Article(id=1242119519720771870, tenantId=1146029695717560320, journalId=1146031591421210625, issueId=1242119517489402136, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1253462400000, receivedDateStr=2009-09-21, revisedDate=1258387200000, revisedDateStr=2009-11-17, acceptedDate=null, acceptedDateStr=null, onlineDate=1265990400000, onlineDateStr=2010-02-13, pubDate=1265990400000, pubDateStr=2010-02-13, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1265990400000, onlineIssueDateStr=2010-02-13, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1774073970962, creator=sys-migrate, updateTime=1774073970962, updator=sys-migrate, issue=Issue{id=1242119517489402136, tenantId=1146029695717560320, journalId=1146031591421210625, year='2010', volume='28', issue='03', pageStart='1', pageEnd='139', issueExtLink='null', onlineDate='null', pubDate='1265990400000', pubDateStr='2010-02-13', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=3, issueType=-1, specialIssue=null, createTime=1774073970431, creator='sys-migrate', updateTime=1774073970431, updator='sys-migrate', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=37, endPage=40, ext={EN=ArticleExt(id=1242119524049293622, articleId=1242119519720771870, tenantId=1146029695717560320, journalId=1146031591421210625, language=EN, title=Hazard of Thermal Explosive of Dicumyl Peroxide, columnId=1242116080374710456, journalTitle=Science & Technology Review, columnName=Articles, runingTitle=null, highlight=null, articleAbstract=In order to prevent and reduce the fire explosion accidents in the process of manufacturing Dicumyl Peroxide (DCP), the thermal hazard of DCP, DCP/20% sodium carbonate and DCP/20% phenol are studied by the Accelerating Rate Calorimeter(ARC) under adiabatic environment. Their thermal stability characteristics, such as the onset exothermic temperature, the maximum temperature rise rate and the time-to-maximum rate, and the exothermal curves, were obtained. The test data were corrected by thermal inertia factors. The compatibility of DCP/20% sodium carbonate and DCP/20% phenol was calculated by using the theoretical model, consisting of two criteria: the initial exothermic temperature and the average acceleration. It can be seen from the results that the initial exothermic temperature of DCP, DCP/20% sodium carbonate and DCP/20% phenol are 97.47, 106.40 and 115.59℃, respectively. And the maximum temperature rise rates are 65.15, 2.15 and 3.44℃·min^-1, respectively, and the average accelerations are 0.2977, 0.0077 and 0.0127. Sodium carbonate and phenol have a good compatibility with DCP as catalysts in industrial yields; however, compared with phenol, sodium carbonate performs much better in manufacturing DCP., authors=null, authorsList=null, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=yNoXmH8RJLjkSucxrTOIkA==, pdfFileSize=2205328, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1242119522883272856, articleId=1242119519720771870, tenantId=1146029695717560320, journalId=1146031591421210625, language=CN, title=过氧化二异丙苯热爆炸危险性研究, columnId=1146540929516700224, journalTitle=科技导报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=为了预防和减少过氧化二异丙苯（DCP）生产过程发生火灾爆炸事故，利用绝热加速量热仪，对DCP、DCP/20%碳酸钠和DCP/20%苯酚的热危险性进行了实验研究，得到其初始放热温度、最大温升速率、最大温升速率时间等热危险性参数和绝热放热曲线；对3种物质的测试结果进行了绝热校正。利用绝热相容性评价的判据初始放热温度和平均加速度的理论模型，计算DCP/20%碳酸钠和DCP/20%苯酚的相容性。结果表明，DCP、DCP/20%碳酸钠和DCP/20%苯酚的初始放热温度分别为97.47、106.40和115.59℃，最大温升速率分别为65.15、2.15和3.44℃·min^-1，平均加速度分别为0.2977、0.0077和0.0127。在实际的工业生产中，所选取的碳酸钠和苯酚催化剂与DCP的相容性都较好，但比较二者发现，选用碳酸钠作为催化剂更为安全。, authors=臧娜, authorsList=臧娜, authorCompany=中国人民武装警察部队学院消防工程系，河北廊坊 065000, correspAuthors=null, authorNote=null, correspAuthorsNote=臧娜, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=tjGMiOus48hskQrUwAs90Q==, pdfFileSize=2205328, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null)}, authors=null, keywords=[Keyword(id=1242119522472231059, 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