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科技导报
| 科技引领 2019, 37(12): 79-85
新一代环保型增塑剂柠檬酸三丁酯绿色合成进展
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徐永强1 , 高强1,2 , 王海燕3 , 商红岩1 , 刘晨光1
作者信息
1. 中国石油大学(华东)重质油国家重点实验室, CNPC催化重点实验室, 青岛 266555;
2. 青海师范大学化学化工学院, 西宁 810008;
3. 中国石油大学(华东)计算机与通信学院, 青岛 266555
Research progress of the synthesis of green plasticizer tributyl citrate catalyzed by solid acid
Affiliations
出版时间: 2019-06-28
doi: 10.3981/j.issn.1000-7857.2019.12.014
文章导航
柠檬酸三丁酯是一种无毒、绿色环保型的增塑剂,是替代目前广泛使用的有毒增塑剂的新一代环保型增塑剂之一。概述了柠檬酸三丁酯的主要性质及主要合成方法,对可用于制备柠檬酸三丁酯的固体酸催化剂进行了分类,总结了其在酯化反应中的应用。分析认为,有机固体酸催化剂是制备柠檬酸三丁酯的合适催化剂。
The tributyl citrate is a non-toxic, green and environmentally friendly plasticizer, one of the new generation plasticizers to replace the widely used toxic plasticizers, and has become a research hotspot. The main properties of the tributyl citrate are listed in detail, and the main synthesis methods of the tributyl citrate are reviewed. The solid acid catalysts for the synthesis of the tributyl citrate are classified and their applications in the esterification are summarized. It is concluded that the organic solid acid catalyst is a suitable catalyst for the preparation of the tributyl citrate.
tributyl citrate
/
plasticizer
/
catalyst
徐永强, 高强, 王海燕, 商红岩, 刘晨光.
新一代环保型增塑剂柠檬酸三丁酯绿色合成进展.
科技导报,
2019
, 37
(12)
: 79
-85
.
DOI: 10.3981/j.issn.1000-7857.2019.12.014
XU Yongqiang, GAO Qiang, WANG Haiyan, SHANG Hongyan, LIU Chenguang.
Research progress of the synthesis of green plasticizer tributyl citrate catalyzed by solid acid[J].
Science & Technology Review ,
2019
, 37
(12)
: 79
-85
.
DOI: 10.3981/j.issn.1000-7857.2019.12.014
2019年第37卷第12期
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文章信息
doi: 10.3981/j.issn.1000-7857.2019.12.014
接收时间:2019-05-20
首发时间:2019-06-24
出版时间:2019-06-28
收稿日期:2019-05-20
修回日期:2019-06-10
https://castjournals.cast.org.cn/joweb/kjdb/CN/10.3981/j.issn.1000-7857.2019.12.014
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2种不同金属材料的力学参数
科 Family 属数 Number of genus 种数 Number of species 占总种数比例 Percentage of total species (%) 属 Genus 种数 Number of species 占总种数比例 Percentage of total species (%) 鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78 小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39 多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39 红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87 小菇属 Mycena 11 5.26 光柄菇属 Pluteus 5 2.39 红菇属 Russula 17 8.13 栓菌属 Trametes 5 2.39
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