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Cu2+/TiO2纳米溶胶制剂光催化性能
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科技导报 |研究论文 2010 , 28 (1001) : 30 -34
Cu2+/TiO2纳米溶胶制剂光催化性能
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李玲玲1,张阳德1,赵劲风2,李坚2,崔海信3,罗皓1,潘一峰2
作者信息
    1. 中南大学;卫生部肝胆肠外科研究中心, 长沙 4100082. 中南大学;卫生部纳米生物技术重点实验室, 长沙 4100083. 中国农业科学院农业环境与可持续发展研究所,北京 100081
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潘一峰
Study of cope ion on the photo-catalytic properties of TiO2
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    出版时间: 2010-01-13
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    以无机钛盐为原料,采用凝胶-溶胶法,制备二氧化钛纳米溶胶和掺入不同质量分数铜的Cu2+/TiO2纳米溶胶,对其进行表征。通过对甲基蓝光催化降解,对Cu2+/TiO2纳米溶胶和TiO2纳米溶胶的光催化活性进行比较,考察了聚合反应时间、表面活性剂、光照时间和强度、薄膜厚度、掺入铜离子浓度等因素对TiO2溶胶光催化活性的影响。结果表明,掺铜TiO2纳米溶胶的光催化活性较高,光催化性能优良,铜掺杂量为0.5%时效果较好。
    纳米  /  TiO2  /  光催化  /  离子掺杂  /  甲基蓝
    Nanometer TiO2 and Cu2+/TiO2 composite material was prepared by the sol-gel method. During the process of preparing the antibacterial TiO2 and Cu2+/TiO2, with various contents of Ti(SO4)2 and copper ion, a series of TiO2 sol and Cu2+/TiO2 sol were obtained. They were characterized with the laser diffraction particle size analyzer, XRD and TEM. The results show that the size of TiO2 grains ranges in 3.9~97.9nm, with an effective diameter of 63.6nm and a polydispersity of 0.222. The effective diameter of Cu2+/TiO2 is 58.4nm, with the polydispersity of 0.237. The TiO2 was anatase, and the diameter of Cu2+/TiO2 sol is slightly smaller than that of TiO2, but the performance against photodegradation may be better than TiO2 sol. TiO2 and Cu2+/TiO2 are compared by the catalytic degradation of methyl blue to see the impact of the polymerize reaction time, surfactant, light source, Cu2+/TiO2 film and the concentration of copper ion on the photo-catalytic of TiO2. Our experiments show that Cu2+/TiO2 sol has better photocatalytic activity than TiO2 sol, with the optimal concentration of copper ion of 0.5%.
    Nanometer  /  titania  /  photocatalysis  /  ion doping  /  methylene blue
    李玲玲;张阳德;赵劲风;李坚;崔海信;罗皓;潘一峰. Cu2+/TiO2纳米溶胶制剂光催化性能. 科技导报, 2010 , 28 (1001) : 30 -34 .
    . Study of cope ion on the photo-catalytic properties of TiO2[J]. Science & Technology Review, 2010 , 28 (1001) : 30 -34 .

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    • 接收时间:2009-07-14
    • 首发时间:2010-01-13
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    • 收稿日期:2009-07-14
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    2种不同金属材料的力学参数

    Family
    属数
    Number of
    genus
    种数
    Number of
    species
    占总种数比例
    Percentage of
    total species (%)

    Genus
    种数
    Number of
    species
    占总种数比例
    Percentage of total
    species (%)
    鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
    小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
    多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
    红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
    小菇属 Mycena 11 5.26
    光柄菇属 Pluteus 5 2.39
    红菇属 Russula 17 8.13
    栓菌属 Trametes 5 2.39
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