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We used common ferreous electrode as cathode and anode. By the process of DC, the ferreous anode dissolved and created Fe2+, and the ferrous sulfate in the liquid deoxidizes the Cr6+ to Cr3+; pH increased along with discharge of H+ at cathode . So the Cr3+ and Fe3+ come into chromic hydroxide and ferreous hydroxide, respectively. Simultaneity, the ferreous hydroxide which accelerates the chromium hydroxide to make deposition can be used as coagulation. Under the best experimental condition, the initial concentration of hoxavalent chromium is 600 mg/L or 600 mg/L hereinafter, pH=3, the quantity of FeSO4 is 1.20 g (Fe2+:Cr2O72+=1:1), reactive time is 40 min, exchange electrode cycle is 10min, electrical current consistency is 0.085 A/cm2, as a result effluent's concentration is 0.57 mg/L, and removal rate is 94%. 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科技导报
|实验技术
2006
, 24
(0611) :
58
-60
电解还原法处理含铬废水
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赵丽1 ,王成端1 ,赵诚1 ,杨晶2
作者信息
1. 西南科技大学环境与资源学院 四川绵阳2. 华南商贸职业学院 广州
通讯作者:
赵丽
The Treatment of Wastewater Containing Cr6+ Through Electroanalysis-deoxidization
Affiliations
出版时间: 2006-11-10
文章导航
采用电解还原方法模拟工业含铬废水的处理。试验以普通铁极板作阴阳极,在直流电的作用下,铁阳极溶解生成的Fe2+和硫酸亚铁中的Fe2+把废水中的六价铬离子还原成三价铬离子;随着氢离子阴极放电使废水pH值逐渐升高,Cr3+和Fe3+便形成氢氧化铬及氢氧化铁沉淀,同时氢氧化铁有凝聚作用,能促进氢氧化铬的迅速沉淀。在实验最佳条件下,废水初始含铬浓度在600mg/L及600mg/L以下、反应pH=3、加入FeSO4的量1.20g(Fe2+与Cr2O72+比例1∶1)、反应时间40min、换极周期10min、电流密度0.085A/cm2,出水浓度达到0.57mg/L,去除率为94%。出水浓度达到国家排放标准。
The article introduces the method of simulating electro-deoxidization to treat the industrial wastewater which contained Cr6+. We used common ferreous electrode as cathode and anode. By the process of DC, the ferreous anode dissolved and created Fe2+, and the ferrous sulfate in the liquid deoxidizes the Cr6+ to Cr3+; pH increased along with discharge of H+ at cathode . So the Cr3+ and Fe3+ come into chromic hydroxide and ferreous hydroxide, respectively. Simultaneity, the ferreous hydroxide which accelerates the chromium hydroxide to make deposition can be used as coagulation. Under the best experimental condition, the initial concentration of hoxavalent chromium is 600 mg/L or 600 mg/L hereinafter, pH=3, the quantity of FeSO4 is 1.20 g (Fe2+:Cr2O72+=1:1), reactive time is 40 min, exchange electrode cycle is 10min, electrical current consistency is 0.085 A/cm2, as a result effluent's concentration is 0.57 mg/L, and removal rate is 94%. Effluent's concentration achieves the national standard.
electroanalysis
/
deoxidization
/
chromium
/
wastewater
赵丽;王成端;赵诚;杨晶.
电解还原法处理含铬废水.
科技导报,
2006
, 24
(0611)
: 58
-60
.
.
The Treatment of Wastewater Containing Cr6+ Through Electroanalysis-deoxidization[J].
Science & Technology Review ,
2006
, 24
(0611)
: 58
-60
.
2006年第24卷第0611期
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接收时间:2009-08-18
首发时间:2006-11-10
出版时间:2006-11-10
收稿日期:2009-08-18
修回日期:1900-01-01
https://castjournals.cast.org.cn/joweb/kjdb/CN/1242117865688600665
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2种不同金属材料的力学参数
科 Family 属数 Number of genus 种数 Number of species 占总种数比例 Percentage of total species (%) 属 Genus 种数 Number of species 占总种数比例 Percentage of total species (%) 鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78 小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39 多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39 红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87 小菇属 Mycena 11 5.26 光柄菇属 Pluteus 5 2.39 红菇属 Russula 17 8.13 栓菌属 Trametes 5 2.39
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