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Therefore, coumarin-3-carboxylic acid eugenol ester can be used in cigarette as an excellent flavor precursor., authors=null, authorsList=null, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=Xu Cui lian, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=VWqaxg/GbwEcMSxtP0jRSw==, pdfFileSize=614473, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1242119415605560102, articleId=1242119413319664406, tenantId=1146029695717560320, journalId=1146031591421210625, language=CN, title=香豆素-3-甲酸丁香酚酯的合成、表征及在烟草中的应用, columnId=1146540929516700224, journalTitle=科技导报, columnName=研究论文, runingTitle=null, highlight=null, 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香豆素-3-甲酸丁香酚酯的合成、表征及在烟草中的应用
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科技导报 |研究论文 2010 , 28 (1001) : 35 -39
香豆素-3-甲酸丁香酚酯的合成、表征及在烟草中的应用
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徐翠莲1,刘善宇2,杨国玉1,姬小明2,樊素芳1,万峥凯1
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    1. 河南农业大学理学院,郑州 4500022. 河南农业大学烟草学院,郑州 450002
通讯作者:
徐翠莲
Synthesis and Characterization of Coumarin-3-Carboxylic Acid Eugenol Ester and Its Use in Cigarette as a Flavor
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      Corresponding Author:
      Xu Cui lian
    出版时间: 2010-01-13
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    为开发稳定的烟用香料前驱体,以香豆素-3-甲酸、丁香酚合成了香豆素-3-甲酸丁香酚酯,产物的结构经红外光谱(IR)、核磁共振氢谱(1HNMR)、核磁共振碳谱(13CNMR)、高分辨率质谱(HMRS)和综合热分析确证。采用热解-GC/MS对该化合物的热解产物进行分离鉴定,并初步进行了卷烟加香试验。结果表明:① 600℃时,香豆素-3-甲酸丁香酚酯的热解产物中共鉴定出22种成分,主要为烯类、烷类、酸类、酚类;② 鉴定出丁香酚,表明香豆素-3-甲酸丁香酚酯能在卷烟燃吸温度下释放出一定量的丁香酚;③ 香豆素-3-甲酸丁香酚酯具有改善和修饰卷烟香气,增加甜韵和豆香香韵,减轻刺激性的作用。因此,香豆素-3-甲酸和丁香酚可以作为香料前驱体应用于卷烟加香。
    香豆素-3-甲酸丁香酚酯  /  合成  /  表征  /  卷烟  /  香料
    In order to develop a new cigarette flavor precursor, coumarin-3-carboxylic acid eugenol ester was synthesized from coumarin-3-carboxylic acid and eugenol. The structure of the title compound was characterized by IR, 1HNMR, 13CNMR, HRMS and thermal analysis. The pyrolysis products were identified by means of pyrolysis-GC/MS, and the effect of the title compound on the flavor of cigarettes by smoking was evaluated. The results show that: (1) 22 compounds were identified at 600℃, and most of them were alkenes, alkanes, acids, and phenolic substances; (2) eugenol was identified, indicating that coumarin-3-carboxylic acid eugenol ester can release a certain amount of eugenol at the smoke temperature; (3) eugenol coumarin-3-carboxylic acid ester can improve and modify the flavor, enhance the notes of sweet aroma and bean aroma., and reduce the biting taste of cigarette smoke. Therefore, coumarin-3-carboxylic acid eugenol ester can be used in cigarette as an excellent flavor precursor.
    Coumarin-3-carboxylic acid eugenol ester  /  synthesis  /  characterization  /  cigarette  /  flavor
    徐翠莲;刘善宇;杨国玉;姬小明;樊素芳;万峥凯. 香豆素-3-甲酸丁香酚酯的合成、表征及在烟草中的应用. 科技导报, 2010 , 28 (1001) : 35 -39 .
    . Synthesis and Characterization of Coumarin-3-Carboxylic Acid Eugenol Ester and Its Use in Cigarette as a Flavor[J]. Science & Technology Review, 2010 , 28 (1001) : 35 -39 .

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    2种不同金属材料的力学参数

    Family
    属数
    Number of
    genus
    种数
    Number of
    species
    占总种数比例
    Percentage of
    total species (%)

    Genus
    种数
    Number of
    species
    占总种数比例
    Percentage of total
    species (%)
    鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
    小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
    多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
    红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
    小菇属 Mycena 11 5.26
    光柄菇属 Pluteus 5 2.39
    红菇属 Russula 17 8.13
    栓菌属 Trametes 5 2.39
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