Article(id=1242138806518886501, tenantId=1146029695717560320, journalId=1146031591421210625, issueId=1242138783504740366, articleNumber=null, orderNo=15, doi=10.3981/j.issn.1000-7857.2020.23.009, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1599148800000, receivedDateStr=2020-09-04, revisedDate=1601136000000, revisedDateStr=2020-09-27, acceptedDate=null, acceptedDateStr=null, onlineDate=1610589539750, onlineDateStr=2021-01-14, pubDate=1607788800000, pubDateStr=2020-12-13, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1610589539750, onlineIssueDateStr=2021-01-14, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1774078569292, creator=sys-migrate, updateTime=1774078569292, updator=sys-migrate, issue=Issue{id=1242138783504740366, tenantId=1146029695717560320, journalId=1146031591421210625, year='2020', volume='38', issue='23', pageStart='1', pageEnd='152', issueExtLink='null', onlineDate='null', pubDate='1607788800000', pubDateStr='2020-12-13', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=3, issueType=-1, specialIssue=null, createTime=1774078563806, creator='sys-migrate', updateTime=1774078563806, updator='sys-migrate', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=85, endPage=93, ext={EN=ArticleExt(id=1242138809727525676, articleId=1242138806518886501, tenantId=1146029695717560320, journalId=1146031591421210625, language=EN, title=Progress of photoelectrocatalytic water splitting based on molecular water oxidation catalysts, columnId=1242138801829651202, journalTitle=Science & Technology Review, columnName=Exclusive：Solar fules, runingTitle=null, highlight=null, articleAbstract=Utilizing sunlight to split water into hydrogen and oxygen is an ideal way to convert solar energy into chemical energy and solve energy and environmental problems. In general, water splitting is hindered by the oxidation of water to oxygen which involves transfer processes of four electrons and four protons. To overcome this obstacle, an effective, robust and low-cost water oxidation catalysts (WOCs), and the anodes and photoanodes that perform fast oxygen evolution at low onset potentials, as well as benign conditions are highly desired. In this article we review recent advances in molecular water oxidation catalysts based on the first-row transition metal elements and advances in commonly used semiconductor materials such as α-Fe2 O3 , WO3 , and BiVO4 . Finally, we briefly discuss the assembly methods (covalent link, π-π stack, etc.) of molecular catalysts to electrodes and the classic examples of anode in catalytic oxidation of water., authors=LEE Husileng1 , WU Xiujuan1 , SUN Licheng1,2 , authorsList=LEE Husileng, WU Xiujuan, SUN Licheng, authorCompany=1. State Key Laboratory of Fine Chemicals, Dalian University of Technology(DUT), Dalian 116024, China;2 O3 、WO3 和BiVO4 等。概述了目前分子水氧化催化剂在电极表面的负载方式，包括物理吸附方式、共价键结合方式、分子催化剂修饰吸附基团方式、静电作用和π-π堆积作用等。提出构建高效稳定的光致水分解分子器件需要解决的问题，从而实现利用太阳能大规模裂解水制备清洁能源的设想。, authors=呼斯楞1 , 吴秀娟1 , 孙立成1,2 , authorsList=呼斯楞, 吴秀娟, 孙立成, authorCompany=1. 大连理工大学, 精细化工国家重点实验室, 大连 116024;
科技导报
| 专题：太阳燃料 2020, 38(23): 85-93
分子水氧化催化剂及其光电催化分解水研究进展
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呼斯楞1 , 吴秀娟1 , 孙立成1,2
作者信息
1. 大连理工大学, 精细化工国家重点实验室, 大连 116024;
通讯作者:
吴秀娟(通信作者),副教授,研究方向为光电催化水氧化反应,电子信箱:wuxiujuan2003@dlut.edu.cn;孙立成(通信作者),教授,研究方向为人工光合作用,电子信箱:sunlc@dlut.edu.cn
Progress of photoelectrocatalytic water splitting based on molecular water oxidation catalysts
Affiliations
出版时间: 2020-12-13
doi: 10.3981/j.issn.1000-7857.2020.23.009
文章导航
总结了近年来基于不同第一过渡系列金属的分子水氧化催化剂，包括贵金属分子水氧化催化剂和非金属分子水氧化催化剂；以及常用的氧化物半导体电极材料，例如α-Fe2 O3 、WO3 和BiVO4 等。概述了目前分子水氧化催化剂在电极表面的负载方式，包括物理吸附方式、共价键结合方式、分子催化剂修饰吸附基团方式、静电作用和π-π堆积作用等。提出构建高效稳定的光致水分解分子器件需要解决的问题，从而实现利用太阳能大规模裂解水制备清洁能源的设想。
Utilizing sunlight to split water into hydrogen and oxygen is an ideal way to convert solar energy into chemical energy and solve energy and environmental problems. In general, water splitting is hindered by the oxidation of water to oxygen which involves transfer processes of four electrons and four protons. To overcome this obstacle, an effective, robust and low-cost water oxidation catalysts (WOCs), and the anodes and photoanodes that perform fast oxygen evolution at low onset potentials, as well as benign conditions are highly desired. In this article we review recent advances in molecular water oxidation catalysts based on the first-row transition metal elements and advances in commonly used semiconductor materials such as α-Fe2 O3 , WO3 , and BiVO4 . Finally, we briefly discuss the assembly methods (covalent link, π-π stack, etc.) of molecular catalysts to electrodes and the classic examples of anode in catalytic oxidation of water.
molecular water oxidation catalysts
/
semiconductor
/
photoanode
呼斯楞, 吴秀娟, 孙立成.
分子水氧化催化剂及其光电催化分解水研究进展.
科技导报,
2020
, 38
(23)
: 85
-93
.
DOI: 10.3981/j.issn.1000-7857.2020.23.009
LEE Husileng, WU Xiujuan, SUN Licheng.
Progress of photoelectrocatalytic water splitting based on molecular water oxidation catalysts[J].
Science & Technology Review ,
2020
, 38
(23)
: 85
-93
.
DOI: 10.3981/j.issn.1000-7857.2020.23.009
2020年第38卷第23期
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文章信息
doi: 10.3981/j.issn.1000-7857.2020.23.009
接收时间：2020-09-04
首发时间：2021-01-14
出版时间：2020-12-13
收稿日期：2020-09-04
修回日期：2020-09-27
通讯作者:
吴秀娟(通信作者),副教授,研究方向为光电催化水氧化反应,电子信箱:wuxiujuan2003@dlut.edu.cn;孙立成(通信作者),教授,研究方向为人工光合作用,电子信箱:sunlc@dlut.edu.cn
https://castjournals.cast.org.cn/joweb/kjdb/CN/10.3981/j.issn.1000-7857.2020.23.009
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2种不同金属材料的力学参数
科 属数 种数 占总种数比例 属 种数 占总种数比例 鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78 小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39 多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39 红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87 小菇属 Mycena 11 5.26 光柄菇属 Pluteus 5 2.39 红菇属 Russula 17 8.13 栓菌属 Trametes 5 2.39
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