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科技导报 |综述文章 2012 , 30 (14) : 70 -74
生物质热解过程中氮元素迁移规律研究进展
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苟进胜, 常建民, 任学勇
作者信息
    北京林业大学材料科学与技术学院;木材科学与工程北京市重点实验室;木质材料科学与应用教育部重点实验室;林业生物质材料与能源教育部工程研究中心,北京 100083
通讯作者:
常建民,教授,研究方向为生物质高值化热裂解炼制与生物质基多功能材料开发,电子信箱:cjianmin@bjfu.edu.cn
A Review on the Release Characterization of Nitrogen Speicies During Biomass Pyrolysis
  • GOU Jinsheng, CHANG Jianmin, REN Xueyong
  • Affiliations
      Engineering Research Center of Forestry Biomass Materials and Bioenergy, Ministry of Education; Key Laboratory of Wooden Material Science and Application, Ministry of Education; Key Laboratory of Wood Science and Engineering; College of Material Science and Technology, Beijing Forestry University, Beijing 100083, China
    出版时间: 2012-05-18 doi: 10.3981/j.issn.1000-7857.2012.14.010
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    生物质在热解过程中会产生含氮化合物,进而转化为NOx,严重危害环境安全。因此,解析生物质热解过程中氮的释放特性,寻求有效调控手段,以减少NOx排放量、消除环境污染是生物质能源清洁利用研究的重要内容。本文首先总结分析不同生物质中氮的含量及在生物质不同部位的分布情况,并对生物质中氮赋存形态的研究方法、结论及存在的问题进行讨论;继而,重点综述生物质热解过程中氮的释放特性和影响因素,梳理生物质热解过程中氮的释放路径,讨论温度、升温速率、原料中氮的赋存形态及含量等因素对氮元素迁移的影响规律;最后,对热解过程中氮在产物中的分配机制进行总结分析,并对生物质热解清洁转化研究进行展望。
    生物质  /  热解  /  可再生能源  /  含氮化合物  /  氮氧化物
    The pyrolysis is one of the promising methods to convert biomass to bio-oils as fuels and chemicals. During the pyrolysis of biomass, some nitrogen species are released, as the precursors of NOx with potential environment pollution. The release characterization of nitrogen species during biomass pyrolysis is reviewed in this paper. Firstly, the content and the distribution of nitrogen in various biomass materials are classified, and the research methods, the conclusions and the problems that remain to be solved concerning the chemical forms or the nitrogen functionalities in different biomass materials are discussed. And then we discuss the release characterization, as well as the factors affecting the nitrogen evolution during pyrolysis. The evolution route of nitrogen in biomass during pyrolysis is elaborated in detail, and the operating parameters such as the temperature, the heating rates and the nitrogen forms and content are shown to contribute to the nitrogen release., The nitrogen distribution in products in gas phase, liquid phase and solid phase is analyzed as well. In the end, some prospective developments are commented for the research of pyrolysis convention of biomass.
    biomass  /  pyrolysis  /  renewable energy  /  nitrogen species  /  NOx
    苟进胜;常建民;任学勇. 生物质热解过程中氮元素迁移规律研究进展. 科技导报, 2012 , 30 (14) : 70 -74 . DOI: 10.3981/j.issn.1000-7857.2012.14.010
    GOU Jinsheng;CHANG Jianmin;REN Xueyong. A Review on the Release Characterization of Nitrogen Speicies During Biomass Pyrolysis[J]. Science & Technology Review, 2012 , 30 (14) : 70 -74 . DOI: 10.3981/j.issn.1000-7857.2012.14.010

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    doi: 10.3981/j.issn.1000-7857.2012.14.010
    • 接收时间:2012-02-23
    • 首发时间:2012-05-18
    • 出版时间:2012-05-18
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    • 收稿日期:2012-02-23
    • 修回日期:2012-04-25
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    常建民,教授,研究方向为生物质高值化热裂解炼制与生物质基多功能材料开发,电子信箱:cjianmin@bjfu.edu.cn
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    2种不同金属材料的力学参数

    Family
    属数
    Number of
    genus
    种数
    Number of
    species
    占总种数比例
    Percentage of
    total species (%)

    Genus
    种数
    Number of
    species
    占总种数比例
    Percentage of total
    species (%)
    鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
    小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
    多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
    红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
    小菇属 Mycena 11 5.26
    光柄菇属 Pluteus 5 2.39
    红菇属 Russula 17 8.13
    栓菌属 Trametes 5 2.39
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