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The optimum reaction temperature is 90℃, the optimum reaction time is 4h, and the optimum KH-550 concentration is 1.5g. Modified powders are characterized by using scanning electron microscopy, X-ray diffraction, infrared spectroscopy, and laser particle size analyzer. The effect of surface modification on the dispersion stabilization of SiC slurry is also analyzed. The results show that the SiC powder treated by aminoorganosilanes does not change the phase structure of original SiC; it only changes the colloidal properties in water. d 0.5 decreases slightly and particle size distribution narrows down. SEM shows that powder agglomeration is reduced and dispersion property is improved for SiC powder. Comparing with the original SiC powder, the surface characteristics of modified SiC powder occur a great change and Zeta potential increases from 17.58mV to 41mV(with pH=3.78). The dispersion stabilization of SiC slurry is remarkably increased., authors=TIE Shengnian, LI Xing, authorsList=TIE Shengnian;LI Xing, authorCompany=Non-Metallic Materials Institute, Qinghai University, Xining 810016, China, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=COHYDf4WKhpd38CLTU6wog==, pdfFileSize=2077130, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1242127599921594693, articleId=1242127597212078694, tenantId=1146029695717560320, journalId=1146031591421210625, language=CN, title=半导体制造用碳化硅粉体偶联剂表面改性, columnId=1146540929516700224, journalTitle=科技导报, columnName=研究论文, runingTitle=null, highlight=null, 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科技导报
|研究论文
2011
, 29
(19) :
29
-33
半导体制造用碳化硅粉体偶联剂表面改性
全屏
铁生年, 李星
作者信息
Research on Surface Modification of SiC Powder with Aminoorganosilanes in the Semiconductor Manufacturing
TIE Shengnian, LI Xing
Affiliations
Non-Metallic Materials Institute, Qinghai University, Xining 810016, China
出版时间: 2011-07-08
doi: 10.3981/j.issn.1000-7857.2011.19.003
文章导航
采用KH-550硅烷偶联剂对SiC粉体进行表面改性,通过单因素实验及正交试验确定出改性过程最优化工艺参数:反应温度90℃,反应时间4h,KH-550硅烷偶联剂用量1.5g,并通过扫描电镜、X射线衍射仪、红外光谱仪、激光粒度分析仪对制备的改性粉体进行表征,分析改性对SiC料浆分散稳定性的影响。结果表明,SiC微粉经偶联剂处理后没有改变原始SiC微粉的物相结构,只是改变了其在水中的胶体性质;中位径d 0.5 略有减小,粒度分度分布范围变窄,扫描电子显微镜(SEM)显示微粉团聚现象减少,分散性得到改善;改性SiC微粉与原始SiC微粉相比,表面特性发生了很大变化,在酸性条件下Zeta电位有显著的提高,pH值为3.78时,Zeta电位获得最高正电位为41mV,悬浮液的分散稳定性得到明显改善。
碳化硅
/
表面改性
/
KH-550硅烷偶联剂
/
分散性
The surface modification of SiC powder with KH-550 aminoorganosilanes was carried out and the optimum process parameters of modification were pointed out by using single factor experiments and orthogonal experiments. The optimum reaction temperature is 90℃, the optimum reaction time is 4h, and the optimum KH-550 concentration is 1.5g. Modified powders are characterized by using scanning electron microscopy, X-ray diffraction, infrared spectroscopy, and laser particle size analyzer. The effect of surface modification on the dispersion stabilization of SiC slurry is also analyzed. The results show that the SiC powder treated by aminoorganosilanes does not change the phase structure of original SiC; it only changes the colloidal properties in water. d 0.5 decreases slightly and particle size distribution narrows down. SEM shows that powder agglomeration is reduced and dispersion property is improved for SiC powder. Comparing with the original SiC powder, the surface characteristics of modified SiC powder occur a great change and Zeta potential increases from 17.58mV to 41mV(with pH=3.78). The dispersion stabilization of SiC slurry is remarkably increased.
silicon carbide
/
surface modification
/
KH-550 aminoorganosilanes
/
dispersion property
铁生年;李星.
半导体制造用碳化硅粉体偶联剂表面改性.
科技导报,
2011
, 29
(19)
: 29
-33
.
DOI: 10.3981/j.issn.1000-7857.2011.19.003
TIE Shengnian;LI Xing.
Research on Surface Modification of SiC Powder with Aminoorganosilanes in the Semiconductor Manufacturing[J].
Science & Technology Review ,
2011
, 29
(19)
: 29
-33
.
DOI: 10.3981/j.issn.1000-7857.2011.19.003
2011年第29卷第19期
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文章信息
doi: 10.3981/j.issn.1000-7857.2011.19.003
接收时间:2010-09-06
首发时间:2011-07-08
出版时间:2011-07-08
收稿日期:2010-09-06
修回日期:2011-05-26
https://castjournals.cast.org.cn/joweb/kjdb/CN/10.3981/j.issn.1000-7857.2011.19.003
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2种不同金属材料的力学参数
科 Family 属数 Number of genus 种数 Number of species 占总种数比例 Percentage of total species (%) 属 Genus 种数 Number of species 占总种数比例 Percentage of total species (%) 鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78 小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39 多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39 红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87 小菇属 Mycena 11 5.26 光柄菇属 Pluteus 5 2.39 红菇属 Russula 17 8.13 栓菌属 Trametes 5 2.39
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