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三氯化铁基少层石墨烯插层化合物的拉曼光谱
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科技导报 |专题论文 2015 , 33 (5) : 13 -17
三氯化铁基少层石墨烯插层化合物的拉曼光谱
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陈闰堃1, 陈佳宁1,2
作者信息
    1. 中国科学院物理研究所, 北京 100190;
    2. 量子物质科学协同创新中心, 北京 100190
通讯作者:
陈佳宁,研究员,研究方向为微纳光学,电子信箱:jnchen@iphy.ac.cn
作者简介:
陈闰堃,博士研究生,研究方向为二维材料近场光学物性,电子信箱:rkchen@iphy.ac.cn
Raman spectroscopy for FeCl3-based few-layer graphene intercalation compounds
  • CHEN Runkun1, CHEN Jianing1,2
  • Affiliations
      1. Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
      2. Collaborative Innovation Center of Quantum Matter, Beijing 100190, China
    出版时间: 2015-03-13 doi: 10.3981/j.issn.1000-7857.2015.05.001
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    利用拉曼光谱技术,研究了三氯化铁插层掺杂的少层石墨烯薄片。通过G 带拉曼成像可判明样品不同的插层掺杂部分及其掺杂程度。G 带拉曼峰在双层石墨烯和四层石墨烯中分别为单峰和双峰的不同结构。在石墨烯边缘处,G 带拉曼峰会比其内部多出1 个本征的G0峰,说明石墨烯边缘仍然存在未经插层掺杂的石墨烯。经过插层的双层石墨烯2D 带拉曼峰仍可拟合出4个洛伦兹峰。
    石墨烯  /  拉曼光谱  /  少层石墨烯插层化合物  /  三氯化铁基
    This paper investigates the FeCl3- based few- layer graphene intercalation compound flakes based on the Raman spectroscopy. Different intercalated parts of the graphene flake and the corresponding doping level can be retrieved by the G band Raman mapping. The G band Raman spectrum consists of a single peak or double peaks for the bilayer and tetralayer graphenes, respectively. A surprising intrinsic G0 peak appears at the edges of the intercalated graphene, which suggests that the doped graphene is partially undoped at the edges. Furthermore for the bilayer graphene intercalation compound flake, the 2D band peak can fit with four Lorenztian peaks with different full width half maxima (FWHM). This study provides a better understanding of the property of the electrically modified graphene.
    graphene  /  Raman spectroscopy  /  few-layer graphene intercalation compounds  /  FeCl3-based
    陈闰堃, 陈佳宁. 三氯化铁基少层石墨烯插层化合物的拉曼光谱. 科技导报, 2015 , 33 (5) : 13 -17 . DOI: 10.3981/j.issn.1000-7857.2015.05.001
    CHEN Runkun, CHEN Jianing. Raman spectroscopy for FeCl3-based few-layer graphene intercalation compounds[J]. Science & Technology Review, 2015 , 33 (5) : 13 -17 . DOI: 10.3981/j.issn.1000-7857.2015.05.001

      国家自然科学基金项目(11474350);国家重点基础研究发展计划(973计划)项目(2014CB921001);中国科学院战略性先导科技专项(B类)(XDB07030200)

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    doi: 10.3981/j.issn.1000-7857.2015.05.001
    • 接收时间:2015-01-07
    • 首发时间:2015-03-27
    • 出版时间:2015-03-13
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    • 收稿日期:2015-01-07
    • 修回日期:2015-01-29
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    陈佳宁,研究员,研究方向为微纳光学,电子信箱:jnchen@iphy.ac.cn
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    鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
    小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
    多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
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    小菇属 Mycena 11 5.26
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