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Electrochromic (EC) materials can reversibly change their optical properties upon charge insertion/extraction, usually with low power consumption, high Coloration Efficiency (CE), and excellent memory effect under an open circuit condition. Hence they have received great attention in the past decades. EC materials can be classified into two categories as anode colored and cathode colored materials by electrochemical reaction modes. As a kind of anode colored materials, NiO is one of most attractive materials due to its high electrochromic efficiency, large dynamic range, good cyclic reversibility, and low cost. Several physical and chemical methods have been used to fabricate nickel oxide films. For example, sputter coating, vacuum evaporation, pulsed laser deposition, spray pyrolysis, sol-gel, chemical deposition and electrochemical deposition. However, the materials prepared by above methods must subject to an post-annealing process in order to show electrochromic properties. In this paper, NiO thin films with reversible electrochromic properties are fabricated using electrochemical technique in organic solutions (N,N-dimethylformamide solution, DMF solution) controlled by potentiostatic electrolysis. Fluorine-doped tin oxide (SnO2:F, FTO) glass plates are used as substrates as well as cathodes. Appropriate experimental conditions for the film deposition are chosen based on our investigation on the effect of solvent dehydration methods and electrodeposition voltages. XRD, SEM, HRTEM and EDS are employed to analyze the composition, structure and thickness of the films. Ultraviolet-visible transmission spectroscopy is applied to measure electrochromic properties of the deposited films. 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科技导报
|研究论文
2009
, 27
(0918) :
66
-70
NiO电致变色薄膜的电化学制备和性能
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孙武珠;苏革;曹立新;柳伟;贾波;王景;董征
作者信息
Fabrication of NiO Electrochromics Films by Electrodeposition and Their Properties
Affiliations
出版时间: 2009-09-28
文章导航
以N,N-二甲基甲酰胺为溶剂、NiCl2为主盐、LiClO4为支持电解质、FTO导电玻璃为基体,采用恒电位电沉积的方法制备了电致变色性能良好的NiO薄膜。实验过程中对溶剂脱水方法、电沉积电压等实验条件进行了研究,探索在此体系中电沉积的最佳条件,制备出电致变色性能和附着性良好的NiO薄膜;通过X射线衍射仪、扫描电镜、高分辨透射电镜和能谱仪等仪器,对膜的成分、结构和厚度进行了分析;采用紫外可见分光光度计,对膜的透光性能进行了表征;通过循环伏安法和双电位阶跃法,对膜的电化学稳定性和响应时间进行研究。
Electrochromism can be defined as a persistent and reversible optical transformation induced by electrochemical processes. Electrochromic (EC) materials can reversibly change their optical properties upon charge insertion/extraction, usually with low power consumption, high Coloration Efficiency (CE), and excellent memory effect under an open circuit condition. Hence they have received great attention in the past decades. EC materials can be classified into two categories as anode colored and cathode colored materials by electrochemical reaction modes. As a kind of anode colored materials, NiO is one of most attractive materials due to its high electrochromic efficiency, large dynamic range, good cyclic reversibility, and low cost. Several physical and chemical methods have been used to fabricate nickel oxide films. For example, sputter coating, vacuum evaporation, pulsed laser deposition, spray pyrolysis, sol-gel, chemical deposition and electrochemical deposition. However, the materials prepared by above methods must subject to an post-annealing process in order to show electrochromic properties. In this paper, NiO thin films with reversible electrochromic properties are fabricated using electrochemical technique in organic solutions (N,N-dimethylformamide solution, DMF solution) controlled by potentiostatic electrolysis. Fluorine-doped tin oxide (SnO2:F, FTO) glass plates are used as substrates as well as cathodes. Appropriate experimental conditions for the film deposition are chosen based on our investigation on the effect of solvent dehydration methods and electrodeposition voltages. XRD, SEM, HRTEM and EDS are employed to analyze the composition, structure and thickness of the films. Ultraviolet-visible transmission spectroscopy is applied to measure electrochromic properties of the deposited films. Cyclic voltammetry and double potential step technique are used to study the electrochromic processes.
electrochromics
/
electrochemical deposition
/
NiO thin film
孙武珠;苏革;曹立新;柳伟;贾波;王景;董征.
NiO电致变色薄膜的电化学制备和性能.
科技导报,
2009
, 27
(0918)
: 66
-70
.
.
Fabrication of NiO Electrochromics Films by Electrodeposition and Their Properties[J].
Science & Technology Review ,
2009
, 27
(0918)
: 66
-70
.
2009年第27卷第0918期
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接收时间:2009-06-19
首发时间:2009-09-28
出版时间:2009-09-28
收稿日期:2009-06-19
修回日期:2009-09-01
https://castjournals.cast.org.cn/joweb/kjdb/CN/1242117228229891016
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2种不同金属材料的力学参数
科 Family 属数 Number of genus 种数 Number of species 占总种数比例 Percentage of total species (%) 属 Genus 种数 Number of species 占总种数比例 Percentage of total species (%) 鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78 小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39 多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39 红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87 小菇属 Mycena 11 5.26 光柄菇属 Pluteus 5 2.39 红菇属 Russula 17 8.13 栓菌属 Trametes 5 2.39
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