Article(id=1304921526617273113, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1304921526004904728, articleNumber=null, orderNo=null, doi=10.16790/j.cnki.1009-9239.im.2026.03.001, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1756656000000, receivedDateStr=2025-09-01, revisedDate=1761667200000, revisedDateStr=2025-10-29, acceptedDate=null, acceptedDateStr=null, onlineDate=1789047136215, onlineDateStr=2026-09-10, pubDate=1773936000000, pubDateStr=2026-03-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1789047136215, onlineIssueDateStr=2026-09-10, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1789047136215, creator=13701087609, updateTime=1789047136215, updator=13701087609, issue=Issue{id=1304921526004904728, tenantId=1146029695717560320, journalId=1149653034449285133, year='2026', volume='59', issue='3', pageStart='1', pageEnd='154', issueExtLink='null', onlineDate='null', pubDate='1773936000000', pubDateStr='2026-03-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1789047136068, creator='13701087609', updateTime=1789118116024, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1305219237560217894, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1304921526004904728, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1305219237560217895, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1304921526004904728, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1, endPage=8, ext={EN=ArticleExt(id=1304921526856348443, articleId=1304921526617273113, tenantId=1146029695717560320, journalId=1149653034449285133, language=EN, title=Design and properties of bio-based epoxy resin constructed via Schiff base dynamic covalent bonds, columnId=1304921526780850970, journalTitle=Insulating Materials, columnName=Special Issue on Low-carbon Environmental Protection Advanced Insulation Materials, runingTitle=null, highlight=null, articleAbstract=

Under the "dual carbon" goals, traditional epoxy resins, which are depend on petrochemical feedstocks and are non-recyclable, have severely hindered the current transformation of power systems. Developing low-carbon and environmental friendly epoxy resins has become a research focus. This study adopted a “rigidity-flexibility” balancing strategy to prepare a bio-based epoxy resin with Schiff base dynamic covalent bonds cured directly by an aldehyde-terminated bio-based epoxy crosslinker and a diamine. Its mechanical properties, insulation performance, and property changes before and after multiple recycling processes were investigated. The results show that the novel epoxy resin achieves a tensile strength of 70.1 MPa and an electric strength of 130 kV/mm. This dynamically cross-linked epoxy resin can be effectively reprocessed and recycled via solvent, retaining a tensile strength of 58.8 MPa and an electric strength of 111 kV/mm after multiple reprocessing cycles.

, authors=Yang ZHANG¹, Wenye ZHANG¹, Weijie ZHOU¹, Baoquan WAN², Junwen REN³, Junwei ZHA^{1, 4, *}, authorsList=Yang ZHANG, Wenye ZHANG, Weijie ZHOU, Baoquan WAN, Junwen REN, Junwei ZHA, authorCompany=null, correspAuthors=Junwei ZHA, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1304921529599423281, articleId=1304921526617273113, tenantId=1146029695717560320, journalId=1149653034449285133, language=CN, title=基于希夫碱动态共价键的生物基环氧树脂设计及性能研究, columnId=1304921527053480732, journalTitle=绝缘材料, columnName=低碳环保先进绝缘材料专题, runingTitle=null, highlight=null, articleAbstract=

“双碳”目标下，依赖于石油化工原料且不可回收的传统环氧树脂严重阻碍了当前电力系统转型，发展低碳环保型环氧树脂已成为当前研究的热点。本文采用刚柔并济的策略制备了一种由醛基封端的生物基环氧交联剂与二胺直接固化的含希夫碱动态共价键生物基环氧树脂，并研究其力学性能、绝缘性能和多次回收再利用前后的性能变化。结果表明：新型环氧树脂的拉伸强度可达70.1 MPa，电气强度可达130 kV/mm。该动态交联环氧树脂可以有效实现再加工与溶剂回收，多次再加工后仍然保持58.8 MPa的拉伸强度和111 kV/mm的电气强度。

, authors=张阳¹, 张文业¹, 周伟杰¹, 万宝全², 任俊文³, 查俊伟^{1, 4, *}, authorsList=张阳, 张文业, 周伟杰, 万宝全, 任俊文, 查俊伟, authorCompany=null, correspAuthors=查俊伟, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=adXJnFxYoAFJoDMt7C+flA==, magXml=9bv3BFPKA8KjwZ/3CgYfog==, pdfUrl=null, pdf=QU6wtIHBNCZG99vZxFEQKA==, pdfFileSize=4792457, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=ZHSIWcKpYvRr2BKg+nxXBg==, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=y79s5gH7MUuV4ee7eyGabw==, mapNumber=null, fund=null)}, authors=[Author(id=1304921530182431551, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921526617273113, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1304921530257929025, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921526617273113, authorId=1304921530182431551, language=EN, stringName=Yang ZHANG, firstName=Yang, middleName=null, lastName=ZHANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=¹, address=¹School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1304921530325037890, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921526617273113, authorId=1304921530182431551, language=CN, stringName=张阳, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=¹, address=¹北京科技大学 化学与生物工程学院，北京　100083, bio={"content":"

张阳（1999-），男（汉族），陕西安康人，博士生，主要从事电工绝缘环氧树脂的研究

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张阳（1999-），男（汉族），陕西安康人，博士生，主要从事电工绝缘环氧树脂的研究

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caption=Electric strength of DDCM/GTE-Vans epoxy resin before and after reprocessing, figureFileSmall=JgXM/NtVWUtGK4JkKpxItw==, figureFileBig=gL7UL0wcTRgLA2oHmySx4A==, tableContent=null), ArticleFig(id=1304921535467254648, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921526617273113, language=CN, label=图9, caption=DDCM/GTE-Vans环氧树脂再加工前后的电气强度, figureFileSmall=JgXM/NtVWUtGK4JkKpxItw==, figureFileBig=gL7UL0wcTRgLA2oHmySx4A==, tableContent=null), ArticleFig(id=1304921535525974905, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921526617273113, language=EN, label=Fig.10, caption=Solvent recovery tests of DDCM/E-51 and DDCM/GTE-Vans epoxy resins, figureFileSmall=qOBSbqyp05iNAom37EfDqg==, figureFileBig=hbo9bFJEGZmtq2A0qEGv2Q==, tableContent=null), ArticleFig(id=1304921535588889466, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921526617273113, language=CN, label=图10, caption=DDCM/E-51与DDCM/GTE-Vans环氧树脂的溶剂回收试验, figureFileSmall=qOBSbqyp05iNAom37EfDqg==, figureFileBig=hbo9bFJEGZmtq2A0qEGv2Q==, tableContent=null), ArticleFig(id=1304921535668581243, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921526617273113, language=EN, label=Table 1, caption=

Properties comparison of DDCM/E-51 and DDCM/GTE-Vans epoxy resins

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样品	拉伸强度/MPa	断裂伸长率/%	介质损耗因数(103 Hz)	再加工性	溶剂回收
DDCM/GTE-Vans	70.1±1.2	6.9±0.6	0.018±0.002	√	√
DDCM/E-51	68.2±0.7	5.5±0.7	0.006±0.002	×	×

), ArticleFig(id=1304921535739884412, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1304921526617273113, language=CN, label=表1, caption=

DDCM/E-51与DDCM/GTE-Vans环氧树脂性能对比

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样品	拉伸强度/MPa	断裂伸长率/%	介质损耗因数(103 Hz)	再加工性	溶剂回收
DDCM/GTE-Vans	70.1±1.2	6.9±0.6	0.018±0.002	√	√
DDCM/E-51	68.2±0.7	5.5±0.7	0.006±0.002	×	×

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