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The samples are studied by the traditional electrochemical techniques, such as potentiodynamic polarization curve, electrochemical impedance spectroscopy, and scanning microelectrode technique which is self-assembly made by authors. In conclusion, it is indicates that the corrosion resistance of welding seam zone is lower than that of base materials in any situation. In the NaCl and FeCl3 solutions with different concentration, the anti-corrosion performance of the Argon tungsten arc welding samples are better than that of CO2 shielded arc welding samples. The conclusion is all verified by the three different techniques. Besides, it is also concluded that the corrosion resistant of the both welding samples and base materials are decreased with the increase of the concentration of chloride ions., authors=LÜ Hongwei1, DONG Shigang1, WANG Jingjing2, LI Ning1, LIN Changjian2, authorsList=LÜHongwei;DONG Shigang;WANG Jingjing;LI Ning;LIN Changjian, authorCompany=1. 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316L不锈钢焊缝腐蚀行为的电化学研究
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316L不锈钢焊缝腐蚀行为的电化学研究
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吕虹玮1, 董士刚1, 王静静2, 李宁1, 林昌健2
作者信息
    1. 厦门大学能源研究院,福建厦门 361005;2. 厦门大学化学化工学院;固体表面物理化学国家重点实验室,福建厦门 361005

通讯作者:

林昌健,教授,研究方向为电化学腐蚀与防护,电子信箱:cjlin@xmu.edu.cn
Electrochemical Behaviors of the 316L Stainless Steel Welding Seam Corrosion
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出版时间: 2013-02-28 doi: 10.3981/j.issn.1000-7857.2013.h1.003
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316L不锈钢以其优良的耐腐蚀性能、加工性能和高抗氧化性能而被广泛应用于核电、石油、化工等领域.316L不锈钢的应用大多需要焊接成型,但焊接过程中化学成分,组织形态和相关性能的改变,使316L不锈钢的耐蚀性能降低,在焊缝接头处以及焊缝部位优先发生腐蚀,严重影响了不锈钢的使用寿命和安全性.本文采用交流阻抗法和阳极极化常规电化学方法,结合课题组自主研发的扫描微电极技术研究316L不锈钢焊缝区的腐蚀行为,探讨钨极氩弧焊和CO2保护焊两种不同焊接方法对316L不锈钢抗腐蚀能力的影响以及氯离子浓度对焊接样品抗腐蚀能力的影响.结果表明,经过腐蚀电化学方法检测后,焊接样品的耐腐蚀性能较基材样品均发生明显降低,具体表现为氩弧焊焊接样品和CO2保护焊焊接样品在阳极极化曲线的开裂电位Eb,腐蚀电位Ecorr均较基材样品负,钝化区ΔE较基材样品变窄.交流阻抗谱测试得出氩弧焊焊接样品与CO2保护焊焊接样品的电荷转移电阻Rct均较基材样品小.同时,通过不同实验分析均表明,在NaCl溶液和FeCl3溶液中,氩弧焊焊接样品的耐蚀性能较CO2保护焊焊接样品好.实验结果还表明,随着氯离子浓度的升高,两种焊接样品的耐蚀性能均降低.
316L不锈钢  /  焊缝区腐蚀  /  电化学技术  /  扫描微电极技术
The effect of two different techniques, including Argon tungsten arc welding (TIG) and CO2 shielded arc welding, on the welding seam corrosion behavior of the 316L stainless steel, and whether or not the concentration of chloride ions affect the welding seam corrosion of the welding samples are explored. The samples are studied by the traditional electrochemical techniques, such as potentiodynamic polarization curve, electrochemical impedance spectroscopy, and scanning microelectrode technique which is self-assembly made by authors. In conclusion, it is indicates that the corrosion resistance of welding seam zone is lower than that of base materials in any situation. In the NaCl and FeCl3 solutions with different concentration, the anti-corrosion performance of the Argon tungsten arc welding samples are better than that of CO2 shielded arc welding samples. The conclusion is all verified by the three different techniques. Besides, it is also concluded that the corrosion resistant of the both welding samples and base materials are decreased with the increase of the concentration of chloride ions.
316L stainless steel  /  welding Seam zone corrosion  /  electrochemical technique  /  scanning microelectrode technique
吕虹玮;董士刚;王静静;李宁;林昌健. 316L不锈钢焊缝腐蚀行为的电化学研究. 科技导报, 2013 , 31 (5-6) : 25 -28 . DOI: 10.3981/j.issn.1000-7857.2013.h1.003
LÜHongwei;DONG Shigang;WANG Jingjing;LI Ning;LIN Changjian. Electrochemical Behaviors of the 316L Stainless Steel Welding Seam Corrosion[J]. Science & Technology Review, 2013 , 31 (5-6) : 25 -28 . DOI: 10.3981/j.issn.1000-7857.2013.h1.003
2013年第31卷第5-6期
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doi: 10.3981/j.issn.1000-7857.2013.h1.003
  • 接收时间:2012-12-20
  • 首发时间:2013-02-28
  • 出版时间:2013-02-28
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  • 收稿日期:2012-12-20
  • 修回日期:2013-01-21
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林昌健,教授,研究方向为电化学腐蚀与防护,电子信箱:cjlin@xmu.edu.cn
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Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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