 5 2.39
    红菇属 Russula 17 8.13
    栓菌属 Trametes 5 2.39
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