Article(id=1242120420200088074, tenantId=1146029695717560320, journalId=1146031591421210625, issueId=1242120303908815076, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1263225600000, receivedDateStr=2010-01-12, revisedDate=1267977600000, revisedDateStr=2010-03-08, acceptedDate=null, acceptedDateStr=null, onlineDate=1278950400000, onlineDateStr=2010-07-13, pubDate=1278950400000, pubDateStr=2010-07-13, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1278950400000, onlineIssueDateStr=2010-07-13, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1774074185655, creator=sys-migrate, updateTime=1774074185655, updator=sys-migrate, issue=Issue{id=1242120303908815076, tenantId=1146029695717560320, journalId=1146031591421210625, year='2010', volume='28', issue='15', pageStart='3', pageEnd='140', issueExtLink='null', onlineDate='null', pubDate='1278950400000', pubDateStr='2010-07-13', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=3, issueType=-1, specialIssue=null, createTime=1774074157929, creator='sys-migrate', updateTime=1774074157929, updator='sys-migrate', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=71, endPage=74, ext={EN=ArticleExt(id=1242120423773639260, articleId=1242120420200088074, tenantId=1146029695717560320, journalId=1146031591421210625, language=EN, title=Preparation and Catalytic Activity of CeO2/CNTs, columnId=1242116080374710456, journalTitle=Science & Technology Review, columnName=Articles, runingTitle=null, highlight=null, articleAbstract=CeO2/CNTs composite nanoparticles supported by self-made carbon nanotubes(CNTs) were prepared by the liquid-phase chemical deposition and the influences of surfactant on the preparation of composite nanoparticles were studied. The shape, the particle size and the crystal structure of the prepared nanoparticles were investigated by using TEM, XRD and FT-IR techniques. The results indicate that in certain conditions, the surfactant's bridging function improves the loading of the active components effectively, and evenly loaded CeO2/CNTs composite nanoparticles can be prepared based on Sodium Dodecyl Benzene Sulfonate. The supporting CeO2 nanoparticles were face-centered cubic crystals, with particle size of about 6.4nm. The mechanism of loading metal oxides on the surface of CNTs is discussed. On this basis, CNTs, CeO2 and CeO2/CNTs were used as the catalyst, respectively, in the nitric acid oxido-degradation of Dongdu weathered coal. The results show that CeO2/CNTs enjoy the best catalytic properties and could enhance the yield of the humic acid significantly as compared with other catalysts. Also, the prepared humic acid had the largest E4/E6 ratio, and the molecular weight of humic acid is smaller., authors=null, authorsList=null, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=QL1oh54GU4WmrRJ2gSgUyw==, pdfFileSize=777968, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1242120421433217620, articleId=1242120420200088074, tenantId=1146029695717560320, journalId=1146031591421210625, language=CN, title=CeO2/CNTs纳米复合粒子的制备及其催化性能, columnId=1146540929516700224, journalTitle=科技导报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=采用液相化学沉积法制备CeO2/CNTs纳米复合粒子,考查了表面活性剂对产物形貌的影响,采用TEM、XRD、FT-IR等手段对产物的形貌和晶相结构进行表征。结果表明,在一定条件下,表面活性剂的“桥接”作用有效地改善了活性组分的负载,以十二烷基苯磺酸钠为表面活性剂,以自制碳纳米管(CNTs)为载体,可以制备出负载均匀的CeO2/CNTs纳米复合粒子。探讨了活性组分CeO2在CNTs表面的负载机制,并在此基础上研究了所得样品在风化煤硝酸氧解制备腐植酸中的催化性能。催化结果表明,CeO2/CNTs纳米复合粒子的催化性能明显优于单纯的CeO2和CNTs的催化性能,能显著提高腐植酸的产率。, authors=侯珂珂1,崔 平2, authorsList=侯珂珂;崔 平, authorCompany=1. 许昌学院化学化工学院, 河南许昌 4610002. 安徽工业大学化学化工学院,安徽马鞍山 243002, correspAuthors=null, authorNote=null, correspAuthorsNote=侯珂珂, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=7Bifdht8xTZ+5hU6yi3dSQ==, pdfFileSize=777968, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null)}, authors=null, keywords=[Keyword(id=1242120421047337487, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242120420200088074, language=CN, orderNo=1, keyword=液相化学沉积法), Keyword(id=1242120421122834960, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242120420200088074, language=CN, orderNo=1, keyword=CeO2), Keyword(id=1242120421198332433, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242120420200088074, language=CN, orderNo=1, keyword=“桥接”作用), Keyword(id=1242120421273829906, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242120420200088074, language=CN, orderNo=1, keyword=催化性能), Keyword(id=1242120423370986071, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242120420200088074, language=EN, orderNo=1, keyword=liquid-phase chemical deposition), Keyword(id=1242120423450677849, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242120420200088074, language=EN, orderNo=1, keyword=CeO2), Keyword(id=1242120423526175322, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242120420200088074, language=EN, orderNo=1, keyword=bridges function), Keyword(id=1242120423614255707, tenantId=1146029695717560320, journalId=1146031591421210625, articleId=1242120420200088074, language=EN, orderNo=1, keyword=catalytic activity)], refs=null, funds=null, companyList=null, figs=null, attaches=null, journal=Journal(id=1125356956822126595, delFlag=0, nameCn=科技导报, nameEn=Science & Technology Review, nameHistory1=null, nameHistory2=null, issn=1000-7857, eissn=, cn=11-1421/N, coden=null, periodic=3, language=CN, oaType=0, ccby=null, superviseOffice=null, ownerOffice=null, pubOffice=null, editorOffice=null, officeType=null, aims=null, clcCode=null, officeProv=null, officeCity=null, officeAddr=null, officeZip=null, officeEmail=null, officePhone=null, editDirector=null, officeDirector=null, officeDirectorPhone=null, officeStaffNum=null, officeEmpNum=null, coverPicUrl=wfghvu3bhh/dKxuZ+ucVHA==, journalPrice=null, startedYear=null, abbrevIsoEn=Sci Technol Rev, journalRemark=null, publicationField=null, createdTime=null, updatedTime=1774230116083, createdBy=null, updatedBy=13041195026, firstLetterCn=S, firstLetterEn=S, subjectCode=Natural Sciences, subjectName=自然科学, subjectCodeEn=Natural Sciences, subjectNameEn=null, picCn=wfghvu3bhh/dKxuZ+ucVHA==, picEn=yjSfclmpNm7ihn9NbTZ69g==, jcr=null, cjcr=null, exts=[JournalExt(id=1242774439910290156, language=CN, name=科技导报, nameHistory1=null, nameHistory2=null, managedBy=中国科学技术协会, sponsoredBy=中国科学技术协会, publishedBy=科技导报社, editorOffice=, officeProv=null, officeCity=null, officeAddr=, officeZip=, editDirector=, officeDirector=null, officePhone=null, coverPicUrl=null, journalRemark=, submitArticleUrl=null, websiteUrl=http://www.kjdb.org/CN/home, createdTime=1774230116107, updatedTime=1774230116107, createdBy=13041195026, updatedBy=13041195026, submissionGuidelinesUrl=http://www.kjdb.org/CN/column/column7.shtml, submissionAuthorUrl=https://kjdbauthor.cast.org.cn/webm, submissionEditorUrl=https://kjdbeditor.cast.org.cn/webm/, submissionReviewUrl=https://kjdbauthor.cast.org.cn/webm, submissionCeEditorUrl=https://kjdbeditor.cast.org.cn/webm/, submissionAeEditorUrl=https://kjdbeditor.cast.org.cn/webm/, option={"copyright":""}), JournalExt(id=1242774439960621805, language=EN, name=Science & Technology Review, nameHistory1=null, nameHistory2=null, managedBy=, sponsoredBy=, publishedBy=, editorOffice=, officeProv=null, officeCity=null, officeAddr=, officeZip=, editDirector=, officeDirector=null, officePhone=null, coverPicUrl=null, journalRemark=, submitArticleUrl=null, websiteUrl=http://www.kjdb.org/EN/home, createdTime=1774230116119, updatedTime=1774230116119, createdBy=13041195026, updatedBy=13041195026, submissionGuidelinesUrl=http://www.kjdb.org/EN/column/column7.shtml, submissionAuthorUrl=https://kjdbauthor.manuscriptcloud.com/login, submissionEditorUrl=https://kjdbeditor.manuscriptcloud.com/login, submissionReviewUrl=https://kjdbauthor.manuscriptcloud.com/login, submissionCeEditorUrl=https://kjdbeditor.manuscriptcloud.com/login, submissionAeEditorUrl=https://kjdbeditor.manuscriptcloud.com/login, option={"copyright":""})], databaseList=null, tenantJournalId=1146031591421210625, websiteList=[Website(id=1146104741081231361, webName=null, webTitle=null, webDomain=null, webCopyrigh=null, webIpcNo=null, seoTitle=null, seoKeywords=null, seoDescription=null, tenantJournalId=null, journalId=1146031591421210625, journalNameCn=null, journalNameEn=null, grayFlag=null, tenantId=1146029695717560320, platformId=null, journalGroupId=null, journalGroupNameCn=null, journalGroupNameEn=null, type=1, domain=https://castjournals.cast.org.cn/joweb/kjdb/CN, language=CN, createTime=1751182263881, createBy=18614031015, updateTime=1751778001962, updateBy=18614031015, name=科技导报, tplId=1146099689490845704, title=科技导报, delFlag=0, indexPage=/home, props=[WebsiteProps(id=1148021146403992296, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146104741081231361, code=articleTextType, value=kx, createTime=1751639170504, updateTime=1751639170504, creator=18614031015, updator=18614031015), WebsiteProps(id=1148021146378826469, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146104741081231361, code=banner, value=null, createTime=1751639170498, updateTime=1751639170498, creator=18614031015, updator=18614031015), WebsiteProps(id=1148021146366243556, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146104741081231361, code=logo, value=https://castjournals.cast.org.cn/joweb/kjdb/CN/file/pic?fileId=9GHSf7eGlIPH0Tv/OOdstA==, createTime=1751639170495, updateTime=1751639170495, creator=18614031015, updator=18614031015), WebsiteProps(id=1148021146395603687, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146104741081231361, code=picServerUrl, value=https://castjournals.cast.org.cn/joweb/kjdb/CN/file/pic, createTime=1751639170502, updateTime=1751639170502, creator=18614031015, updator=18614031015), WebsiteProps(id=1148021146387215078, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146104741081231361, code=staticResourcePath, value=https://castjournals.cast.org.cn/joweb/cast_kjdb_cn_619/, createTime=1751639170500, updateTime=1751639170500, creator=18614031015, updator=18614031015)]), Website(id=1146105254833139715, webName=null, webTitle=null, webDomain=null, webCopyrigh=null, webIpcNo=null, seoTitle=null, seoKeywords=null, seoDescription=null, tenantJournalId=null, journalId=1146031591421210625, journalNameCn=null, journalNameEn=null, grayFlag=null, tenantId=1146029695717560320, platformId=null, journalGroupId=null, journalGroupNameCn=null, journalGroupNameEn=null, type=1, domain=https://castjournals.cast.org.cn/joweb/kjdb/EN, language=EN, createTime=1751182386363, createBy=18614031015, updateTime=1753500121937, updateBy=18614031015, name=科技导报, tplId=1146101810881728533, title=Science & Technology Review, delFlag=0, indexPage=/home, props=[WebsiteProps(id=1155838567709528217, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146105254833139715, code=articleTextType, value=kx, createTime=1753502988984, updateTime=1753502988984, creator=18614031015, updator=18614031015), WebsiteProps(id=1155838567692750998, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146105254833139715, code=banner, value=null, createTime=1753502988980, updateTime=1753502988980, creator=18614031015, updator=18614031015), WebsiteProps(id=1155838567688556693, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146105254833139715, code=logo, value=https://castjournals.cast.org.cn/joweb/kjdb/EN/file/pic?fileId=9GHSf7eGlIPH0Tv/OOdstA==, createTime=1753502988979, updateTime=1753502988979, creator=18614031015, updator=18614031015), WebsiteProps(id=1155838567705333912, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146105254833139715, code=picServerUrl, value=https://castjournals.cast.org.cn/joweb/kjdb/EN/file/pic, createTime=1753502988983, updateTime=1753502988983, creator=18614031015, updator=18614031015), WebsiteProps(id=1155838567701139607, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1146105254833139715, code=staticResourcePath, value=https://castjournals.cast.org.cn/joweb/cast_kjdb_en_623/, createTime=1753502988982, updateTime=1753502988982, creator=18614031015, updator=18614031015)])], journalTitle=科技导报, weixinUrl=null, journalUrl=null, iacademicId=null, status=1, seqNo=null, journalTitleEn=Science & Technology Review, journalPhotoCn=wfghvu3bhh/dKxuZ+ucVHA==, journalPhotoEn=yjSfclmpNm7ihn9NbTZ69g==, journalFirstLetter=S, journalRecommend=null, journalNew=null, journalCollection=1, jcrJf=null, cjcrJf=0.91, jcrJfStr=null, cjcrJfStr=null, submissionFirstDecision=null, sciSubjectClassification=null, casSubjectClassification=null, citeScore=null, totalCitationFrequency=null, icpCode=null, psCode=null, advertisingLicenseCode=null, copyrightInformation=null, country=null, option=, provinceCode=null, provinceName=null, collectFlag=false, interPubPlatform=null, interPubPlatformUrl=null), detailUrlCn=https://castjournals.cast.org.cn/joweb/kjdb/CN/Y2010/V28/I15/71, detailUrlEn=https://castjournals.cast.org.cn/joweb/kjdb/EN/Y2010/V28/I15/71, pdfUrlCn=https://castjournals.cast.org.cn/joweb/kjdb/CN/PDF/Y2010/V28/I15/71, pdfUrlEn=https://castjournals.cast.org.cn/joweb/kjdb/EN/PDF/Y2010/V28/I15/71, aliStartDate=null, aliEndDate=null, collectionFlag=false, citedCount=null, citedUrl=null, previewStatus=0, delFlag=0, hasFullText=0, orderTime=1278950400000, fullTextJson=null, articleText=null, reference=null)
收藏切换
CeO2/CNTs纳米复合粒子的制备及其催化性能
收藏切换
PDF下载
科技导报 | 研究论文 2010,28(15): 71-74
收起
收藏切换
科技导报 | 研究论文 2010, 28(15): 71-74
CeO2/CNTs纳米复合粒子的制备及其催化性能
全屏
侯珂珂1,崔 平2
作者信息
    1. 许昌学院化学化工学院, 河南许昌 4610002. 安徽工业大学化学化工学院,安徽马鞍山 243002

通讯作者:

侯珂珂
Preparation and Catalytic Activity of CeO2/CNTs
Affiliations
出版时间: 2010-07-13
文章导航
收藏切换
采用液相化学沉积法制备CeO2/CNTs纳米复合粒子,考查了表面活性剂对产物形貌的影响,采用TEM、XRD、FT-IR等手段对产物的形貌和晶相结构进行表征。结果表明,在一定条件下,表面活性剂的“桥接”作用有效地改善了活性组分的负载,以十二烷基苯磺酸钠为表面活性剂,以自制碳纳米管(CNTs)为载体,可以制备出负载均匀的CeO2/CNTs纳米复合粒子。探讨了活性组分CeO2在CNTs表面的负载机制,并在此基础上研究了所得样品在风化煤硝酸氧解制备腐植酸中的催化性能。催化结果表明,CeO2/CNTs纳米复合粒子的催化性能明显优于单纯的CeO2和CNTs的催化性能,能显著提高腐植酸的产率。
液相化学沉积法  /  CeO2  /  “桥接”作用  /  催化性能
CeO2/CNTs composite nanoparticles supported by self-made carbon nanotubes(CNTs) were prepared by the liquid-phase chemical deposition and the influences of surfactant on the preparation of composite nanoparticles were studied. The shape, the particle size and the crystal structure of the prepared nanoparticles were investigated by using TEM, XRD and FT-IR techniques. The results indicate that in certain conditions, the surfactant's bridging function improves the loading of the active components effectively, and evenly loaded CeO2/CNTs composite nanoparticles can be prepared based on Sodium Dodecyl Benzene Sulfonate. The supporting CeO2 nanoparticles were face-centered cubic crystals, with particle size of about 6.4nm. The mechanism of loading metal oxides on the surface of CNTs is discussed. On this basis, CNTs, CeO2 and CeO2/CNTs were used as the catalyst, respectively, in the nitric acid oxido-degradation of Dongdu weathered coal. The results show that CeO2/CNTs enjoy the best catalytic properties and could enhance the yield of the humic acid significantly as compared with other catalysts. Also, the prepared humic acid had the largest E4/E6 ratio, and the molecular weight of humic acid is smaller.
liquid-phase chemical deposition  /  CeO2  /  bridges function  /  catalytic activity
侯珂珂;崔 平. CeO2/CNTs纳米复合粒子的制备及其催化性能. 科技导报, 2010 , 28 (15) : 71 -74 .
. Preparation and Catalytic Activity of CeO2/CNTs[J]. Science & Technology Review, 2010 , 28 (15) : 71 -74 .
2010年第28卷第15期
PDF下载
110
47
引用本文
BibTeX
文章信息
  • 接收时间:2010-01-12
  • 首发时间:2010-07-13
  • 出版时间:2010-07-13
补充材料
相关文章
文章信息
作者
出版历史
  • 收稿日期:2010-01-12
  • 修回日期:2010-03-08
基金
作者信息

通讯作者:

侯珂珂
参考文献
分享链接
https://castjournals.cast.org.cn/joweb/kjdb/CN/1242120420200088074
分享至
全文二维码

扫描看全文

引用本文
BibTeX
本文的引用情况
2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
关闭全屏