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This novel thermochromic system can be driven by the solar heat, and are sensible and environmentally friendly. The ILs-Ni(II)-complex-PVDF composite films are thermochromic with different nickel complexes. Cryo-solvatochromism in response to cooling from room temperature to well below 0℃ can be achieved in a 1-hydroxylalkyl-3-methylimidazolium cation based ionic liquid, containing a Ni(II) complex and excess 1-butyl-3-methylimidazolium chloride. This review presents the recent fundamental and application work on a number of thermochromic and cryochromic systems based on Ni(II) complex and Ionic liquids, including the 1-hydroxylalkyl-3-methylimidazolium cation based ionic liquids and deep eutectic solvent., authors=YU Linpo, CHEN George Zheng, authorsList=YU Linpo, CHEN George Zheng, authorCompany=Centre for Sustainable Energy Technologies, the University of Nottingham Ningbo China, Ningbo 315100, China, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=C26Lc3FtjW1ckt3wxR+Dqw==, pdfFileSize=5211627, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1242134304776593605, 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离子液体在热致变色材料中的应用
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离子液体在热致变色材料中的应用
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余林颇, 陈政
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    宁波诺丁汉大学可持续能源技术研究中心, 宁波315100

通讯作者:

陈政(通信作者),教授,研究方向为热致变色材料、储能材料及电化学,电子信箱:George.Chen@nottingham.edu.cn
Application of ionic liquids in thermochromic materials
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出版时间: 2015-12-28 doi: 10.3981/j.issn.1000-7857.2015.24.016
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含有大量羟基的离子液体可以与镍(II)金属配合物发生配位反应,含有二者的溶液具有热致变色性质。这种新型的热致变色体系,只需要普通太阳光的热量就能驱动变色,具有变色灵敏、环境友好等特点。这种热致变色体系在与高分子材料聚偏氟乙烯(PVDF)形成复合物后,仍然具有优良的热致变色特性,且这种复合物可以由不同的镍(II)金属配合物组成。另外,这种热致变色体系还可以通过引入额外的氯离子,使体系在温度低于0℃以下时有颜色变化响应,体系转变为冷致变色体系。本文介绍几种基于羟烷基咪唑类和基于季铵盐的深共熔溶剂类离子液体,分别与镍(II)金属配合物所组成的热致/冷致变色体系及相关基础研究和复合膜应用研究工作。
热致变色  /  冷致变色  /  镍(II)金属配合物  /  离子液体  /  复合膜
Because of existence of abundant hydroxyl groups, both of hydroxyly-3-methylimidazolium cation based ionic liquids and deep eutectic solvent can react with the Ni(II) complexes showing thermochromism. This novel thermochromic system can be driven by the solar heat, and are sensible and environmentally friendly. The ILs-Ni(II)-complex-PVDF composite films are thermochromic with different nickel complexes. Cryo-solvatochromism in response to cooling from room temperature to well below 0℃ can be achieved in a 1-hydroxylalkyl-3-methylimidazolium cation based ionic liquid, containing a Ni(II) complex and excess 1-butyl-3-methylimidazolium chloride. This review presents the recent fundamental and application work on a number of thermochromic and cryochromic systems based on Ni(II) complex and Ionic liquids, including the 1-hydroxylalkyl-3-methylimidazolium cation based ionic liquids and deep eutectic solvent.
thermochromism  /  cryochromism  /  nickle (II) complexes  /  ionic liquids  /  composite films
余林颇, 陈政. 离子液体在热致变色材料中的应用. 科技导报, 2015 , 33 (24) : 98 -105 . DOI: 10.3981/j.issn.1000-7857.2015.24.016
YU Linpo, CHEN George Zheng. Application of ionic liquids in thermochromic materials[J]. Science & Technology Review, 2015 , 33 (24) : 98 -105 . DOI: 10.3981/j.issn.1000-7857.2015.24.016
2015年第33卷第24期
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doi: 10.3981/j.issn.1000-7857.2015.24.016
  • 接收时间:2015-07-06
  • 首发时间:2016-01-07
  • 出版时间:2015-12-28
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  • 收稿日期:2015-07-06
  • 修回日期:2015-08-14
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陈政(通信作者),教授,研究方向为热致变色材料、储能材料及电化学,电子信箱:George.Chen@nottingham.edu.cn
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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