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微弧氧化法制备镁基羟基磷灰石/碳纳米管复合生物涂层及其性能研究
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夏承森, 温翠莲, 詹晓章, 黄小桂, 罗立津
科技导报 | 专题论文 2016,34(8): 60-66
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科技导报 | 专题论文 2016, 34(8): 60-66
微弧氧化法制备镁基羟基磷灰石/碳纳米管复合生物涂层及其性能研究
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夏承森, 温翠莲, 詹晓章, 黄小桂, 罗立津
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温翠莲,副教授,研究方向为金属基生物材料,电子信箱:clwen@fzu.edu.cn
Synthesis and properties of hydroxyapatite/CNTs composite coating on magnesium alloy by micro-arc oxidation
XIA Chengsen, WEN Cuilian, ZHAN Xiaozhang, HUANG Xiaogui, LUO Lijin
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出版时间: 2016-04-28
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通过化学沉淀法制备了羟基磷灰石/碳纳米管纳米(HA/CNTs)复合粉体,并作为电解液的添加剂,采用微弧氧化方法(MAO)制备了镁合金表面MAO/HA/CNTs 复合活性涂层。分别采用扫描电子显微镜(SEM)、X 射线衍射分析(XRD)、傅里叶红外光谱(FTIR)和电化学工作站,研究所制备的复合粉体的形貌和物相组成、复合粉体对微弧氧化涂层表面形貌和在模拟体液(SBF)中耐腐蚀性能和生物活性的影响。结果表明,所制备的HA/CNTs 复合粉体结晶良好,无其他杂质相;复合粉体在微弧氧化过程中沉积在样品表面,对微弧氧化涂层起到封孔作用。MAO/HA/CNTs 样品的腐蚀电位为-1.50 V,经过30 天的SBF 浸泡后,表面沉积了大量的亚微米级别的颗粒沉积物,相比于镁基体和MAO 样品具有更好的生物活性和耐腐蚀性。
羟基磷灰石  /  碳纳米管  /  镁合金  /  微弧氧化  /  生物涂层
MAO/HA/CNTs composite coating is synthesized on magnesium alloy by micro arc oxidation (MAO) with Hydroxyapatite/CNTs (HA/CNTs) nano composite powders as additives, which is obtained by chemical precipitation method. SEM, XRD, FTIR and electrochemical workstation are adopted to investigate morphology and phase composition of as-prepared composite coating, corrosion resistance and bioactivities of samples in SBF solutions. The results show that the prepared HA/CNTs composite powders are well crystallized and without any impurities. The HA/CNTs can be deposited on the surface of samples successfully during MAO process, sealing the holes of MAO coating. Moreover, the corrosion potential of MAO/HA/CNTs modified samples is -1.50 V; the surface is deposited by a large number of submicron scale particles after soaking in SBF for 30 days, which shows better biological activity and higher corrosion resistance compared with Mg substrate and MAO modified samples.
hydroxyapatite  /  CNTs  /  magnesium alloy  /  micro-arc oxidation  /  bioactive coating
夏承森, 温翠莲, 詹晓章, 黄小桂, 罗立津. 微弧氧化法制备镁基羟基磷灰石/碳纳米管复合生物涂层及其性能研究. 科技导报, 2016 , 34 (8) : 60 -66 .
XIA Chengsen, WEN Cuilian, ZHAN Xiaozhang, HUANG Xiaogui, LUO Lijin. Synthesis and properties of hydroxyapatite/CNTs composite coating on magnesium alloy by micro-arc oxidation[J]. Science & Technology Review, 2016 , 34 (8) : 60 -66 .
2016年第34卷第8期
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  • 接收时间:2015-12-14
  • 首发时间:2016-04-28
  • 出版时间:2016-04-28
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  • 收稿日期:2015-12-14
  • 修回日期:2015-01-11
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温翠莲,副教授,研究方向为金属基生物材料,电子信箱:clwen@fzu.edu.cn
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Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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