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亚胺类共价有机框架研究进展
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楚正坤, 刘洁
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    苏州科技大学化学与生命科学学院, 苏州 215009

通讯作者:

刘洁(通信作者),副教授,研究方向为材料化学,电子信箱:jliu@mail.usts.edu.cn
Research progress of imine covalent organic frameworks
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出版时间: 2024-01-28 doi: 10.3981/j.issn.1000-7857.2024.02.007
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亚胺类共价有机框架(imine covalent organic frameworks,Imine COFs)材料是芳香胺和芳香醛单体根据席夫碱反应原理缩合形成的一类多孔有机晶体材料。Imine COFs材料具有大的比表面积、高孔隙率、易功能化和可设计性强等优点,已成为近年研究最为广泛的一类COFs材料。从设计、合成方法和应用等方面综述了 Imine COFs 材料的研究进展;基于该领域现状,概述了在新型 COFs材料构筑及工业化应用进展上目前存在的困难,提出了优化合成方法、探索工业化应用条件、开发多功能复合纳米Imine-COFs及阐明材料理化性能基本原理等未来研究趋势。
共价有机框架  /  亚胺类材料  /  晶体材料  /  多孔材料  /  有机材料
Imine Covalent Organic Frameworks (Imine COFs) are a kind of porous organic crystal materials formed by the condensation of aromatic amines and aromatic aldehydes according to the Schiff-base reaction principle. Imine COFs have become the most widely studied COFs materials in recent years due to their advantages of large specific surface area, high porosity, easy functionalization and strong designability. The latest research progress of Imine COFs materials in recent years is reviewed from the aspects of design, synthesis methods and applications. Based on the current status of this field, the existing difficulties in the progress of novel COFs material construction and industrial applications are outlined, and future research trends are proposed, including optimizing the synthesis methods, exploring the conditions for industrial applications, developing multifunctional composite nano-Imine-COFs, and emphasizing the fundamentals of the materials' physicochemical properties, in order to provide ideas for the in-depth research and practical application of Imine COFs materials.
covalent organic frameworks  /  imines materials  /  crystals materials  /  porous materials  /  organic materials
楚正坤, 刘洁. 亚胺类共价有机框架研究进展. 科技导报, 2024 , 42 (2) : 67 -78 . DOI: 10.3981/j.issn.1000-7857.2024.02.007
CHU Zhengkun, LIU Jie. Research progress of imine covalent organic frameworks[J]. Science & Technology Review, 2024 , 42 (2) : 67 -78 . DOI: 10.3981/j.issn.1000-7857.2024.02.007
2024年第42卷第2期
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doi: 10.3981/j.issn.1000-7857.2024.02.007
  • 接收时间:2022-08-19
  • 首发时间:2024-04-15
  • 出版时间:2024-01-28
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  • 收稿日期:2022-08-19
  • 修回日期:2023-02-03
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刘洁(通信作者),副教授,研究方向为材料化学,电子信箱:jliu@mail.usts.edu.cn
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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