Article(id=1242136555318485297, tenantId=1146029695717560320, journalId=1146031591421210625, issueId=1242136541515030780, articleNumber=null, orderNo=14, doi=10.3981/j.issn.1000-7857.2017.23.009, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1471449600000, receivedDateStr=2016-08-18, revisedDate=1504454400000, revisedDateStr=2017-09-04, acceptedDate=null, acceptedDateStr=null, onlineDate=1513392153367, onlineDateStr=2017-12-16, pubDate=1513094400000, pubDateStr=2017-12-13, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1513392153367, onlineIssueDateStr=2017-12-16, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1774078032564, creator=sys-migrate, updateTime=1774078032566, updator=sys-migrate, issue=Issue{id=1242136541515030780, tenantId=1146029695717560320, journalId=1146031591421210625, year='2017', volume='35', issue='23', pageStart='1', pageEnd='112', issueExtLink='null', onlineDate='null', pubDate='1513094400000', pubDateStr='2017-12-13', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=3, issueType=-1, specialIssue=null, createTime=1774078029275, creator='sys-migrate', updateTime=1774078029275, updator='sys-migrate', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=58, endPage=61, ext={EN=ArticleExt(id=1242136558497767750, articleId=1242136555318485297, tenantId=1146029695717560320, journalId=1146031591421210625, language=EN, title=Construction and characterization of spiro[indoline-3,3'-pyrrolizin]-2-one skeleton, columnId=1242116080374710456, journalTitle=Science & Technology Review, columnName=Articles, runingTitle=null, highlight=null, articleAbstract=The title compound spiro[indoline-3,3'-pyrrolizin]-2-one C₂₇H₂₄ClN₃O₂ is synthesized by the one-pot multicomponent reaction of chalcone, 5-methylisatin and proline in trace amounts of methanol under stirring at 60℃. Its structure is determined by single crystal X-ray diffraction. The crystal is monoclinic, space group P₂(1)/c, with M_r=504.01, a=0.84907(6) nm, b=1.07072(9) nm, c=2.9121(4) nm, V=2.6415 (5) nm³, Z=4, D_c=1.267 mg/m³, μ=0.180 mm^-1, and F(000)=1064. The structure is solved by direct methods and refined by full-matrix least squares method to the final R=0.0657 and ω_R=0.1376. X-ray analysis reveals that the newly formed ring of tetrahydropyrrole in the crystal structure is of envelope conformation., authors=XU Linlin, ZHU Xiaotong, ZHANG Jinpeng, authorsList=XU Linlin, ZHU Xiaotong, ZHANG Jinpeng, authorCompany=School of Public Health, Xuzhou Medical University, Xuzhou 221004, China, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=7Dc3VgGWT3ZNlSOmq5vCCQ==, pdfFileSize=737015, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1242136557658910981, articleId=1242136555318485297, tenantId=1146029695717560320, journalId=1146031591421210625, language=CN, title=螺[吲哚-3,3'-吡咯嗪]-2-酮骨架构建及结构表征, columnId=1146540929516700224, journalTitle=科技导报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=以查尔酮、5-甲基靛红和脯氨酸为原料，微量的甲醇作溶剂，多组分一步合成得到螺[吲哚-3，3'-吡咯嗪]-2-酮化合物C₂₇H₂₄ClN₃O₂。其结构通过单晶X射线衍射法确定，晶体属单斜晶系，空间群P₂（1）/c，分子量M_r=504.01，晶胞参数a=0.84907（6）nm，b=1.07072（9）nm，c=2.9121（4）nm，V=2.6415（5）nm³，Z=4，晶胞密度D_c=1.267 mg/m³，吸收系数μ=0.180 mm^-1，单胞中电子的数目F（000）=1064。晶体结构用直接法解出，经全矩阵最小二乘法对原子参数进行修正，最终的偏离因子为R=0.0657，ω_R=0.1376。在晶体结构中新形成的四氢吡咯环为信封式构象。, authors=徐琳琳, 朱晓彤, 张金鹏, authorsList=徐琳琳, 朱晓彤, 张金鹏, authorCompany=徐州医科大学公共卫生学院, 徐州 221004, correspAuthors=null, authorNote=徐琳琳,中级实验师,研究方向为抗肿瘤药物活性,电子信箱:xulinlin16@163.com, correspAuthorsNote=张金鹏(通信作者),高级实验师,研究方向为含氮杂环化合物的合成及分析,电子信箱:xiaopangpeng@126.com, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=bgUIQyKhrMuKuGcEmcgjkQ==, pdfFileSize=737015, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, 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