Article(id=1242140147379150899, tenantId=1146029695717560320, journalId=1146031591421210625, issueId=1242140146309603376, articleNumber=null, orderNo=3, doi=10.3981/j.issn.1000-7857.2022.23.001, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1662480000000, receivedDateStr=2022-09-07, revisedDate=1666886400000, revisedDateStr=2022-10-28, acceptedDate=null, acceptedDateStr=null, onlineDate=1670838031943, onlineDateStr=2022-12-12, pubDate=1670860800000, pubDateStr=2022-12-13, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1670838031943, onlineIssueDateStr=2022-12-12, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1774078888980, creator=sys-migrate, updateTime=1774078888980, updator=sys-migrate, issue=Issue{id=1242140146309603376, tenantId=1146029695717560320, journalId=1146031591421210625, year='2022', volume='40', issue='23', pageStart='1', pageEnd='120', issueExtLink='null', onlineDate='null', pubDate='1670860800000', pubDateStr='2022-12-13', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=3, issueType=-1, specialIssue=null, createTime=1774078888726, creator='sys-migrate', updateTime=1774078888726, updator='sys-migrate', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=6, endPage=23, ext={EN=ArticleExt(id=1242140153720943061, articleId=1242140147379150899, tenantId=1146029695717560320, journalId=1146031591421210625, language=EN, title=Solid state Mg-based hydrogen storage materials: Research progress and future perspective, columnId=1242137384486249344, journalTitle=Science & Technology Review, columnName=Special to S&T Review, runingTitle=null, highlight=null, articleAbstract=Magnesium-based hydrogen storage materials have the advantages of high hydrogen storage capacity, abundant magnesium resources and low cost, and are considered to be of promising application prospects. In recent years, numerous researches have focused on improving the performance of hydrogen supply by pyrolysis/hydrolysis of MgH2 and many good achievements have been obtained. Based on the recent research progress, this paper summarizes the effects of the material/ structure modification and the reaction conditions on pyrolysis/hydrolysis performance of the magnesium-based hydrogen storage materials, and expounds the relationship between composition-microstructure-properties of solid Mg-based hydrogen storage materials. Meanwhile, the Mg-based hydrogen storage systems and their industrial applications are summarized. At last, the current results of the solid state Mg-based hydrogen storage are summarized and some suggestions for the future investigations are proposed., authors=ZHANG Qiuyu1,2 , REN Li1,2 , LI Yinghui1,2 , LIN Xi1,2,3 , YANG Haiyan1,2 , ZHANG Song4 , MAO Zhengsong4 , ZOU Jianxin1,2,3 , DING Wenjiang1,2,3 , authorsList=ZHANG Qiuyu, REN Li, LI Yinghui, LIN Xi, YANG Haiyan, ZHANG Song, MAO Zhengsong, ZOU Jianxin, DING Wenjiang, authorCompany=1. Shanghai Key Laboratory of Hydrogen Science & Center of Hydrogen Science, Shanghai Jiao Tong University, Shanghai 200240, China;2 的热分解放氢焓值高（75 kJ/mol H2 ），造成其放氢温度较高、动力学差； MgH2 的水解过程中，由于常温水解产物Mg（OH）2 逐渐包裹在MgH2 表面，阻隔了MgH2 与水的接触，从而导致水解产氢效率较低。近年来，大量研究工作聚焦于改善MgH2 的热解/水解供氢性能及实际应用，已经取得了大量成果。针对目前国内外镁基固态储氢材料的研发，总结了材料/结构改性、反应条件对镁基储氢材料的热解/水解性能的影响，重点阐述了固态镁基储氢材料组成成分-微观结构-储放氢性能之间的关系，并对镁基储氢系统及实际应用场景进行了归纳。未来通过镁基固态储运氢技术的发展，将实现氢气的高安全、高效及大规模储运，助力中国氢能产业的发展。, authors=张秋雨1,2 , 任莉1,2 , 李映辉1,2 , 林羲1,2,3 , 杨海燕1,2 , 张松4 , 毛正松4 , 邹建新1,2,3 , 丁文江1,2,3 , authorsList=张秋雨, 任莉, 李映辉, 林羲, 杨海燕, 张松, 毛正松, 邹建新, 丁文江, authorCompany=1. 上海市氢科学重点实验室&上海交通大学氢科学中心, 上海 200240;
科技导报
|专稿
2022
, 40
(23) :
6
-23
镁基固态储氢材料研究进展
全屏
张秋雨1,2 , 任莉1,2 , 李映辉1,2 , 林羲1,2,3 , 杨海燕1,2 , 张松4 , 毛正松4 , 邹建新1,2,3 , 丁文江1,2,3
作者信息
1. 上海市氢科学重点实验室&上海交通大学氢科学中心, 上海 200240;
通讯作者:
邹建新(通信作者),教授,研究方向为镁基氢化物储氢材料、金属气相反应机理、纳米功能材料制备与表征以及纳米材料在能源方面的应用,电子信箱:zoujx@sjtu.edu.cn;丁文江(共同通信作者),教授,中国工程院院士,研究方向为先进镁合金材料及加工,电子信箱:wjding@sjtu.edu.cn
作者简介:
张秋雨，博士后，研究方向为新型镁基储氢材料，电子信箱： zhangqiuyu20181113@126.com
Solid state Mg-based hydrogen storage materials: Research progress and future perspective
ZHANG Qiuyu1,2 , REN Li1,2 , LI Yinghui1,2 , LIN Xi1,2,3 , YANG Haiyan1,2 , ZHANG Song4 , MAO Zhengsong4 , ZOU Jianxin1,2,3 , DING Wenjiang1,2,3
Affiliations
1. Shanghai Key Laboratory of Hydrogen Science & Center of Hydrogen Science, Shanghai Jiao Tong University, Shanghai 200240, China;
出版时间: 2022-12-13
doi: 10.3981/j.issn.1000-7857.2022.23.001
文章导航
镁基储氢材料具有储氢量高、镁资源丰富以及成本低廉等优点，被认为是极具应用前景的一类固态储氢材料。利用镁基储氢材料供氢主要有热分解放氢和水解产氢2种途径。MgH2 的热分解放氢焓值高（75 kJ/mol H2 ），造成其放氢温度较高、动力学差； MgH2 的水解过程中，由于常温水解产物Mg（OH）2 逐渐包裹在MgH2 表面，阻隔了MgH2 与水的接触，从而导致水解产氢效率较低。近年来，大量研究工作聚焦于改善MgH2 的热解/水解供氢性能及实际应用，已经取得了大量成果。针对目前国内外镁基固态储氢材料的研发，总结了材料/结构改性、反应条件对镁基储氢材料的热解/水解性能的影响，重点阐述了固态镁基储氢材料组成成分-微观结构-储放氢性能之间的关系，并对镁基储氢系统及实际应用场景进行了归纳。未来通过镁基固态储运氢技术的发展，将实现氢气的高安全、高效及大规模储运，助力中国氢能产业的发展。
镁基储氢材料
/
水解产氢
/
镁基固态储运氢系统
/
储氢性能
Magnesium-based hydrogen storage materials have the advantages of high hydrogen storage capacity, abundant magnesium resources and low cost, and are considered to be of promising application prospects. In recent years, numerous researches have focused on improving the performance of hydrogen supply by pyrolysis/hydrolysis of MgH2 and many good achievements have been obtained. Based on the recent research progress, this paper summarizes the effects of the material/ structure modification and the reaction conditions on pyrolysis/hydrolysis performance of the magnesium-based hydrogen storage materials, and expounds the relationship between composition-microstructure-properties of solid Mg-based hydrogen storage materials. Meanwhile, the Mg-based hydrogen storage systems and their industrial applications are summarized. At last, the current results of the solid state Mg-based hydrogen storage are summarized and some suggestions for the future investigations are proposed.
Mg-based hydrogen storage materials
/
hydrolysis to produce hydrogen
/
Mg-based solid state hydrogen storage and transportation systems
/
hydrogen storage properties
张秋雨, 任莉, 李映辉, 林羲, 杨海燕, 张松, 毛正松, 邹建新, 丁文江.
镁基固态储氢材料研究进展.
科技导报,
2022
, 40
(23)
: 6
-23
.
DOI: 10.3981/j.issn.1000-7857.2022.23.001
ZHANG Qiuyu, REN Li, LI Yinghui, LIN Xi, YANG Haiyan, ZHANG Song, MAO Zhengsong, ZOU Jianxin, DING Wenjiang.
Solid state Mg-based hydrogen storage materials: Research progress and future perspective[J].
Science & Technology Review ,
2022
, 40
(23)
: 6
-23
.
DOI: 10.3981/j.issn.1000-7857.2022.23.001
2022年第40卷第23期
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文章信息
doi: 10.3981/j.issn.1000-7857.2022.23.001
接收时间：2022-09-07
首发时间：2022-12-12
出版时间：2022-12-13
收稿日期：2022-09-07
修回日期：2022-10-28
通讯作者:
邹建新(通信作者),教授,研究方向为镁基氢化物储氢材料、金属气相反应机理、纳米功能材料制备与表征以及纳米材料在能源方面的应用,电子信箱:zoujx@sjtu.edu.cn;丁文江(共同通信作者),教授,中国工程院院士,研究方向为先进镁合金材料及加工,电子信箱:wjding@sjtu.edu.cn
https://castjournals.cast.org.cn/joweb/kjdb/CN/10.3981/j.issn.1000-7857.2022.23.001
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2种不同金属材料的力学参数
科 属数 种数 占总种数比例 属 种数 占总种数比例 鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78 小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39 多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39 红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87 小菇属 Mycena 11 5.26 光柄菇属 Pluteus 5 2.39 红菇属 Russula 17 8.13 栓菌属 Trametes 5 2.39
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