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articleAbstract=为了开发新型烟用香料,将各种挥发性香味酸做成糖酯添加到卷烟中,并对其卷烟加香效果进行评价。本文以1,2-O-丙叉基-?琢-D-呋喃木糖和一系列具有香味的有机酸为原料,无水碳酸钠和4-二甲氨基吡啶(4-DMAP)为催化剂,N,N'-二环己基碳二亚胺(DCC)为缩合剂,经过酯化反应合成出15种5-木糖酯类衍生物,其中13种化合物为新化合物。所有化合物结构均经IR、1H NMR、MS和元素分析得到确证。该15种化合物的卷烟加香实验结果表明,加入各糖酯前体的卷烟评吸结果与对照卷烟相比,均可使香气质改善,香气量增加,达到烟香协调、余味净化、杂气减轻的效果。故合成的5-木糖酯可以作为香原料应用到卷烟中。 。, authors=姬小明1,刘 云2,刘 乐1,赵铭钦1 , authorsList=姬小明;刘 云;刘 乐;赵铭钦, authorCompany=1. 河南农业大学烟草学院,郑州 4500022. 宝鸡市烟草公司,陕西宝鸡 721000, correspAuthors=null, authorNote=null, correspAuthorsNote=姬小明, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=QSTrDzausP1TJEegjKQhDw==, pdfFileSize=666214, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null)}, authors=[Author(id=1278368592777355731, tenantId=1146029695717560320, journalId=null, 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科技导报
| 研究论文 2010, 28(21): 68-74
5-木糖酯类衍生物的合成及其卷烟加香应用
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姬小明;刘 云;刘 乐;赵铭钦
作者信息
Synthesis of 5-xylose Ester Derivatives and Their Application in Cigarette Flavoring
Affiliations
出版时间: 2010-11-13
文章导航
为了开发新型烟用香料,将各种挥发性香味酸做成糖酯添加到卷烟中,并对其卷烟加香效果进行评价。本文以1,2-O-丙叉基-?琢-D-呋喃木糖和一系列具有香味的有机酸为原料,无水碳酸钠和4-二甲氨基吡啶(4-DMAP)为催化剂,N,N'-二环己基碳二亚胺(DCC)为缩合剂,经过酯化反应合成出15种5-木糖酯类衍生物,其中13种化合物为新化合物。所有化合物结构均经IR、1H NMR、MS和元素分析得到确证。该15种化合物的卷烟加香实验结果表明,加入各糖酯前体的卷烟评吸结果与对照卷烟相比,均可使香气质改善,香气量增加,达到烟香协调、余味净化、杂气减轻的效果。故合成的5-木糖酯可以作为香原料应用到卷烟中。 。
1
/
2-O-丙叉基-?琢-D-呋喃木糖
/
乙酸酐
/
有机酸
/
4-二甲氨基吡啶
/
合成
In order to develop new cigarette flavors, a sensory evaluation is made of cigarettes added with sugar esters, synthesised with some volatilizable organic acids with flavors. Taking 1,2-O-propylidene- -D-furan xylose and a series of organic acids with flavors as raw materials, exsiccated sodium carbonate and 4-dimethylaminopyridine (4-DMAP) as catalyst, N,N'-dicyclohexyl carbodiimide (DCC) as condensing agent, through the esterification, 15 kinds of 5-xylose ester derivatives were synthesized in which 13 compounds were new ones. All the structures of the compounds were confirmed by IR, 1H NMR, MS spectra and elemental analysis. The results of tobacco flavoring experiments of these 15 kinds of compounds show that, compared with cigarette control group, adding sugar esters precursor into cigarettes could improve the aroma quality, increase the aroma quantity, harmonize the aroma, clean the after-taste and reduce offensive odor of cigarettes. It is concluded that the synthesised 5-xylose seter derivatives could be used as flavor materials in cigarette flavoring.
1
/
2-O-propylidene-?琢-D-furan xylose
/
acetic anhydride
/
organic acid
/
4-dimethylaminopyridine
/
synthesis
姬小明;刘 云;刘 乐;赵铭钦.
5-木糖酯类衍生物的合成及其卷烟加香应用.
科技导报,
2010
, 28
(21)
: 68
-74
.
;.
Synthesis of 5-xylose Ester Derivatives and Their Application in Cigarette Flavoring[J].
Science & Technology Review ,
2010
, 28
(21)
: 68
-74
.
2010年第28卷第21期
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接收时间:2010-03-08
首发时间:2010-11-13
出版时间:2010-11-13
收稿日期:2010-03-08
修回日期:2010-05-24
https://castjournals.cast.org.cn/joweb/kjdb/CN/1242120831002804586
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2种不同金属材料的力学参数
科 Family 属数 Number of genus 种数 Number of species 占总种数比例 Percentage of total species (%) 属 Genus 种数 Number of species 占总种数比例 Percentage of total species (%) 鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78 小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39 多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39 红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87 小菇属 Mycena 11 5.26 光柄菇属 Pluteus 5 2.39 红菇属 Russula 17 8.13 栓菌属 Trametes 5 2.39
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