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氧化石墨对对硝基苯酚的吸附行为
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氧化石墨对对硝基苯酚的吸附行为
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查飞, 曾慧崇, 常玥
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    西北师范大学化学化工学院, 兰州730070
Adsorption Properties of Graphite Oxide for p-Nitrophenol
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出版时间: 2014-02-28 doi: 10.3981/j.issn.1000-7857.2014.06.005
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以石墨粉为原料,经Hummers 法制备氧化石墨,采用红外光谱、X 射线衍射和扫描电镜对产物结构进行表征。结果表明,氧化石墨含有C—OH、—COOH 和C—O—C 等官能团,使石墨的层间作用力减弱,层间距增大。研究了氧化石墨对对硝基苯酚的吸附行为,当吸附温度为298 K,pH 为7.0 时,氧化石墨对对硝基苯酚的吸附量为80.69 mg/g,是石墨粉吸附量的6.1 倍。吸附热力学研究表明,氧化石墨对对硝基苯酚的吸附可以用Langmuir 方程拟合,吸附是自发的放热过程,低温有利于吸附的进行。动力学拟合显示吸附符合二级动力学模型。
氧化石墨  /  对硝基苯酚  /  吸附热力学  /  吸附动力学
The graphite oxide was prepared from the powdered graphite via the Hummers method. It was characterized by the methods of the FT-IR, the XRD and the SEM. It is shown that the graphite oxide contains various oxygen-containing functional groups such as C—OH, —COOH and C—O—C, which increase the layer spaces. Adsorption experiments indicate that the graphite oxide has an outstanding adsorption ability for the p-nitrophenol. With the adsorption temperature at 298 K and the pH value at 7.0, the adsorptive capability of the graphite oxide is up to 80.69 mg/g, 6.1 times of that of the graphite powder. From the adsorption isotherms and thermodynamic functions, it is shown that the adsorption can be described by the Langmuir isothermal equation and is a spontaneous and exothermic process. The kinetic study shows that the adsorption can be fitted by second-order dynamic equations.
graphite oxide  /  p-nitrophenol  /  adsorption thermodynamics  /  adsorption kinetics
查飞, 曾慧崇, 常玥. 氧化石墨对对硝基苯酚的吸附行为. 科技导报, 2014 , 32 (6) : 34 -39 . DOI: 10.3981/j.issn.1000-7857.2014.06.005
ZHA Fei, ZENG Huichong, CHANG Yue. Adsorption Properties of Graphite Oxide for p-Nitrophenol[J]. Science & Technology Review, 2014 , 32 (6) : 34 -39 . DOI: 10.3981/j.issn.1000-7857.2014.06.005
2014年第32卷第6期
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doi: 10.3981/j.issn.1000-7857.2014.06.005
  • 接收时间:2013-09-16
  • 首发时间:2014-03-07
  • 出版时间:2014-02-28
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  • 收稿日期:2013-09-16
  • 修回日期:2013-11-17
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2种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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