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The structure of the copolymer was characterized by FTIR. The influences of several factors on the apparent viscosity are studied, such as the initiation temperature, the amount of initiator, the monomer concentration, the hydrophobic monomer concentration, the surfactant concentration, and the monomer proportion. The results show that after incorporating anions and hydrophobic groups at the same time in the backbone of the polyacrylamide, the viscosity of the copolymer aqueous solution increases significantly under the coordination of the electric viscosity of anions and the hydrophobic association property of hydrophobic group. The hydrophobic associative behavior of the copolymer is studied by the fluorescence probe technique and, at the same time, the rheological properties of the copolymer aqueous solution are also investigated., authors=SONG Chunlei1 , AN Huiyong2 , authorsList=SONG Chunlei;AN Huiyong, authorCompany=1. 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科技导报
|研究论文
2011
, 29
(26) :
25
-29
疏水缔合共聚物的合成及溶液性质
全屏
宋春雷1 , 安会勇2
作者信息
1. 中国科学院长春应用化学研究所生态环境高分子材料重点实验室,长春 130022;2. 辽宁石油化工大学化学与材料科学学院,辽宁抚顺 113001
通讯作者:
安会勇,副教授,研究方向为水溶性聚合物,电子信箱:ahy46@sina.com
Synthesis of Hydrophobically Associated Copolymer Three-Component Copolymer and Their Properties
SONG Chunlei1 , AN Huiyong2
Affiliations
1. Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;2. School of Chemistry and Materials, Liaoning Shihua University, Fushun 113001, Liaoning Province, China
出版时间: 2011-09-18
doi: 10.3981/j.issn.1000-7857.2011.26.002
文章导航
采用自由基胶束聚合法成功制备了丙烯酰胺(AM)/甲基丙烯酸十八酯(SMA)/2-甲基-2-丙烯酰胺基丙磺酸(AMPS)三元疏水缔合共聚物(HAPAM).考查了引发温度、单体质量分数、表面活性剂含量、疏水单体含量、单体配比以及引发剂浓度对共聚物表观黏度的影响,在聚丙烯酰胺(PAM)大分子主链上引入阴离子基团和疏水基团后,阴离子的电黏效应与疏水基团的疏水缔合作用相互协同,使得共聚物水溶液的黏度明显提高.利用FTIR光谱对共聚物结构进行表征,用RF-5301型荧光分光光度仪研究证实了共聚物在水溶液中的缔合行为.采用Brukerfiled流变仪对所合成的疏水缔合共聚物水溶液的流变行为进行研究.
Hydrophobically associated poly (AM/AMPS/SMA) were prepared by free radical micellar copolymerization. The structure of the copolymer was characterized by FTIR. The influences of several factors on the apparent viscosity are studied, such as the initiation temperature, the amount of initiator, the monomer concentration, the hydrophobic monomer concentration, the surfactant concentration, and the monomer proportion. The results show that after incorporating anions and hydrophobic groups at the same time in the backbone of the polyacrylamide, the viscosity of the copolymer aqueous solution increases significantly under the coordination of the electric viscosity of anions and the hydrophobic association property of hydrophobic group. The hydrophobic associative behavior of the copolymer is studied by the fluorescence probe technique and, at the same time, the rheological properties of the copolymer aqueous solution are also investigated.
hydrophobic association
/
micellar copolymerization
/
copolymer
/
apparent viscosity
宋春雷;安会勇.
疏水缔合共聚物的合成及溶液性质.
科技导报,
2011
, 29
(26)
: 25
-29
.
DOI: 10.3981/j.issn.1000-7857.2011.26.002
SONG Chunlei;AN Huiyong.
Synthesis of Hydrophobically Associated Copolymer Three-Component Copolymer and Their Properties[J].
Science & Technology Review ,
2011
, 29
(26)
: 25
-29
.
DOI: 10.3981/j.issn.1000-7857.2011.26.002
2011年第29卷第26期
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文章信息
doi: 10.3981/j.issn.1000-7857.2011.26.002
接收时间:2011-06-10
首发时间:2011-09-18
出版时间:2011-09-18
收稿日期:2011-06-10
修回日期:2011-08-11
通讯作者:
安会勇,副教授,研究方向为水溶性聚合物,电子信箱:ahy46@sina.com
https://castjournals.cast.org.cn/joweb/kjdb/CN/10.3981/j.issn.1000-7857.2011.26.002
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2种不同金属材料的力学参数
科 Family 属数 Number of genus 种数 Number of species 占总种数比例 Percentage of total species (%) 属 Genus 种数 Number of species 占总种数比例 Percentage of total species (%) 鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78 小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39 多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39 红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87 小菇属 Mycena 11 5.26 光柄菇属 Pluteus 5 2.39 红菇属 Russula 17 8.13 栓菌属 Trametes 5 2.39
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