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合成化学中的“焊接”技术——2010年度诺贝尔化学奖成果介绍
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科技导报 |本刊专稿 2010 , 28 (24) : 29 -32
合成化学中的“焊接”技术——2010年度诺贝尔化学奖成果介绍
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施章杰,余大刚
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    北京大学化学与分子工程学院,北京 100871
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施章杰
The "Welding" Technology in Organic Synthesis
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    出版时间: 2010-12-10
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    在过渡金属特别是钯的催化下,金属有机化合物和卤化物两个有机片段的高效高选择性的连接已经成为被广泛使用的有机合成方法。本文概述了2010年度诺贝尔化学奖得主Richard F. Heck、Ei-ichi Negishi和Akira Suzuki的主要研究,及其对钯催化的交叉偶联反应研究的杰出贡献。
    诺贝尔化学奖  /  钯催化  /  交叉偶联反应
    Transition metals, especially Pd, catalyzed cross-coupling reactions from organohalides and organometallic reagents have been well developed and broadly utilized in organic synthesis. This paper summarizes the main research of the 2010 Nobel Prize in Chemistry laureates, Richard F. Heck, Ei-ichi Negishi, Akira Suzuki, and their outstanding contribution to the palladium-catalyzed cross-coupling reactions.
    Nobel Prize in Chemistry  /  palladium catalysis  /  cross coupling
    施章杰;余大刚. 合成化学中的“焊接”技术——2010年度诺贝尔化学奖成果介绍. 科技导报, 2010 , 28 (24) : 29 -32 .
    . The "Welding" Technology in Organic Synthesis[J]. Science & Technology Review, 2010 , 28 (24) : 29 -32 .

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    2种不同金属材料的力学参数

    Family
    属数
    Number of
    genus
    种数
    Number of
    species
    占总种数比例
    Percentage of
    total species (%)

    Genus
    种数
    Number of
    species
    占总种数比例
    Percentage of total
    species (%)
    鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
    小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
    多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
    红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
    小菇属 Mycena 11 5.26
    光柄菇属 Pluteus 5 2.39
    红菇属 Russula 17 8.13
    栓菌属 Trametes 5 2.39
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