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科技导报
| 研究论文 2015, 33(3): 24-28
有机废水过热近临界水氧化技术
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赵光明1 , 刘玉存1 , 柴涛1 , 王洪伟1 , 田江霞2
作者信息
1. 中北大学化工与环境学院, 太原030051;
2. 山西天和高清科技有限公司, 太原030051
Organic wastewater treatment by using superheated and near-critical water oxidation
Affiliations
出版时间: 2015-02-13
doi: 10.3981/j.issn.1000-7857.2015.03.003
文章导航
根据超临界水氧化处理废水反应效率的影响机理,增加温度能明显促进反应速率,降低压力可以减小反应器壁厚、降低设备投资和运行成本、减缓腐蚀。通过实验研究了在水的过热近临界区域对废水氧化处理的可行性。选择焦化废水、青霉素废水、造纸厂废水、丙烯腈废水、TNT 废水5 种较难降解的典型有机废水进行净化处理实验。实验温度为420~530℃,压力为21~26MPa。实验结果表明:在恒压下随着温度增加,5 种典型废水的化学需氧量(CODcr)净化率都迅速增加;在恒温下随着压力增加,5 种典型废水的CODcr净化率只稍有上升;随着温度增加,不同压力下系统反应出水CODcr 的差值和净化率的差值都在逐渐减小。在温度520~530℃,压力21 MPa 时5 种典型废水净化后的CODcr 值均小于200 mg/L。通过对过热近临界水氧化技术的技术经济性分析,从工程实际考虑,对工业有机废水处理更适宜采用过热近临界水氧化技术,而不是超临界水氧化技术。
有机废水处理
/
过热近临界水氧化
/
超临界水氧化
In this paper, the feasibility of waste water oxidation treatment in superheated near-critical region of water is studied through experiments. Five kinds of typical industrial organic wastewater which are difficult to biodegrade are chosen for purification experiments. They are coking wastewater, penicillin wastewater, papermaking wastewater, acrylonitrile wastewater and TNT wastewater, respectively. The temperature of the experiment is 420-530℃ and the pressure 21-26 MPa. The results show that at a constant pressure the CODcr removal ratios of the five kinds of wastewater are increasing rapidly with temperature increase,whereas at a constant temperature the CODcr removal ratios are only slightly increased as the pressure increases. Additionally, the differences of CODcr removal rates and purification rate of water in the outlet of the system at different pressures are gradually reduced as the temperature increases. Under conditions of temperature at 520-530℃ and pressure at 21 MPa, the purified CODcr values of the five typical kinds of wastewater are less than 200 mg/L, even less than 100 mg/L. Through a technological and economic analysis, it is pointed out that considering the engineering practice, the superheated and near-critical water oxidation is more suitable for industrial organic wastewater treatment, instead of the supercritical water oxidation technology.
treatment of organic wastewater
/
superheated and near-critical water oxidation
/
supercritical water oxidation
赵光明, 刘玉存, 柴涛, 王洪伟, 田江霞.
有机废水过热近临界水氧化技术.
科技导报,
2015
, 33
(3)
: 24
-28
.
DOI: 10.3981/j.issn.1000-7857.2015.03.003
ZHAO Guangming, LIU Yucun, CHAI Tao, WANG Hongwei, TIAN Jiangxia.
Organic wastewater treatment by using superheated and near-critical water oxidation[J].
Science & Technology Review ,
2015
, 33
(3)
: 24
-28
.
DOI: 10.3981/j.issn.1000-7857.2015.03.003
2015年第33卷第3期
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引用本文
BibTeX
文章信息
doi: 10.3981/j.issn.1000-7857.2015.03.003
接收时间:2014-10-22
首发时间:2015-03-03
出版时间:2015-02-13
收稿日期:2014-10-22
修回日期:2014-12-21
https://castjournals.cast.org.cn/joweb/kjdb/CN/10.3981/j.issn.1000-7857.2015.03.003
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2种不同金属材料的力学参数
科 Family 属数 Number of genus 种数 Number of species 占总种数比例 Percentage of total species (%) 属 Genus 种数 Number of species 占总种数比例 Percentage of total species (%) 鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78 小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39 多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39 红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87 小菇属 Mycena 11 5.26 光柄菇属 Pluteus 5 2.39 红菇属 Russula 17 8.13 栓菌属 Trametes 5 2.39
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