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科技导报
| 专题论文 2016, 34(19): 127-131
木材基银钛复合薄膜的制备及其可见光降解甲醛
全屏
高丽坤, 李坚
作者信息
通讯作者:
李坚(通信作者),中国工程院院士,研究方向为木材功能性改良及生物质基复合材料,电子信箱:nefulijian@163.com
Preparation of Ag/Ti composite film based on wood substrate and the formaldehyde degradation under visible light irradiation
GAO Likun, LI Jian
Affiliations
出版时间: 2016-10-13
doi: 10.3981/j.issn.1000-7857.2016.19.022
文章导航
以水热合成法和银镜反应,以木材为基质,制备了微纳米结构的二氧化钛和纳米银复合薄膜。采用场发射电子扫描电镜(SEM)、X射线衍射仪(XRD)、透射电镜(TEM)、光电子能谱仪(XPS)和紫外光分光光度计(UV-vis),对制备的银钛复合薄膜负载的木材基材料微观形貌、晶型结构、化学状态及光学性能进行表征,通过实验证明该银钛复合薄膜负载的木材在可见光照射下具有降解甲醛的作用。结果表明,在可见光照射下,相比单纯的二氧化钛薄膜负载的木材,银钛复合薄膜负载的木材降解甲醛性能显著提升。在此异质结构的体系中,由于银的费米能级低于二氧化钛的导带能级,因此银纳米粒子可作为电子捕获中心以控制电子和空穴的分离,从而提高材料的光催化性能。
木材基材料
/
银钛复合薄膜
/
光催化
/
气体甲醛
/
可见光降解
The micro-nano Ag-TiO2 composite film on the surface of wood substrate is fabricated using the hydrothermal synthesis and silver mirror method. The morphological feature, the crystal form, the chemical state and the optical properties of the as-prepared TiO 2/Agcoated wood are analyzed using the field emission scanning electron microscopy(FESEM), the X-ray diffraction(XRD), the transmission electron microscopy(TEM), the X-ray photoelectron spectroscopy(XPS) and the UV-vis diffusion reflectance spectroscopy(UV-vis). Meanwhile, it is shown that the TiO2 /Ag-coated wood has the property of formaldehyde degradation under the visible light irradiation. In this heterostructured system, due to the fact that the Fermi level of Ag is lower than the conduction band of TiO2 , the Ag nanoparticles can act as the electron scavenging centers to cause the electron and hole separation, leading to the enhanced photo-catalytic activity of TiO 2. In this paper, a new material for formaldehyde degradation is prepared, and the functional wood-based materials have great potential applications in new-style functional materials.
wood-based materials
/
Ag-TiO2 composite film
/
photo-catalytic
/
gas formaldehyde
/
degradation under visible light irradiation
高丽坤, 李坚.
木材基银钛复合薄膜的制备及其可见光降解甲醛.
科技导报,
2016
, 34
(19)
: 127
-131
.
DOI: 10.3981/j.issn.1000-7857.2016.19.022
GAO Likun, LI Jian.
Preparation of Ag/Ti composite film based on wood substrate and the formaldehyde degradation under visible light irradiation[J].
Science & Technology Review ,
2016
, 34
(19)
: 127
-131
.
DOI: 10.3981/j.issn.1000-7857.2016.19.022
2016年第34卷第19期
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引用本文
BibTeX
文章信息
doi: 10.3981/j.issn.1000-7857.2016.19.022
接收时间:2015-12-15
首发时间:2016-10-21
出版时间:2016-10-13
收稿日期:2015-12-15
修回日期:2016-01-11
通讯作者:
李坚(通信作者),中国工程院院士,研究方向为木材功能性改良及生物质基复合材料,电子信箱:nefulijian@163.com
https://castjournals.cast.org.cn/joweb/kjdb/CN/10.3981/j.issn.1000-7857.2016.19.022
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2种不同金属材料的力学参数
科 Family 属数 Number of genus 种数 Number of species 占总种数比例 Percentage of total species (%) 属 Genus 种数 Number of species 占总种数比例 Percentage of total species (%) 鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78 小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39 多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39 红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87 小菇属 Mycena 11 5.26 光柄菇属 Pluteus 5 2.39 红菇属 Russula 17 8.13 栓菌属 Trametes 5 2.39
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