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温度对高岭石吸附水溶液中铅离子的影响
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温度对高岭石吸附水溶液中铅离子的影响
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王学松1,黄宗行1,胡海琼1,王静1,孙成 2
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    1. 淮海工学院化学工程系2. 南京大学环境学院
通讯作者:
王学松
Effects of Temperature on the Sorption of Pb2+ from Aqueous Solution by Natural Kaolinite
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    出版时间: 2006-12-10
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    研究了温度的变化对高岭石吸附水溶液中铅离子的影响,结果表明,实验数据更好地符合Freundlich吸附等温方程。热力学参数(ΔG°,ΔH°)的数值指示了该吸附过程是自发的和吸热的。利用黏附几率进一步考察了高岭石作为吸附剂处理水溶液中铅离子的机理,结果表明,该吸附过程主要为物理吸附所主导。
    高岭石  /  吸附  /  铅离子  /  活化能  /  黏附几率
    This report is based on the investigation of the effects of temperature on the removal of Pb2+ in aqueous effluent using natural kaolinite in a batch sorption process. The result showed that the experimental data are in good agreement with the Freundlich isotherm. Various thermodynamic parameters, such as ΔG°, ΔH°, ΔS° and Ea have been calculated. The data showed that the sorption process is spontaneous and endothermic in nature. The sticking probability model was further employed to assess the applicability of the natural kaolinite as an alternative adsorbent for Pb2+ in aqueous system. The findings of this investigation suggest that physical sorption plays a role in controlling the sorption rate.
    kaolinite  /  adsorption  /  lead ions  /  activation energy  /  sticking probability
    王学松;黄宗行;胡海琼;王静;孙成. 温度对高岭石吸附水溶液中铅离子的影响. 科技导报, 2006 , 24 (0612) : 27 -30 .
    . Effects of Temperature on the Sorption of Pb2+ from Aqueous Solution by Natural Kaolinite[J]. Science & Technology Review, 2006 , 24 (0612) : 27 -30 .

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    2种不同金属材料的力学参数

    Family
    属数
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    genus
    种数
    Number of
    species
    占总种数比例
    Percentage of
    total species (%)

    Genus
    种数
    Number of
    species
    占总种数比例
    Percentage of total
    species (%)
    鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
    小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
    多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
    红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
    小菇属 Mycena 11 5.26
    光柄菇属 Pluteus 5 2.39
    红菇属 Russula 17 8.13
    栓菌属 Trametes 5 2.39
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