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CO2选择性加氢制甲醇非铜基催化剂研究进展
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CO2选择性加氢制甲醇非铜基催化剂研究进展
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沙峰1,2, 韩哲1,2, 汤驰洲2, 唐珊2, 王集杰2, 李灿2
作者信息
    1. 南开大学材料科学与工程学院, 天津 300350;
    2. 中国科学院大连化学物理研究所, 催化基础国家重点实验室, 洁净能源国家实验室(筹), 大连 116023

通讯作者:

李灿(通信作者),研究员,中国科学院院士,研究方向为催化材料、催化反应和光谱表征,电子信箱:canli@dicp.ac.cn
Research progress of non-copper-based catalysts for selective hydrogenation of carbon dioxide to methanol
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出版时间: 2020-12-13 doi: 10.3981/j.issn.1000-7857.2020.23.012
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综述了CO2选择性加氢制甲醇非铜基催化剂的研究进展,着重讨论了负载型金属催化剂、双金属催化剂、固溶体催化剂、氧化铟基催化剂。分析表明,以MaZrOx(Ma=Zn,Ga,Cd)固溶体催化剂为代表的新兴复合氧化物催化剂及In2O3基催化剂,可同时实现高甲醇选择性、高甲醇收率、良好稳定性,极具大规模工业化应用前景。
CO2  /  甲醇  /  液态阳光  /  多相催化
Carbon dioxide is one of the most important greenhouse gases that cause global climate change. Reducing carbon dioxide emissions and converting it to chemicals and fuels with high-value are of great significance for sustainable development. Carbon dioxide hydrogenation to methanol utilizing green hydrogen produced from renewable resources such as solar energy is one of the important ways to solve the greenhouse effect and develop green energy. In recent years, non-copper-based catalysts represented by solid solutions have developed rapidly, showing good industrial application prospects. This paper reviews the research progress of non-copper-based catalysts for selective hydrogenation of carbon dioxide to methanol, with focuses on supported metal catalysts, bimetallic catalysts, solid solution catalysts, and indium oxide-based catalysts, so as to provide references for the design of efficient and stable methanol synthesis catalysts.
carbon dioxide  /  methanol  /  liquid sunlight  /  heterogeneous catalysis
沙峰, 韩哲, 汤驰洲, 唐珊, 王集杰, 李灿. CO2选择性加氢制甲醇非铜基催化剂研究进展. 科技导报, 2020 , 38 (23) : 113 -127 . DOI: 10.3981/j.issn.1000-7857.2020.23.012
SHA Feng, HAN Zhe, TANG Chizhou, TANG Shan, WANG Jijie, LI Can. Research progress of non-copper-based catalysts for selective hydrogenation of carbon dioxide to methanol[J]. Science & Technology Review, 2020 , 38 (23) : 113 -127 . DOI: 10.3981/j.issn.1000-7857.2020.23.012
2020年第38卷第23期
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doi: 10.3981/j.issn.1000-7857.2020.23.012
  • 接收时间:2020-10-15
  • 首发时间:2021-01-14
  • 出版时间:2020-12-13
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  • 收稿日期:2020-10-15
  • 修回日期:2020-10-20
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通讯作者:

李灿(通信作者),研究员,中国科学院院士,研究方向为催化材料、催化反应和光谱表征,电子信箱:canli@dicp.ac.cn
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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