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2. Petro China Research Institute of Petroleum Exploration & Development-Langfang, Langfang 065007, China, fund=null, authors=XIA Yongjiang1,2, GUAN Baoshan2, LIANG Li2, LIU Ping2, authorsList=XIA Yongjiang, GUAN Baoshan, LIANG Li, LIU Ping), CN=ArticleExt(id=1242131705063092580, articleId=1242131700470329669, tenantId=1146029695717560320, journalId=1146031591421210625, language=CN, title=表面活性剂对煤层气压裂伤害研究, columnId=1146540929516700224, journalTitle=科技导报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=为评价压裂液中表面活性剂对煤层气压裂过程的影响,利用煤岩样品针对阳离子、非离子、阴离子表面活性剂和表面活性剂复配体系,开展膨胀性、润湿性、吸附性能、表面张力、煤岩伤害和煤层气吸附解吸附物理模拟实验。将不同表面活性剂和复配体系的煤岩膨胀高度、接触角、煤粉中吸附形态和吸附量、措施前后表面张力和煤岩渗透率、吸附和解吸附曲线进行对比分析,进而优选表面活性剂体系。研究结果表明:水和表面活性剂溶液对所选煤岩膨胀性影响不大;阳离子可以增加憎水性,非离子保持煤岩水润湿性,阴离子会增加煤岩水润性;非离子表面活性剂有利于扩大煤岩孔隙进而提高煤层气的解吸附作用;双子表面活性剂(GM)为点状吸附,烷基酚聚氧乙烯醚(OP)为平铺吸附,十八烷基三甲基氯化铵(1831)为连体状吸附;双子-烷基酚聚氧乙烯醚(GMOP-4)复配体系措施前后表面张力较低,大幅度降低了GM 的吸附量且对煤层气解吸附过程具有促进作用;GMOP-4 复配体系实现了阳离子表面活性剂在煤层气压裂措施中低成本、高性能的应用。, correspAuthors=null, authorNote=夏永江,博士后,研究方向为储层改造,电子信箱:xiayongjiang3286@163.com, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=+b2Ypd1bfgsUgna2tct9xA==, pdfFileSize=1948250, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, authorCompany=1. 中国矿业大学(北京)地球科学与测绘工程学院, 北京 100083;
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表面活性剂对煤层气压裂伤害研究
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科技导报 | 研究论文 2014, 32(8): 32-38
表面活性剂对煤层气压裂伤害研究
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夏永江1,2, 管保山2, 梁利2, 刘萍2
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    1. 中国矿业大学(北京)地球科学与测绘工程学院, 北京 100083;
    2. 中国石油勘探开发研究院廊坊分院, 廊坊 065007
Fracturing Damage of Coal Bed Methane Caused by Surfactants
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出版时间: 2014-03-18 doi: 10.3981/j.issn.1000-7857.2014.08.004
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为评价压裂液中表面活性剂对煤层气压裂过程的影响,利用煤岩样品针对阳离子、非离子、阴离子表面活性剂和表面活性剂复配体系,开展膨胀性、润湿性、吸附性能、表面张力、煤岩伤害和煤层气吸附解吸附物理模拟实验。将不同表面活性剂和复配体系的煤岩膨胀高度、接触角、煤粉中吸附形态和吸附量、措施前后表面张力和煤岩渗透率、吸附和解吸附曲线进行对比分析,进而优选表面活性剂体系。研究结果表明:水和表面活性剂溶液对所选煤岩膨胀性影响不大;阳离子可以增加憎水性,非离子保持煤岩水润湿性,阴离子会增加煤岩水润性;非离子表面活性剂有利于扩大煤岩孔隙进而提高煤层气的解吸附作用;双子表面活性剂(GM)为点状吸附,烷基酚聚氧乙烯醚(OP)为平铺吸附,十八烷基三甲基氯化铵(1831)为连体状吸附;双子-烷基酚聚氧乙烯醚(GMOP-4)复配体系措施前后表面张力较低,大幅度降低了GM 的吸附量且对煤层气解吸附过程具有促进作用;GMOP-4 复配体系实现了阳离子表面活性剂在煤层气压裂措施中低成本、高性能的应用。
煤层气  /  水力压裂  /  表面活性剂  /  煤岩伤害实验
The coal expansibility, wettability, adsorption, surface tension, damage, adsorption and desorption experiments of cationic surfactant, nonionic surfactant and anionic surfactant were performed to investigate the effect of surfactants on hydraulic fracturing in coal bed methane (CBM) reservoir. The expansion height, contact angle, adsorption forms and absorbance, the surface tension and permeability of coal samples before and after damage, adsorption and desorption of different surfactants and compounded systems were compared and analyzed to identify the optimal system. The investigation shows that the surfactants and water have little effect on coal expansibility. The cationic surfactant increases the coal sample's hydrophobicity, the nonionic surfactant maintains the coal wettability, and the anionic surfactant increases the coal hydrophilia. The nonionic surfactant enlarges coal porosity and accelerates coal gas desorption. The GM is dot adsorption, OP is tile adsorption, and 1831 is conjoined structure adsorption. The GMOP-4 compounded system with low surface tension significantly decreases the GM adsorption volume and accelerates coal gas desorption. The GMOP-4 compounded system realizes the low-cost and high-performance application of cationic surfactants in CBM hydraulic fracturing.
CBM  /  hydraulic fracturing  /  surfactant  /  coal sample damage experiment
夏永江, 管保山, 梁利, 刘萍. 表面活性剂对煤层气压裂伤害研究. 科技导报, 2014 , 32 (8) : 32 -38 . DOI: 10.3981/j.issn.1000-7857.2014.08.004
XIA Yongjiang, GUAN Baoshan, LIANG Li, LIU Ping. Fracturing Damage of Coal Bed Methane Caused by Surfactants[J]. Science & Technology Review, 2014 , 32 (8) : 32 -38 . DOI: 10.3981/j.issn.1000-7857.2014.08.004
2014年第32卷第8期
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doi: 10.3981/j.issn.1000-7857.2014.08.004
  • 接收时间:2013-10-23
  • 首发时间:2014-03-26
  • 出版时间:2014-03-18
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  • 收稿日期:2013-10-23
  • 修回日期:2014-01-15
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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