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2. School of Civil & Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China;
3. Research Institute of Petroleum Exploration & Production, Sinopec Zhongyuan Oilfield Company, Puyang 457001, China;
4. School of Petrochemical & Energy Engineering, Zhejiang Ocean University, Zhoushan 316022, China, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=RCVnwKB9BczQogKExquaDQ==, pdfFileSize=3971807, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1242134454253204267, articleId=1242134451623371518, tenantId=1146029695717560320, journalId=1146031591421210625, language=CN, title=纳微米聚合物颗粒驱油剂的表征及性能评价, columnId=1242116809164390686, journalTitle=科技导报, columnName=综述文章, runingTitle=null, highlight=null, articleAbstract=蒸馏沉淀聚合法制备AM/AA/MMA 聚合物颗粒,利用傅里叶变换红外光谱仪、扫描电子显微镜和激光粒度仪进行表征,研究NaCl 质量浓度对聚合物颗粒水化膨胀性能的影响及水化时间对聚合物颗粒运移封堵性能的影响,并在不同渗透率的岩心中进行驱油实验。实验结果表明,AM/AA/MMA 聚合物颗粒为规则球形,干球粒径约为500 nm。随着水化时间增加,聚合物颗粒粒径逐渐增加,水化时间增至200 h 后,粒径基本不再增加。随着NaCl 质量浓度增加,聚合物颗粒的膨胀倍数逐渐减小,质量浓度由5 g/L 增至20 g/L,膨胀倍数减小了1.01。随着水化时间增加,聚合物颗粒对岩心的封堵作用增强,水化时间由24 h 增至120 h,岩心封堵率增大了40.62%。注入0.5 倍孔隙体积、质量浓度为1.5 g/L 的聚合物颗粒溶液段塞,可平均提高采收率9%以上,随着渗透率增加,提高的采收率逐渐增加,当渗透率大于50×10-3 μm2 后,提高的采收率基本不变。, authors=龙运前1 , 朱维耀2 , 王明3 , 韩宏彦2 , 黄小荷4 , authorsList=龙运前, 朱维耀, 王明, 韩宏彦, 黄小荷, authorCompany=1. 浙江海洋学院创新应用研究院, 舟山 316022;
2. 北京科技大学土木与环境工程学院, 北京 100083;
3. 中国石化中原油田分公司石油勘探开发研究院, 濮阳 457001;
4. 浙江海洋学院石化与能源工程学院, 舟山 316022, correspAuthors=null, authorNote=龙运前,助理研究员,研究方向为化学驱提高采收率技术,电子信箱:longyunqian@163.com, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=0KdJ6WiUqwNednushcEOPA==, pdfFileSize=3971807, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=国家重点基础研究发展计划(973计划)项目(2013CB228002);国家自然科学基金项目(50934003,11472246);浙江海洋学院科研启动项目)}, authors=null, keywords=[Keyword(id=1242134453666001698, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242134451623371518, language=CN, orderNo=1, keyword=蒸馏沉淀聚合), Keyword(id=1242134453791830819, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242134451623371518, language=CN, orderNo=1, keyword=纳微米聚合物颗粒), 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科技导报
| 综述文章 2016, 34(2): 156-161
纳微米聚合物颗粒驱油剂的表征及性能评价
全屏
龙运前1 , 朱维耀2 , 王明3 , 韩宏彦2 , 黄小荷4
作者信息
1. 浙江海洋学院创新应用研究院, 舟山 316022;
2. 北京科技大学土木与环境工程学院, 北京 100083;
3. 中国石化中原油田分公司石油勘探开发研究院, 濮阳 457001;
4. 浙江海洋学院石化与能源工程学院, 舟山 316022
Characterization and performance evaluation for nano/micron-sized polymer particles flooding agent
Affiliations
出版时间: 2016-01-28
doi: 10.3981/j.issn.1000-7857.2016.2.025
文章导航
蒸馏沉淀聚合法制备AM/AA/MMA 聚合物颗粒,利用傅里叶变换红外光谱仪、扫描电子显微镜和激光粒度仪进行表征,研究NaCl 质量浓度对聚合物颗粒水化膨胀性能的影响及水化时间对聚合物颗粒运移封堵性能的影响,并在不同渗透率的岩心中进行驱油实验。实验结果表明,AM/AA/MMA 聚合物颗粒为规则球形,干球粒径约为500 nm。随着水化时间增加,聚合物颗粒粒径逐渐增加,水化时间增至200 h 后,粒径基本不再增加。随着NaCl 质量浓度增加,聚合物颗粒的膨胀倍数逐渐减小,质量浓度由5 g/L 增至20 g/L,膨胀倍数减小了1.01。随着水化时间增加,聚合物颗粒对岩心的封堵作用增强,水化时间由24 h 增至120 h,岩心封堵率增大了40.62%。注入0.5 倍孔隙体积、质量浓度为1.5 g/L 的聚合物颗粒溶液段塞,可平均提高采收率9%以上,随着渗透率增加,提高的采收率逐渐增加,当渗透率大于50×10-3 μm2 后,提高的采收率基本不变。
蒸馏沉淀聚合
/
纳微米聚合物颗粒
/
水化膨胀
/
运移封堵
/
采收率
AM/AA/MMA nano/micron-sized polymer particles are prepared by distillation precipitation polymerization method and characterized using Fourier transform infrared spectroscopy, scanning electron microscopy and laser particle size instrument. The effect of NaCl mass concentration on the hydration expansion property of polymer particles and the effect of hydration time on the migration plugging property of polymer particles are investigated. The oil displacement experiments are carried out in different permeability cores. The experimental results show that AM/AA/MMA polymer particles are regular spherical and the dry particle size is about 500 nm. The polymer particle size gradually increases with the increase of hydration time; But after 200 h, the size of the particle is no longer increased. The expansion ratio of polymer particles decreases gradually with the increase of NaCl mass concentration; when the NaCl mass concentration increases from 5 g/L to 20 g/L, the expansion ratio is reduced by 1.01. The pugging effect of polymer particles on core may enhance with the increase of hydration time; From 24 h to 120 h, the core plugging rate is increased by 40.62%. The injection of 0.5 times pore volume polymer particles solution with 1.5 g/L mass concentration can increase by an average of more than 9% of the recovery rate. With the increase of permeability, the enhanced oil recovery increases gradually. But the enhanced oil recovery will remain constant when the permeability is higher than 50×10-3 μm2 .
distillation precipitation polymerization
/
nano/micron-sized polymer particles
/
hydration expansion
/
migration plugging
/
recovery rate
龙运前, 朱维耀, 王明, 韩宏彦, 黄小荷.
纳微米聚合物颗粒驱油剂的表征及性能评价.
科技导报,
2016
, 34
(2)
: 156
-161
.
DOI: 10.3981/j.issn.1000-7857.2016.2.025
LONG Yunqian, ZHU Weiyao, WANG Ming, HAN Hongyan, HUANG Xiaohe.
Characterization and performance evaluation for nano/micron-sized polymer particles flooding agent[J].
Science & Technology Review ,
2016
, 34
(2)
: 156
-161
.
DOI: 10.3981/j.issn.1000-7857.2016.2.025
2016年第34卷第2期
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BibTeX
文章信息
doi: 10.3981/j.issn.1000-7857.2016.2.025
接收时间:2015-06-16
首发时间:2016-02-04
出版时间:2016-01-28
收稿日期:2015-06-16
修回日期:2015-11-04
https://castjournals.cast.org.cn/joweb/kjdb/CN/10.3981/j.issn.1000-7857.2016.2.025
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2种不同金属材料的力学参数
科 Family 属数 Number of genus 种数 Number of species 占总种数比例 Percentage of total species (%) 属 Genus 种数 Number of species 占总种数比例 Percentage of total species (%) 鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78 小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39 多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39 红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87 小菇属 Mycena 11 5.26 光柄菇属 Pluteus 5 2.39 红菇属 Russula 17 8.13 栓菌属 Trametes 5 2.39
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