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科技导报
|研究论文
2014
, 32
(31) :
71
-74
低温环境下煤表面吸附的均匀性试验
全屏
岳高伟1,2 , 王兆丰2 , 谢策2
作者信息
1. 河南理工大学土木工程学院, 焦作 454000;
2. 河南理工大学安全科学与工程学院, 焦作 454000
作者简介:
岳高伟,副教授,研究方向为矿业安全与防治,电子信箱:mxlygw@163.com
Experimental Study of Coal Surface Adsorption Uniformity in Low Temperature Environment
YUE Gaowei1,2 , WANG Zhaofeng2 , XIE Ce2
Affiliations
1. School of Civil Engineering, Henan Polytechnic University, Jiaozuo 454000, China;
2. School of Safety Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, China
出版时间: 2014-11-08
doi: 10.3981/j.issn.1000-7857.2014.31.010
文章导航
等量吸附热是表征固体表面吸附非均匀性的重要参数.采用高低温吸附仿真实验装置,对九里山无烟煤、新元贫煤、潘北气肥煤进行瓦斯吸附测试,通过计算等量吸附热与吸附量的关系,探讨从常温(30、20℃)降至低温(-10、-20、-30℃)对煤表面不均匀性的影响.结果表明,不同变质程度煤的瓦斯吸附量都随温度降低而增大;在常温时(30、20℃)煤的等量吸附热随吸附量的增大而减小,表明煤表面能量是不均匀的.降温至-10、-20、-30℃时煤的等量吸附热几乎和吸附量无关,表明煤表面是均匀的.煤吸附瓦斯理论Langmuir 方程在低温环境(0℃以下)更加适用.
吸附
/
低温环境
/
表面均匀性
/
等量吸附热
The isosteric adsorption heat is an important parameter to measure the solid surface inhomogeneity during its adsorption. In this paper a high/low temperature adsorption experiment device is utilized to test the gas adsorption of anthracite coal of Jiulishan coal mine, lean coal of Xinyuan coal mine and gas-fat coal of Panbei coal mine at different temperatures ranging from 30 to -30℃. Then according to the relationship of isosteric adsorption heat and adsorption capacity, the influence of coal surface inhomogeneity is discussed at ordinary temperatures (30, 20℃) and low temperatures (-10, -20, -30℃). The analytical results show that the gas adsorption capacities of different coal ranks all increase with the decrease of environmental temperature. In an ordinary temperature environment (30, 20℃ ) the isosteric adsorption heat of coal decreases as the gas adsorption capacity increases, which indicates that the coal surface energy of adsorption is heterogeneous. But when cooling to -10, -20, or -30℃, the isosteric adsorption heat is almost irrelevant to the adsorption capacity of coal, which indicates that the coal surface energy of adsorption is uniform. So the Langmuir equation of the coal gas adsorption theory is more suitable to a low temperature environment (below 0℃).
adsorption
/
low temperature environment
/
surface uniformity
/
isosteric adsorption heat
岳高伟, 王兆丰, 谢策.
低温环境下煤表面吸附的均匀性试验.
科技导报,
2014
, 32
(31)
: 71
-74
.
DOI: 10.3981/j.issn.1000-7857.2014.31.010
YUE Gaowei, WANG Zhaofeng, XIE Ce.
Experimental Study of Coal Surface Adsorption Uniformity in Low Temperature Environment[J].
Science & Technology Review ,
2014
, 32
(31)
: 71
-74
.
DOI: 10.3981/j.issn.1000-7857.2014.31.010
2014年第32卷第31期
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文章信息
doi: 10.3981/j.issn.1000-7857.2014.31.010
接收时间:2014-05-27
首发时间:2014-11-15
出版时间:2014-11-08
收稿日期:2014-05-27
修回日期:2014-06-25
https://castjournals.cast.org.cn/joweb/kjdb/CN/10.3981/j.issn.1000-7857.2014.31.010
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2种不同金属材料的力学参数
科 Family 属数 Number of genus 种数 Number of species 占总种数比例 Percentage of total species (%) 属 Genus 种数 Number of species 占总种数比例 Percentage of total species (%) 鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78 小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39 多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39 红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87 小菇属 Mycena 11 5.26 光柄菇属 Pluteus 5 2.39 红菇属 Russula 17 8.13 栓菌属 Trametes 5 2.39
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