Article(id=1304923103541350996, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1304923090710982825, articleNumber=null, orderNo=null, doi=10.16790/j.cnki.1009-9239.im.2026.04.007, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1746720000000, receivedDateStr=2025-05-09, revisedDate=1750262400000, revisedDateStr=2025-06-19, acceptedDate=null, acceptedDateStr=null, onlineDate=1789047512183, onlineDateStr=2026-09-10, pubDate=1776614400000, pubDateStr=2026-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1789047512183, onlineIssueDateStr=2026-09-10, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1789047512183, creator=13701087609, updateTime=1789047512183, updator=13701087609, issue=Issue{id=1304923090710982825, tenantId=1146029695717560320, journalId=1149653034449285133, year='2026', volume='59', issue='4', pageStart='1', pageEnd='144', issueExtLink='null', onlineDate='null', pubDate='1776614400000', pubDateStr='2026-04-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1789047509124, creator='13701087609', updateTime=1789118076681, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1305219072573071941, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1304923090710982825, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1305219072573071942, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1304923090710982825, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=54, endPage=61, ext={EN=ArticleExt(id=1304923103721706069, articleId=1304923103541350996, tenantId=1146029695717560320, journalId=1149653034449285133, language=EN, title=Study on electrical properties degradation law of cable termination insulating oil under short-term moisture absorption, columnId=1190369198472794288, journalTitle=Insulating Materials, columnName=Insulation Technology, runingTitle=null, highlight=null, articleAbstract=
Trace moisture absorption of insulating oils in high-voltage cable terminations during on-site filling or long-term operation may cause electrical performance deterioration and even insulation breakdown. The differences in molecular structure and polarity characteristics among different types of insulating oils will lead to significant differences in the adsorption behaviors of water molecules and the degradation laws of electrical performances. In this paper, the natural water absorption of silicone oil and polyisobutylene insulating oil under different exposure time was studied. The evolution of moisture content in different temperature and humidity environments was determined by Karl Fischer titration method, and the dielectric loss factor, volume resistivity, and power-frequency breakdown voltage of the insulating oil after water absorption were tested. Through molecular dynamics and quantum chemical calculations combined with Gaussian software, the differences in the moisture absorption mechanisms of the two types insulating oils were revealed from the perspectives of microscopic dipole moment, adsorption energy, and Gibbs free energy. The results show that due to the existence of Si-O bonds and polar groups in molecular chain of silicone oil, the dipole moment is 0.69 Debye. The initial absorption rate and total moisture amount are relatively high, and its moisture absorption process conforms to the exponential growth trend, the saturated moisture content is approximately 52×10-6. The polyisobutylene has a typical non-polar C-H chain structure with a low dipole moment of 0.02 Debye, and the its moisture absorption process shows a linear upward trend. Moisture absorption will lead to a significantly increases in dielectric loss factor, decreases in volume resistivity and electric strength for the two types of insulating oils. Silicone oil fails to meet the national standard requirement for insulation strength after 2 h of exposure, while polyisobutylene maintains good insulation strength within 5 h of exposure.
, authors=Wei ZHANG
1, Chenying LI
1, Jingying CAO
1, Xiao TAN
1, Jie CHEN
1, Cang BAI
2, authorsList=Wei ZHANG, Chenying LI, Jingying CAO, Xiao TAN, Jie CHEN, Cang BAI, authorCompany=null, correspAuthors=null, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1304923105080660580, articleId=1304923103541350996, tenantId=1146029695717560320, journalId=1149653034449285133, language=CN, title=短时吸水条件下电缆终端绝缘油电性能劣化规律研究, columnId=1190369198724452531, journalTitle=绝缘材料, columnName=绝缘技术, runingTitle=null, highlight=null, articleAbstract=
高压电缆终端绝缘油在现场灌装或长期运行条件下的微量吸水可能导致其电气性能劣化甚至发生绝缘击穿故障。不同类型绝缘油在分子结构、极性特性上的差异会导致其对水分子的吸附行为及电性能劣化规律显著不同。本文研究硅油与聚异丁烯两种绝缘油在不同暴露时间下的自然吸水情况,采用卡尔费休滴定法测定不同温湿度环境下的水分含量演变,并测试吸水后绝缘油的介质损耗因数、体积电阻率及工频击穿电压;结合Gaussian软件进行分子动力学与量子化学计算,从微观偶极矩、吸附能及吉布斯自由能角度揭示两类绝缘油的吸水机制差异。结果表明:硅油因分子链中存在Si-O键及极性基团,偶极矩为0.69 Debye,初期吸水速率与总吸水量较高,其吸水过程符合指数增长规律,饱和含水量约为52×10-6;聚异丁烯为典型非极性C-H链结构,偶极矩为0.02 Debye,吸水过程呈线性上升趋势。吸水会导致两种绝缘油的介质损耗因数明显增大、体积电阻率降低、电气强度下降,硅油在暴露2 h后即不满足国标绝缘强度要求,而聚异丁烯在暴露5 h内仍具有较好的绝缘强度。
, authors=张伟
1, 李陈莹
1, 曹京荥
1, 谭笑
1, 陈杰
1, 柏仓
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张伟(1989-),女(汉族),黑龙江宝清人,高级工程师,博士,主要从事线缆设备评价、电缆材料研究等方面的工作。
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58(3):152-157., articleTitle=Mechanism analysis of the influence of water on the terminal breakdown position of oil filled cable, refAbstract=null)], funds=null, companyList=[AuthorCompany(id=1304923105319735909, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304923103541350996, xref=1, ext=[AuthorCompanyExt(id=1304923105328124518, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304923103541350996, companyId=1304923105319735909, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=
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The change curves of water content in silicone oil and polyisobutylene under different exposure time, figureFileSmall=+wnwFGrT0cpEzrCasdCL4Q==, figureFileBig=KH5659Sei3RC3iqS4lHz7w==, tableContent=null), ArticleFig(id=1304923109992190616, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304923103541350996, language=CN, label=图3, caption=
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The change curves of dielectric loss factors of silicone oil and polyisobutylene under different exposure time, figureFileSmall=/8t3DWlLzpOGmw40otYyMA==, figureFileBig=xbW+mEQdAlGnXs4X248EOA==, tableContent=null), ArticleFig(id=1304923110113825434, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304923103541350996, language=CN, label=图4, caption=
不同暴露时间下硅油和聚异丁烯介质损耗因数的变化曲线, figureFileSmall=/8t3DWlLzpOGmw40otYyMA==, figureFileBig=xbW+mEQdAlGnXs4X248EOA==, tableContent=null), ArticleFig(id=1304923110172545691, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304923103541350996, language=EN, label=Fig.5, caption=
The change curves of volume resistivity of silicone oil and polyisobutylene under different exposure time, figureFileSmall=tCCJZxPahvOz5XIUmz39kw==, figureFileBig=lG8G+lyBki27EFy9JoNyVQ==, tableContent=null), ArticleFig(id=1304923110231265948, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304923103541350996, language=CN, label=图5, caption=
不同暴露时间下硅油和聚异丁烯体积电阻率变化曲线, figureFileSmall=tCCJZxPahvOz5XIUmz39kw==, figureFileBig=lG8G+lyBki27EFy9JoNyVQ==, tableContent=null), ArticleFig(id=1304923110294180509, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304923103541350996, language=EN, label=Fig.6, caption=
The change curves of breakdown voltage of silicone oil and polyisobutylene under different exposure time, figureFileSmall=uBAhOejocYnuEml7nz3OxA==, figureFileBig=iK0Mvp97k4gjFNRbNaaaIw==, tableContent=null), ArticleFig(id=1304923110369677982, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304923103541350996, language=CN, label=图6, caption=
硅油和聚异丁烯在不同暴露时间下击穿电压的变化曲线, figureFileSmall=uBAhOejocYnuEml7nz3OxA==, figureFileBig=iK0Mvp97k4gjFNRbNaaaIw==, tableContent=null), ArticleFig(id=1304923110424203935, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304923103541350996, language=EN, label=Fig.7, caption=
The optimized molecular structures of silicone oil and polyisobutylene, figureFileSmall=/M1f1tAiXAZva97dyyErYg==, figureFileBig=TOCesWTelMHsbJMv1G8JLg==, tableContent=null), ArticleFig(id=1304923110487118496, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304923103541350996, language=CN, label=图7, caption=
硅油及聚异丁烯优化后的分子结构(a) 硅油 (b) 聚异丁烯
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