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生物降解材料聚乳酸-聚乙二醇的合成及表征
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科技导报 | 研究论文 2009,27(0913): 7-8
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科技导报 |研究论文 2009 , 27 (0913) : 7 -8
生物降解材料聚乳酸-聚乙二醇的合成及表征
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陈佑宁1,樊国栋2,杨小玲1
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    1. 咸阳师范学院2. 陕西科技大学化学与化工学院
通讯作者:
陈佑宁
Synthesis of Polylactic Acid-Polyethylene Glycol via Melt Copolymerization
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    出版时间: 2009-07-13
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    采用熔融共聚法合成聚乳酸-聚乙二醇,探讨了催化剂种类及其用量、反应温度、反应时间、聚乙二醇的种类及其用量对产物分子量的影响,并对产物进行了表征。实验结果表明,170℃,0.8%辛酸亚锡催化作用下,乳酸与1% PEG400共聚10 h可合成黏均分子量为2.79×104的PLA-PEG共聚物,且亲水性有较大改善。
    聚乳酸-聚乙二醇(PLA-PEG)共聚物  /  熔融共聚  /  合成
    In this study, Polylactic Acid-Polyethylene glycol (PLA-PEG) was synthesized via melt copolymerization. The influence of the type and the amount of catalyst, the reaction temperature, the reaction time, the type and the amount of PEG on molecular weights of products are discussed. The performances of products are analyzed. The results show that from lactic acid and 1% polyethylene glycol(PEG)[Mn=400] with 0.8% stannous tin as catalyst, under the condition of 170℃, for 10 h, one obtains Polylactic Acid-Polyethylene glycol(M?浊=2.79×104), with improved hydrophilicity.
    polylactic acid-polyethylene glycol  /  melt copolymerization  /  synthesize
    陈佑宁;樊国栋;杨小玲. 生物降解材料聚乳酸-聚乙二醇的合成及表征. 科技导报, 2009 , 27 (0913) : 7 -8 .
    . Synthesis of Polylactic Acid-Polyethylene Glycol via Melt Copolymerization[J]. Science & Technology Review, 2009 , 27 (0913) : 7 -8 .

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    • 接收时间:2009-04-03
    • 首发时间:2009-07-13
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    2种不同金属材料的力学参数

    Family
    属数
    Number of
    genus
    种数
    Number of
    species
    占总种数比例
    Percentage of
    total species (%)

    Genus
    种数
    Number of
    species
    占总种数比例
    Percentage of total
    species (%)
    鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
    小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
    多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
    红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
    小菇属 Mycena 11 5.26
    光柄菇属 Pluteus 5 2.39
    红菇属 Russula 17 8.13
    栓菌属 Trametes 5 2.39
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