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科技导报 |综述文章 2011 , 29 (30) : 68 -72
过渡金属基分子筛SCR催化剂失活机制及抗失活技术研究进展
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马静, 翁端, 吴晓东, 司知蠢
作者信息
    清华大学材料科学与工程系;先进材料教育部重点实验室,北京 100084
通讯作者:
翁端(中国科协所属全国学会个人会员登记号:E491100461S),教授,研究方向为环境材料及工业生态学,电子信箱:duanweng@tsinghua.edu.cn
Research Progress on Deactivation and Resistance of Transitional Metal Based Zeolite SCR Catalysts
  • MA Jing, WENG Duan, WU Xiaodong, SI Zhichun
  • Affiliations
      Key Laboratory for Advanced Materials of Ministry of Education, Department of Materials Science & Engineering, Tsinghua University, Beijing 100084, China
    出版时间: 2011-10-28 doi: 10.3981/j.issn.1000-7857.2011.30.010
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    过渡金属基分子筛是在氨选择性催化还原氮氧化物技术领域广泛应用的一类催化材料,在实际应用中容易中毒失活。失活形式主要有水热老化失活,P、S中毒失活,HCs中毒失活及尿素中毒失活等。本文分析了过渡金属基分子筛催化剂的4种失活机制及相应的抗失活工艺,并展望了过渡金属基分子筛的发展方向。
    过渡金属基分子筛  /  水热老化  /  磷硫  /  碳氢化合物  /  尿素
    Transitional metal based zeolites are widely used to remove nitrogen oxides by NH3-SCR, which will eventually become de-activated in practical application proceses, including hydrothermal aging, P and S poisoning, HCs poisoning and urea poisoning. The deactivation mechanisms and the related methods to improve the resistance to deactivation are reviewed. The development trends of the transitional metal based zeolite are outlined.
    transitional metal based zeolite  /  hydrothermal aging  /  P and S  /  HCs  /  urea
    马静;翁端;吴晓东;司知蠢. 过渡金属基分子筛SCR催化剂失活机制及抗失活技术研究进展. 科技导报, 2011 , 29 (30) : 68 -72 . DOI: 10.3981/j.issn.1000-7857.2011.30.010
    MA Jing;WENG Duan;WU Xiaodong;SI Zhichun. Research Progress on Deactivation and Resistance of Transitional Metal Based Zeolite SCR Catalysts[J]. Science & Technology Review, 2011 , 29 (30) : 68 -72 . DOI: 10.3981/j.issn.1000-7857.2011.30.010

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    doi: 10.3981/j.issn.1000-7857.2011.30.010
    • 接收时间:2011-10-10
    • 首发时间:2011-10-28
    • 出版时间:2011-10-28
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    • 收稿日期:2011-10-10
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    翁端(中国科协所属全国学会个人会员登记号:E491100461S),教授,研究方向为环境材料及工业生态学,电子信箱:duanweng@tsinghua.edu.cn
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    2种不同金属材料的力学参数

    Family
    属数
    Number of
    genus
    种数
    Number of
    species
    占总种数比例
    Percentage of
    total species (%)

    Genus
    种数
    Number of
    species
    占总种数比例
    Percentage of total
    species (%)
    鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
    小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
    多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
    红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
    小菇属 Mycena 11 5.26
    光柄菇属 Pluteus 5 2.39
    红菇属 Russula 17 8.13
    栓菌属 Trametes 5 2.39
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