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2. Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
3. Beijing Engineering Research Center of Printed Electronics, Beijing Institute of Graphic Communication, Beijing 102600, China, fund=null, authors=MA Ying1, LIU Lu1, AN Boxing1, LI Fengyu2, DING Dan3, LIU Ruping3, SONG Yanlin2, authorsList=MA Ying, LIU Lu, AN Boxing, LI Fengyu, DING Dan, LIU Ruping, SONG Yanlin), CN=ArticleExt(id=1242136797447270512, articleId=1242136795513696341, tenantId=1146029695717560320, journalId=1146031591421210625, language=CN, title=氧化石墨烯墨水的制备及直写图案化, columnId=1146540929516700224, journalTitle=科技导报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=采用改进的Hummers法制备宽度分布范围为30~70 μm的大尺寸氧化石墨烯及其墨水,并通过直写打印实验,研究了最佳打印条件和氧化石墨烯墨水直写图案化。结果表明,当氧化石墨烯浓度为15 mg/mL、打印压力为70 kPa、线速度为3 mm/s时,打印线条流畅,形貌精细可控;还原剂为15%氢碘酸、还原时间为3 h时,打印线条的还原程度最高,且电性能最佳,电导率可达4.40×104 S/m,远超过现有打印技术的石墨烯图案电导率;实现了氧化石墨烯墨水在亲水聚对苯二甲酸乙二醇酯(PET)、聚二甲基硅氧烷(PDMS)、玻璃、硅片等多种柔性和非柔性基底上的图案化直写打印,且经还原处理的氧化石墨烯图案可作为连接导线实现发光二极管的集成,对于石墨烯基印刷电子器件的发展具有重要意义。, correspAuthors=null, authorNote=马颖,副教授,研究方向为光电功能材料与器件,电子信箱:may171@iccas.ac.cn, correspAuthorsNote=宋延林(通信作者),研究员,研究方向为纳米材料绿色印刷,电子信箱:ylsong@iccas.ac.cn, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=6y35qhBOMON23tAT1uw7wg==, pdfFileSize=2263610, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, authorCompany=1. 沈阳建筑大学材料科学与工程学院, 沈阳 110168;
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氧化石墨烯墨水的制备及直写图案化
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科技导报 | 研究论文 2018, 36(7): 88-94
氧化石墨烯墨水的制备及直写图案化
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马颖1, 刘璐1, 安博星1, 李风煜2, 丁丹3, 刘儒平3, 宋延林2
作者信息
    1. 沈阳建筑大学材料科学与工程学院, 沈阳 110168;
    2. 中国科学院化学研究所绿色印刷重点实验室, 北京 100190;
    3. 北京印刷学院北京市印刷电子工程技术研究中心, 北京 102600

通讯作者:

宋延林(通信作者),研究员,研究方向为纳米材料绿色印刷,电子信箱:ylsong@iccas.ac.cn
Fabrication and patterning of graphene oxide ink with direct ink writing
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出版时间: 2018-04-13 doi: 10.3981/j.issn.1000-7857.2018.07.013
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采用改进的Hummers法制备宽度分布范围为30~70 μm的大尺寸氧化石墨烯及其墨水,并通过直写打印实验,研究了最佳打印条件和氧化石墨烯墨水直写图案化。结果表明,当氧化石墨烯浓度为15 mg/mL、打印压力为70 kPa、线速度为3 mm/s时,打印线条流畅,形貌精细可控;还原剂为15%氢碘酸、还原时间为3 h时,打印线条的还原程度最高,且电性能最佳,电导率可达4.40×104 S/m,远超过现有打印技术的石墨烯图案电导率;实现了氧化石墨烯墨水在亲水聚对苯二甲酸乙二醇酯(PET)、聚二甲基硅氧烷(PDMS)、玻璃、硅片等多种柔性和非柔性基底上的图案化直写打印,且经还原处理的氧化石墨烯图案可作为连接导线实现发光二极管的集成,对于石墨烯基印刷电子器件的发展具有重要意义。
氧化石墨烯墨水  /  直写打印  /  印刷电子  /  图案化
Giant graphene oxide (GGO) with radial size distribution of 30~70 μm is fabricated using the modified Hummers method, and graphene oxide ink is prepared. Through direct ink writing, the optimal printing parameters and patterning of graphene oxide ink are realized. When graphene oxide with a concentration of 15 mg/mL is printed at 70 kPa and 3 mm/s, the printing line is smooth and its morphology is fine and controllable. When the printing line is reduced by 15% hydroiodic acid for 3 h, its reduction degree is the highest and has the best electrical performance, with a conductivity up to 4.40×104 S/m, which is much higher than that of the graphene patterned by the existing printing technology. Patterning of graphene oxide ink on various flexible and non-flexible substrates, such as PET, PDMS, glass and silicon wafers is alao successfully achieved. Reduced graphene oxide pattern can be used as a connecting conductor to realize the integration of LED, which is of great significance for the development of graphene based printed electronic devices.
graphene oxide ink  /  direct ink writing  /  printed electronics  /  patterning
马颖, 刘璐, 安博星, 李风煜, 丁丹, 刘儒平, 宋延林. 氧化石墨烯墨水的制备及直写图案化. 科技导报, 2018 , 36 (7) : 88 -94 . DOI: 10.3981/j.issn.1000-7857.2018.07.013
MA Ying, LIU Lu, AN Boxing, LI Fengyu, DING Dan, LIU Ruping, SONG Yanlin. Fabrication and patterning of graphene oxide ink with direct ink writing[J]. Science & Technology Review, 2018 , 36 (7) : 88 -94 . DOI: 10.3981/j.issn.1000-7857.2018.07.013
2018年第36卷第7期
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doi: 10.3981/j.issn.1000-7857.2018.07.013
  • 接收时间:2017-11-02
  • 首发时间:2018-04-27
  • 出版时间:2018-04-13
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  • 收稿日期:2017-11-02
  • 修回日期:2018-02-23
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通讯作者:

宋延林(通信作者),研究员,研究方向为纳米材料绿色印刷,电子信箱:ylsong@iccas.ac.cn
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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