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2. School of Materials Science and Engineering, Guangxi University, Nanning 530004, China;
3. Guangxi Polytechnic Vocational and Techical College, Chongzuo 532200, China, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=ajsTvc00e6UZ1TPYLehDJg==, pdfFileSize=2441439, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1242133621948096863, articleId=1242133619263742293, tenantId=1146029695717560320, journalId=1146031591421210625, language=CN, title=LED用黄绿色荧光粉LiZnPO4:Mn2+,Al3+的合成及Al3+敏化发光研究, columnId=1146540929516700224, journalTitle=科技导报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=为了获得可用于发光二极管(LED)的新型黄绿色荧光粉,用高温固相法合成了Li1-xZn0.9-xPO4:Mn0.1,Alx系列的荧光粉.用XRD 表征并分析了样品,获悉样品具有LiZnPO4的结构.用荧光发射光谱及激发光谱表征了样品的发光性能,讨论了Al3+掺杂对LiZnPO4:Mn,Al 荧光粉发光性能的影响.结果表明:Al3+掺杂量对激发及发射光强度的影响均为开口向下、有极值的抛物线,Al3+的最佳掺杂量为3%,对应样品是Li0.97Zn0.87PO4:Mn0.1,Al0.03;Al3+最佳掺杂量样品的发光强度是未掺Al3+样品的3.98 倍,说明在LiZnPO4基质中Al3+对Mn2+的发光具有增敏作用;Al3+的掺入只影响Mn2+的发光强度,不影响Mn2+的发光模式.Li0.97Zn0.87PO4:Mn0.1,Al0.03的色坐标值表明,该样品为黄绿色荧光粉,其在紫外线激发LED 领域具有潜在的应用前景., authors=农荣1,2,3, 黄映恒2, 卢科1, 廖森1, 谭鸿禹2, authorsList=农荣, 黄映恒, 卢科, 廖森, 谭鸿禹, authorCompany=1. 广西大学化学化工学院, 南宁530004;
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LED用黄绿色荧光粉LiZnPO4:Mn2+,Al3+的合成及Al3+敏化发光研究
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农荣, 黄映恒, 卢科, 廖森, 谭鸿禹
科技导报 | 研究论文 2015,33(13): 13-16
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科技导报 | 研究论文 2015, 33(13): 13-16
LED用黄绿色荧光粉LiZnPO4:Mn2+,Al3+的合成及Al3+敏化发光研究
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农荣, 黄映恒, 卢科, 廖森, 谭鸿禹
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通讯作者:

廖森,教授,研究方向为无机功能材料化学,电子信箱:liaosen@gxu.edu.cn
Synthesis and Al3+ sensitized luminescence of green-yellow emitting phosphor LiZnPO4:Mn2+, Al3+ for LED
NONG Rong, HUANG Yingheng, LU Ke, LIAO Sen, TAN Hongyu
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出版时间: 2015-07-13 doi: 10.3981/j.issn.1000-7857.2015.13.001
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为了获得可用于发光二极管(LED)的新型黄绿色荧光粉,用高温固相法合成了Li1-xZn0.9-xPO4:Mn0.1,Alx系列的荧光粉.用XRD 表征并分析了样品,获悉样品具有LiZnPO4的结构.用荧光发射光谱及激发光谱表征了样品的发光性能,讨论了Al3+掺杂对LiZnPO4:Mn,Al 荧光粉发光性能的影响.结果表明:Al3+掺杂量对激发及发射光强度的影响均为开口向下、有极值的抛物线,Al3+的最佳掺杂量为3%,对应样品是Li0.97Zn0.87PO4:Mn0.1,Al0.03;Al3+最佳掺杂量样品的发光强度是未掺Al3+样品的3.98 倍,说明在LiZnPO4基质中Al3+对Mn2+的发光具有增敏作用;Al3+的掺入只影响Mn2+的发光强度,不影响Mn2+的发光模式.Li0.97Zn0.87PO4:Mn0.1,Al0.03的色坐标值表明,该样品为黄绿色荧光粉,其在紫外线激发LED 领域具有潜在的应用前景.
无机化合物  /  磷酸盐  /  荧光粉  /  发光  /  光学材料
A series of Li1-xZn0.9-xPO4:Mn0.1, Alx phosphors are prepared by the solid-state method to obtain a new green-yellow phosphor that can be applied for the light emitting diodes (LED). XRD results confirm that the samples contain LiZnPO4 phase of crystals. Photoluminescence properties of the samples are characterized with photoluminescence of excitation (PLE) and emission spectra (PL), and the effect of Al3+ doping on the PL and PLE properties of Li1-xZn0.9-xPO4:Mn0.1, Alx phosphors is discussed. The results indicate that the dependent curve of relative intensity for PLE and PL on Al3+ doping concentration is a parabola curve with mouth downward and maximum value, and the optimal molar concentration of Al3+ for the samples is 3%,with corresponding sample being Li0.97Zn0.87PO4:Mn0.1, Al0.03. The research results indicate that the peak area of emission bands of Li1-xZn0.9-xPO4:Mn0.1, Alx with the optimal x is 3.98 times of that of sample with x=0. The fact suggests that the Al3+ ions can enhance the emission of Mn2+. Furthermore, Al3+ doping only affects the intensity of Mn2+ emission, and cannot influence its mode. The value for chromaticity coordinate of Li0.97Zn0.87 PO4:Mn0.1, Al0.03 indicates that it is a green-yellow emitting phosphor, which can be potentially useful as a UV excited phosphor for LEDs.
inorganic compounds  /  phosphates  /  phosphor  /  luminescence  /  optical materials
农荣, 黄映恒, 卢科, 廖森, 谭鸿禹. LED用黄绿色荧光粉LiZnPO4:Mn2+,Al3+的合成及Al3+敏化发光研究. 科技导报, 2015 , 33 (13) : 13 -16 . DOI: 10.3981/j.issn.1000-7857.2015.13.001
NONG Rong, HUANG Yingheng, LU Ke, LIAO Sen, TAN Hongyu. Synthesis and Al3+ sensitized luminescence of green-yellow emitting phosphor LiZnPO4:Mn2+, Al3+ for LED[J]. Science & Technology Review, 2015 , 33 (13) : 13 -16 . DOI: 10.3981/j.issn.1000-7857.2015.13.001
2015年第33卷第13期
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doi: 10.3981/j.issn.1000-7857.2015.13.001
  • 接收时间:2015-04-02
  • 首发时间:2015-07-25
  • 出版时间:2015-07-13
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  • 收稿日期:2015-04-02
  • 修回日期:2015-05-08
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廖森,教授,研究方向为无机功能材料化学,电子信箱:liaosen@gxu.edu.cn
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https://castjournals.cast.org.cn/joweb/kjdb/CN/10.3981/j.issn.1000-7857.2015.13.001
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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