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Co/CFs的制备及其电催化析氢性能研究
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杨宁, 李彩彩, 孙庆丰
科技导报 | 研究论文 2020,38(11): 152-159
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科技导报 |研究论文 2020 , 38 (11) : 152 -159
Co/CFs的制备及其电催化析氢性能研究
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杨宁, 李彩彩, 孙庆丰
作者信息
通讯作者:
李彩彩(通信作者),副教授,研究方向为木质基新型能源材料与器件,电子信箱:ccli@zafu.edu.cn;孙庆丰(通信作者),教授,研究方向为木材仿生智能科学和木材纳米结构解译,电子信箱:qfsun@zafu.edu.cn
作者简介:
杨宁,硕士研究生,研究方向为木质基先进功能材料,电子信箱:18729480443@163.com
Preparation of Co/CFs for electrocatalytic hydrogen evolution
YANG Ning, LI Caicai, SUN Qingfeng
Affiliations
    School of Engineering, Zhejiang A&F University, Hangzhou 311300, China
出版时间: 2020-06-13 doi: 10.3981/j.issn.1000-7857.2020.11.017
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以木质纤维素为基体,采用浸渍、高温碳化的方法制备了木质碳纤维负载的钴纳米颗粒(Co/CFs)电催化剂。利用X射线衍射(XRD)、X射线光电子能谱(XPS)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)等对样品的化学组成和微观形貌进行了表征分析,并借助电化学工作站测试了样品的电催化析氢性能。结果表明,CFs的引入有效缓解了Co纳米颗粒(Co NPs)易团聚的问题,有利于实现活性位点的最大程度暴露。当Co/CFs用作析氢催化剂,达到10 mA·cm-2的电流密度时需要的过电位仅为250 mV,并可保持长达15 h的催化稳定性。
木质纤维素碳纤维  /  金属钴纳米颗粒  /  电催化析氢
The carbon fibers-supported cobalt nanoparticles (Co/CFs) electrocatalyst with lignocellulose as a matrix is prepared by impregnating and then carbonizing at a high temperature. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Scanning Electron Microscopy (SEM)and Transmission Electron Microscopy (TEM) are used to analyze the compositions and the micromorphology of the samples. And the electrocatalytic activities are tested by a CHI workstation. It is shown that the use of CFs alleviates the problem of easy agglomeration of Co nanoparticles (Co NPs), which is conducive to achieve a maximum exposure of active sites. When used as a hydrogen evolution catalyst, only a low overpotential of 250 mV is required for obtaining a current density of 10 mA cm-2 and the catalyst could also maintain its stability for a time as long as 15 h.
lignocellulosic carbon fibers  /  cobalt  /  electrocatalytic hydrogen evolution
杨宁, 李彩彩, 孙庆丰. Co/CFs的制备及其电催化析氢性能研究. 科技导报, 2020 , 38 (11) : 152 -159 . DOI: 10.3981/j.issn.1000-7857.2020.11.017
YANG Ning, LI Caicai, SUN Qingfeng. Preparation of Co/CFs for electrocatalytic hydrogen evolution[J]. Science & Technology Review, 2020 , 38 (11) : 152 -159 . DOI: 10.3981/j.issn.1000-7857.2020.11.017

    浙江省自然科学基金探索项目(LQ20C160004)

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doi: 10.3981/j.issn.1000-7857.2020.11.017
  • 接收时间:2020-02-24
  • 首发时间:2020-06-30
  • 出版时间:2020-06-13
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  • 收稿日期:2020-02-24
  • 修回日期:2020-03-24
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李彩彩(通信作者),副教授,研究方向为木质基新型能源材料与器件,电子信箱:ccli@zafu.edu.cn;孙庆丰(通信作者),教授,研究方向为木材仿生智能科学和木材纳米结构解译,电子信箱:qfsun@zafu.edu.cn
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2种不同金属材料的力学参数

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Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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