Article(id=1242130872942527025, tenantId=1146029695717560320, journalId=1146031591421210625, issueId=1242130862028947957, articleNumber=null, orderNo=null, doi=10.3981/j.issn.1000-7857.2013.26.010, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1362672000000, receivedDateStr=2013-03-08, revisedDate=1371916800000, revisedDateStr=2013-06-23, acceptedDate=null, acceptedDateStr=null, onlineDate=1379433600000, onlineDateStr=2013-09-18, pubDate=1379433600000, pubDateStr=2013-09-18, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1379433600000, onlineIssueDateStr=2013-09-18, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1774076677782, creator=sys-migrate, updateTime=1774076677782, updator=sys-migrate, issue=Issue{id=1242130862028947957, tenantId=1146029695717560320, journalId=1146031591421210625, year='2013', volume='31', issue='26', pageStart='3', pageEnd='96', issueExtLink='null', onlineDate='null', pubDate='1379433600000', pubDateStr='2013-09-18', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=3, issueType=-1, specialIssue=null, createTime=1774076675180, creator='sys-migrate', updateTime=1774076675180, updator='sys-migrate', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=60, endPage=63, ext={EN=ArticleExt(id=1242130877476569687, articleId=1242130872942527025, tenantId=1146029695717560320, journalId=1146031591421210625, language=EN, title=Catalytic Synthesis of Long-chain Alkylbenzene by Al-MCM-41-Supported Ionic Liquid, columnId=1242116080374710456, journalTitle=Science & Technology Review, columnName=Articles, runingTitle=null, highlight=null, articleAbstract=In order to develop a highly efficient solid catalyst system, the ionic liquid is introduced into mesoporous molecular sieves of Al-MCM-41. Under the hydrothermal condition, the mesoporous molecular sieves of Al-MCM-41 are synthesized, to prepare the supported catalyst, dipped in the ionic liquid. The product is further characterized by FT-IR, TG, N₂ adsorp/desorp and elemental analyses. It is shown that the ionic liquid is grafted into the mesoporous molecular sieves of Al-MCM-41 successfully. The optimum reaction conditions are determined by the process of the orthogonal experimental design. Under the optimized reaction conditions, it is shown that when the molar ratio of benzene/olefin is 8:1, at the temperature of 200℃, with airspeed of 1.5h^-1 and pressure of 3 MPa, the conversion rate of olefin and the selectivity are best. Under the optimum reaction conditions, the conversion rate of olefin with Al-MCM-41 grafted by the ionic liquid catalyst is 95.32%., authors=HUANG Liangliang¹, CHEN Li², authorsList=HUANG Liangliang;CHEN Li, authorCompany=1. School of Materials and Chemistry Sciences, Liaoning Shihua University, Fushun 113001, Liaoning Province, China;2. Yuandong Yeyan Lianhua, Fushun 113017, Liaoning Province, China, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=gCu05zdZkDbe+p4LnbZeFA==, pdfFileSize=859703, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1242130876516077580, articleId=1242130872942527025, tenantId=1146029695717560320, journalId=1146031591421210625, language=CN, title=Al-MCM-41固载离子液体催化-合成长链烷基苯, columnId=1146540929516700224, journalTitle=科技导报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=为了合成高效的固体催化剂,离子液体被引入到介孔分子筛中。采用水热合成法制备了Al-MCM-41介孔分子筛,并浸渍离子液体制备出一种固载化催化剂。通过FT-IR、TG、N₂吸附-脱附等方法进行表征,分析其晶型结构,成功将离子液体固载到Al-MCM-41介孔分子筛上。通过对工艺条件的考察和正交实验设计,确定了最佳反应条件。当苯烯摩尔比为8:1、反应温度为200℃、空速1.5h^-1、压力3MPa时,反应的转化率和选择性综合达到最佳,Al-MCM-41固载离子液体催化剂的烯烃转化率为95.32%。, authors=黄亮亮¹, 陈立², authorsList=黄亮亮;陈立, authorCompany=1. 辽宁石油化工大学化学与材料科学学院, 辽宁抚顺 113001;2. 远东页岩炼化有限责任公司, 辽宁抚顺 113017, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=s7cq/FQ3AwaF1BjAF33LCw==, pdfFileSize=859703, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null)}, authors=null, keywords=[Keyword(id=1242130875576549950, tenantId=1146029695717560320, journalId=1146031591421210625, 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