Article(id=1304921767483568646, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1304921686403474081, articleNumber=null, orderNo=null, doi=10.16790/j.cnki.1009-9239.im.2026.06.002, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1761062400000, receivedDateStr=2025-10-22, revisedDate=1766332800000, revisedDateStr=2025-12-22, acceptedDate=null, acceptedDateStr=null, onlineDate=1789047193642, onlineDateStr=2026-09-10, pubDate=1781884800000, pubDateStr=2026-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1789047193642, onlineIssueDateStr=2026-09-10, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1789047193642, creator=13701087609, updateTime=1789047193642, updator=13701087609, issue=Issue{id=1304921686403474081, tenantId=1146029695717560320, journalId=1149653034449285133, year='2026', volume='59', issue='6', pageStart='1', pageEnd='188', issueExtLink='null', onlineDate='null', pubDate='1781884800000', pubDateStr='2026-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1789047174311, creator='13701087609', updateTime=1789118019323, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1305218831971021057, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1304921686403474081, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1305218831971021058, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1304921686403474081, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=10, endPage=24, ext={EN=ArticleExt(id=1304921767659729415, articleId=1304921767483568646, tenantId=1146029695717560320, journalId=1149653034449285133, language=EN, title=Research progress on low dielectric constant inorganic dielectric materials for 5G/6G wireless communications and advanced packaging technologies, columnId=null, journalTitle=Insulating Materials, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Functional inorganic dielectric materials with low dielectric constants (ε_r<10), represented by ceramic materials, glass-ceramic composites, and microcrystalline glass, play an irreplaceable role in cutting-edge technologies such as high-frequency and high-speed communications, high-density integrated packaging, and high-reliability electronic devices. Among these, high-temperature co-fired ceramic (HTCC) technology employs high-strength alumina ceramics, high thermal conductivity aluminum nitride ceramics, or low-dielectric-constant silicon-based ceramics as insulating packaging materials. Low-temperature/ultra-low-temperature co-fired ceramic (LTCC/ULTCC) technology employs intrinsically low-sintering-temperature ceramics, sintering aid-reduced sintering-temperature ceramics, glass-ceramic composites, and microcrystalline glass as packaging materials. This paper elaborated and summarized the above low-dielectric-constant inorganic dielectric materials, and prospected the application of machine learning (ML) in the prediction and design of novel low-dielectric and low-loss packaging materials, providing a new route for the development of related systems.

, authors=Jian BAO, Zhengqiao LI, Jing GUO, Changhao WANG, Zhaochen XI, Di ZHOU^*, authorsList=Jian BAO, Zhengqiao LI, Jing GUO, Changhao WANG, Zhaochen XI, Di ZHOU, authorCompany=null, correspAuthors=Di ZHOU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1304921769526194716, articleId=1304921767483568646, tenantId=1146029695717560320, journalId=1149653034449285133, language=CN, title=面向5G/6G无线通信和先进封装技术的低介电常数无机电介质材料研究进展, columnId=null, journalTitle=绝缘材料, columnName=, runingTitle=null, highlight=null, articleAbstract=

以陶瓷材料、玻璃-陶瓷复合材料和微晶玻璃为代表的低介电常数（ε_r<10）无机电介质功能材料在高频高速通信、高密度集成封装及高可靠性电子设备等尖端技术中发挥着不可替代的作用。其中，高温共烧陶瓷（HTCC）技术中通常使用高强度氧化铝陶瓷、高热导率氮化铝陶瓷或低介电常数硅基陶瓷作为绝缘封装材料。低温/超低温共烧陶瓷（LTCC/ULTCC）技术则使用本征低烧结温度陶瓷、助烧剂降烧陶瓷、玻璃-陶瓷复合材料及微晶玻璃等作为封装材料。本文对上述低介电常数无机电介质材料的研究进展进行了详细的论述和总结，同时对利用机器学习（ML）预测和设计新型低介低损封装材料的前景进行展望，为相关体系的发展提供新的路径。

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包健（1998-），男（汉族），山东临沂人，博士生，主要从事低介电常数电介质功能陶瓷与器件的研究

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包健（1998-），男（汉族），山东临沂人，博士生，主要从事低介电常数电介质功能陶瓷与器件的研究

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keyword=低温/超低温共烧陶瓷), Keyword(id=1304921781228298944, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921767483568646, language=CN, orderNo=4, keyword=机器学习)], refs=[Reference(id=1304921783346426583, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921767483568646, doi=null, pmid=null, pmcid=null, year=2019, volume=null, issue=null, pageStart=45, pageEnd=7,, url=null, language=null, rfNumber=95, rfOrder=119, authorNames=JIANG D H, CHEN J J, LU B B, journalName=Ceramics International, refType=null, unstructuredReference=JIANG D H, CHEN J J, LU B B, et al. 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Journal of the American Ceramic Society,2024,107(5):3380-3389., articleTitle=Acceleration of optimizing the dielectric properties of (Ca_0.7Nd_0.2)_1-x(Li_0.5Nd_0.5)_xTi_1-y(Mg_1/3Nb_2/3)_yO₃ with the aid of machine learning, refAbstract=null), Reference(id=1304921793437918051, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921767483568646, doi=null, pmid=null, pmcid=null, year=2025, volume=45, issue=6, pageStart=117206, pageEnd=null, url=null, language=null, rfNumber=110, rfOrder=136, authorNames=APPIAH M, YANG Y X, ULLAH B, journalName=Journal of the European Ceramic Society, refType=null, unstructuredReference=APPIAH M, YANG Y X, ULLAH B, et al. Exceptionally optimized millimeter-wave properties of cordierite-based materials via innovative processing and predictive analytics[J]. Journal of the European Ceramic Society,2025,45(6):117206., articleTitle=Exceptionally optimized millimeter-wave properties of cordierite-based materials via innovative processing and predictive analytics, refAbstract=null)], funds=null, companyList=[AuthorCompany(id=1304921779416359576, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921767483568646, xref=null, ext=[AuthorCompanyExt(id=1304921779420553881, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921767483568646, companyId=1304921779416359576, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=School of Electronic Science and Engineering, Xi′an Jiaotong University, Xi′an 710049, China), AuthorCompanyExt(id=1304921779428942490, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921767483568646, companyId=1304921779416359576, language=CN, country=null, province=null, city=null, 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tableContent=null), ArticleFig(id=1304921782805357268, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921767483568646, language=CN, label=图10, caption=机器学习辅助材料研究的主要流程示意图, figureFileSmall=FRkZ5qNCOo4Wd99bi+XA0g==, figureFileBig=TBQ3qg0qPIEI06VBlyDIAA==, tableContent=null), ArticleFig(id=1304921782872466133, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921767483568646, language=EN, label=Table 1, caption=

The characteristics of alumina HTCC powder material from Kyocera

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材料名称		A440	A443	A473	AO610W	AO700	AO800	A476
颜色		黑紫色	黑色	白色	浅粉色	灰色	灰色	白色
特性		通用	表面贴装	高频	高发热	高抗弯强度		射频
介电常数	1 MHz	9.8	9.6	9.1	9.2	9.4	9.4	9.4
	2 GHz	—	—	8.5	9.0	9.2	9.4	—
介电损耗/(×10-4)	1 MHz	24	5	5	9	6	4	4
	2 GHz	—	—	10	11	6	13	—
热膨胀系数(RT～400℃)/(×10-6℃-1)		7.1	6.9	6.9	6.9	7.2	7.5	7.2
热导率/(W/(m·K))		14	18	18	17	21	16	24
抗弯强度/MPa		400	460	400	460	620	740	350
杨氏模量/GPa		310	310	270	281	315	300	320

), ArticleFig(id=1304921782943769302, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921767483568646, language=CN, label=表1, caption=

京瓷氧化铝HTCC粉体材料特性

, figureFileSmall=null, figureFileBig=null, tableContent=

材料名称		A440	A443	A473	AO610W	AO700	AO800	A476
颜色		黑紫色	黑色	白色	浅粉色	灰色	灰色	白色
特性		通用	表面贴装	高频	高发热	高抗弯强度		射频
介电常数	1 MHz	9.8	9.6	9.1	9.2	9.4	9.4	9.4
	2 GHz	—	—	8.5	9.0	9.2	9.4	—
介电损耗/(×10-4)	1 MHz	24	5	5	9	6	4	4
	2 GHz	—	—	10	11	6	13	—
热膨胀系数(RT～400℃)/(×10-6℃-1)		7.1	6.9	6.9	6.9	7.2	7.5	7.2
热导率/(W/(m·K))		14	18	18	17	21	16	24
抗弯强度/MPa		400	460	400	460	620	740	350
杨氏模量/GPa		310	310	270	281	315	300	320

), ArticleFig(id=1304921783002489559, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921767483568646, language=EN, label=Table 2, caption=

The research progress on sintering aids and sintering processes for AlN ceramics

, figureFileSmall=null, figureFileBig=null, tableContent=

烧结温度/℃	助烧剂/工艺	热导率/(W/(m·K))	抗弯强度/MPa	参考文献
1 850	Y2O3+长时间退火	222	—	[21]
1 650	CaF2-Li2CO3-Y2O3	141	—	[22]
1 650	CaF2-Dy2O3	142	—
1 900	CaF2	190.4		[23]
1 600	CaZrO3-Y2O3+两步法烧结	156	560	[24]
1 700	Y2O3-CeO2	176	392	[25]
1 900	CeO2	156	—	[26]
1 850	Y2O3	205	295	[27]
1 860	Y2O3	206	344	[28]
1 750	Sm2O3-Y2O3-CaO	153.7	402	[29]

), ArticleFig(id=1304921783077987032, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921767483568646, language=CN, label=表2, caption=

AlN陶瓷的助烧剂和烧结工艺研究进展

, figureFileSmall=null, figureFileBig=null, tableContent=

烧结温度/℃	助烧剂/工艺	热导率/(W/(m·K))	抗弯强度/MPa	参考文献
1 850	Y2O3+长时间退火	222	—	[21]
1 650	CaF2-Li2CO3-Y2O3	141	—	[22]
1 650	CaF2-Dy2O3	142	—
1 900	CaF2	190.4		[23]
1 600	CaZrO3-Y2O3+两步法烧结	156	560	[24]
1 700	Y2O3-CeO2	176	392	[25]
1 900	CeO2	156	—	[26]
1 850	Y2O3	205	295	[27]
1 860	Y2O3	206	344	[28]
1 750	Sm2O3-Y2O3-CaO	153.7	402	[29]

), ArticleFig(id=1304921783140901593, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921767483568646, language=EN, label=Table 3, caption=

Low dielectric constant microwave dielectric ceramic with sintering temperatures exceeding 950℃

, figureFileSmall=null, figureFileBig=null, tableContent=

物相组成	烧结温度/℃	εr	Q·f/GHz	TCF/(×10-6℃-1)	参考文献
SiO2(非晶)	熔融法	3.83	12 100	-8.30	[33]
Al2SiO5	1 525	4.43	41 800	-17.00	[43]
Mg3P2O8	1 150	4.90	31 000	-19.20	[44]
Li2MgSiO4	1 250	5.10	15 385	—	[35]
LiAlO2	1 250	5.45	14 748	-190.00	[45]
CaCuSi4O10	1 045	5.75	20 210	-38.90	[46]
SrCuSi4O10	1 025	5.77	48 790	-46.30	[46]
Li2ZnSiO4	1 250	5.80	14 700	-96.60	[47]
BaCuSi4O10	1 100	6.03	49 952	-18.00	[48]
CaCoSi2O6	1 175	6.04	12 457	-18.90	[43]
α-Mg2P2O7	1 150	6.10	38 175	-746.00	[49]
SrZnSi3O8	1 150	6.12	78 064	-33.20	[43]
Mg2Al4Si5O18	1 440	6.20	40 000	-24.00	[36]
Ni3P2O8	1 200	6.23	83 430	-24.63	[44]
BaAl2Si2O8	1 450	6.36	44 800	-46.90	[35]
Zn2SiO4	1 340	6.60	219 000	-61.00	[43]
BaZnSi3O8	1 100	6.60	52 400	-24.50	[43]
BaSi2O5	1 250	6.70	59 500	-28.00	[50]
SrMgSi2O6	1 125	6.70	25 800	-46.00	[51]
MgSiO3	1 380	6.70	121 200	-17.00	[52]
Co2P2O7	1 160	6.76	36 400	-23.90	[53]
CaSiO3	1 500	6.80	42 200	-19.00	[54]
SrSiO3	1 500	6.80	12 100	-66.00	[54]
Mg2SiO4	1 500	6.80	270 000	-70.00	[55]
CaMgSiO4	1 350	7.05	62 500	-62.90	[56]
α-Sr2P2O7	1 150	7.11	35 500	-23.00	[57]
Sr2Al2SiO7	1 525	7.20	33 000	-37.00	[35]
LiYbSiO4	1 140	7.30	25 257	4.50～8.00	[58]
Ba5Si8O21	1 200	7.30	16 700	25.00	[50]
Mn2P2O7	1 100	7.34	23 847	-95.80	[57]
CaMnSi2O6	1 220	7.39	34 100	-25.60	[59]
CaMgSi2O6	1 290	7.46	59 640	-46.00	[43]
KBaPO4	1 150	7.58	31 577	-13.30	[60]
BaZn2P2O8	1 000	7.72	17 000	-41.10	[61]
Ca3Si2O7	1 300	7.80	28 400	—	[62]
Nd2SiO5	1 500	7.94	38 800	-53.00	[35]
YPO4	1 600	8.00	67 933	-35.30	[63]

), ArticleFig(id=1304921783220593370, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921767483568646, language=CN, label=表3, caption=

烧结温度高于950℃的低介电常数微波介质陶瓷

, figureFileSmall=null, figureFileBig=null, tableContent=

物相组成	烧结温度/℃	εr	Q·f/GHz	TCF/(×10-6℃-1)	参考文献
SiO2(非晶)	熔融法	3.83	12 100	-8.30	[33]
Al2SiO5	1 525	4.43	41 800	-17.00	[43]
Mg3P2O8	1 150	4.90	31 000	-19.20	[44]
Li2MgSiO4	1 250	5.10	15 385	—	[35]
LiAlO2	1 250	5.45	14 748	-190.00	[45]
CaCuSi4O10	1 045	5.75	20 210	-38.90	[46]
SrCuSi4O10	1 025	5.77	48 790	-46.30	[46]
Li2ZnSiO4	1 250	5.80	14 700	-96.60	[47]
BaCuSi4O10	1 100	6.03	49 952	-18.00	[48]
CaCoSi2O6	1 175	6.04	12 457	-18.90	[43]
α-Mg2P2O7	1 150	6.10	38 175	-746.00	[49]
SrZnSi3O8	1 150	6.12	78 064	-33.20	[43]
Mg2Al4Si5O18	1 440	6.20	40 000	-24.00	[36]
Ni3P2O8	1 200	6.23	83 430	-24.63	[44]
BaAl2Si2O8	1 450	6.36	44 800	-46.90	[35]
Zn2SiO4	1 340	6.60	219 000	-61.00	[43]
BaZnSi3O8	1 100	6.60	52 400	-24.50	[43]
BaSi2O5	1 250	6.70	59 500	-28.00	[50]
SrMgSi2O6	1 125	6.70	25 800	-46.00	[51]
MgSiO3	1 380	6.70	121 200	-17.00	[52]
Co2P2O7	1 160	6.76	36 400	-23.90	[53]
CaSiO3	1 500	6.80	42 200	-19.00	[54]
SrSiO3	1 500	6.80	12 100	-66.00	[54]
Mg2SiO4	1 500	6.80	270 000	-70.00	[55]
CaMgSiO4	1 350	7.05	62 500	-62.90	[56]
α-Sr2P2O7	1 150	7.11	35 500	-23.00	[57]
Sr2Al2SiO7	1 525	7.20	33 000	-37.00	[35]
LiYbSiO4	1 140	7.30	25 257	4.50～8.00	[58]
Ba5Si8O21	1 200	7.30	16 700	25.00	[50]
Mn2P2O7	1 100	7.34	23 847	-95.80	[57]
CaMnSi2O6	1 220	7.39	34 100	-25.60	[59]
CaMgSi2O6	1 290	7.46	59 640	-46.00	[43]
KBaPO4	1 150	7.58	31 577	-13.30	[60]
BaZn2P2O8	1 000	7.72	17 000	-41.10	[61]
Ca3Si2O7	1 300	7.80	28 400	—	[62]
Nd2SiO5	1 500	7.94	38 800	-53.00	[35]
YPO4	1 600	8.00	67 933	-35.30	[63]

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