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2. Shaanxi Xixian New Area Jinghe Xincheng Water Affairs Co., Xi'an 710048, China, fund=null, authors=LI Huanhuan1, LI Haihong1*, WU Danping2, authorsList=LI Huanhuan, LI Haihong, WU Danping), CN=ArticleExt(id=1242140498694054309, articleId=1242140495472833482, tenantId=1146029695717560320, journalId=1146031591421210625, language=CN, title=Plackett-Burman设计联合Box-Behnken响应面法优化改性生物炭对亚甲基蓝的吸附工艺, columnId=1242140490116707244, journalTitle=科技导报, columnName=专题:环境污染与绿色发展, runingTitle=null, highlight=null, articleAbstract=以柠檬酸改性辣椒秸秆基生物炭为对象,研究其对亚甲基蓝吸附过程的最优工艺。以改性炭投加量、亚甲基蓝浓度、吸附时间、温度、溶液 pH值、摇床转速为考察因素,亚甲基蓝吸附量为考察指标,利用 Plackett-Burman(P-B)设计筛选出具有显著效应的因素,进一步结合 Box-Behnken Design(BBD)响应面法对显著性因素进行优化,并加以验证分析,得到最佳吸附工艺参数。结果表明:在选定的6个因素中,影响亚甲基蓝吸附量的显著性顺序为改性炭投加量>亚甲基蓝浓度>摇床转速;优化后最佳吸附条件是:改性炭投加量为45.40 mg、亚甲基蓝浓度为 86 mg/L、摇床转速为 130 r/min,在该条件下亚甲基蓝吸附量可达 41.03 mg/g。经验证,与模型预测值 42.24 mg/g相差 2.87%,因此 P-B/BBD 法在优化改性生物炭吸附亚甲基蓝的工艺中稳定有效,为优化炭材料的吸附工艺提供了数据参考。, correspAuthors=null, authorNote=李欢欢,硕士研究生,研究方向为工业废水处理,电子信箱:1421696305@qq.com, correspAuthorsNote=李海红(通信作者),教授,研究方向为新型环保材料研发及工业废水处理,电子信箱:1624116019@qq.com, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=nkGhORsWXLtVfVdiQcw3WA==, pdfFileSize=2501016, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, authorCompany=1. 西安工程大学环境与化学工程学院,西安 710048
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科技导报 | 专题:环境污染与绿色发展 2023, 41(11): 80-88
Plackett-Burman设计联合Box-Behnken响应面法优化改性生物炭对亚甲基蓝的吸附工艺
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李欢欢1,李海红1*,吴丹萍2
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    1. 西安工程大学环境与化学工程学院,西安 710048
    2. 陕西西咸新区泾河新城水务有限公司,西安 710048

通讯作者:

李海红(通信作者),教授,研究方向为新型环保材料研发及工业废水处理,电子信箱:1624116019@qq.com
Optimize the adsorption process of methylene blue by modified biochar
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出版时间: 2023-06-13 doi: 10.3981/j.issn.1000-7857.2023.11.008
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以柠檬酸改性辣椒秸秆基生物炭为对象,研究其对亚甲基蓝吸附过程的最优工艺。以改性炭投加量、亚甲基蓝浓度、吸附时间、温度、溶液 pH值、摇床转速为考察因素,亚甲基蓝吸附量为考察指标,利用 Plackett-Burman(P-B)设计筛选出具有显著效应的因素,进一步结合 Box-Behnken Design(BBD)响应面法对显著性因素进行优化,并加以验证分析,得到最佳吸附工艺参数。结果表明:在选定的6个因素中,影响亚甲基蓝吸附量的显著性顺序为改性炭投加量>亚甲基蓝浓度>摇床转速;优化后最佳吸附条件是:改性炭投加量为45.40 mg、亚甲基蓝浓度为 86 mg/L、摇床转速为 130 r/min,在该条件下亚甲基蓝吸附量可达 41.03 mg/g。经验证,与模型预测值 42.24 mg/g相差 2.87%,因此 P-B/BBD 法在优化改性生物炭吸附亚甲基蓝的工艺中稳定有效,为优化炭材料的吸附工艺提供了数据参考。
改性生物炭  /  亚甲基蓝  /  吸附工艺  /  Plackett-Burman设计  /  Box-Behnken响应面法
Taking citric acid-modified pepper straw-based biochar as the object, an optimal process for the adsorption process of methylene blue was studied. The dosage of modified carbon, methylene blue concentration, adsorption time, temperature, solution pH, and shaker speed were taken as investigation factors and methylene blue adsorption as investigation index, the Plackett-Burman (P-B) design was used to screen out the factors of significant effects. And further combined with the Box-Behnken Design (BBD) response surface method, the significant factors were optimized and verified and analyzed to obtain the optimal adsorption process parameters. The results showed that among the selected 6 factors, the order of significance affecting the adsorption capacity of methylene blue was modified carbon dosage > methylene blue concentration > shaking table rotation speed. The interaction effect between the significant factors was as follows: dosage of modified carbon and rotating speed of shaking table > dosage of modified carbon and concentration of methylene blue > concentration of methylene blue and rotating speed of shaking table. After optimization, the optimum adsorption conditions were obtained as follows: the dosage of modified carbon was 45.40 mg, the concentration of methylene blue was 86.00 mg/L, and the rotating speed of the shaking table was 130 r/min. Under these conditions, the adsorption capacity of methylene blue could reach 41.03 mg/g, the difference between the verified value and the model predicted value of 42.24 mg/g was 2.87%, therefore, the P-B/BBD method is stable and effective in optimizing the adsorption process of modified biochar for methylene blue, which provides a data reference for optimizing the adsorption process of carbon materials.
modified biochar  /  methylene blue  /  adsorption process  /  Plackett-Burman design  /  Box-Behnken response surface method
李欢欢,李海红,吴丹萍. Plackett-Burman设计联合Box-Behnken响应面法优化改性生物炭对亚甲基蓝的吸附工艺. 科技导报, 2023 , 41 (11) : 80 -88 . DOI: 10.3981/j.issn.1000-7857.2023.11.008
LI Huanhuan, LI Haihong, WU Danping. Optimize the adsorption process of methylene blue by modified biochar[J]. Science & Technology Review, 2023 , 41 (11) : 80 -88 . DOI: 10.3981/j.issn.1000-7857.2023.11.008
2023年第41卷第11期
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doi: 10.3981/j.issn.1000-7857.2023.11.008
  • 接收时间:2022-04-18
  • 首发时间:2023-06-29
  • 出版时间:2023-06-13
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  • 收稿日期:2022-04-18
  • 修回日期:2023-01-12
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李海红(通信作者),教授,研究方向为新型环保材料研发及工业废水处理,电子信箱:1624116019@qq.com
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Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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