Article(id=1193556933585105862, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1193556932167431095, articleNumber=null, orderNo=null, doi=10.16790/j.cnki.1009-9239.im.2025.04.014, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=research-article, receivedDate=1713888000000, receivedDateStr=2024-04-24, revisedDate=1715702400000, revisedDateStr=2024-05-15, acceptedDate=null, acceptedDateStr=null, onlineDate=1762495748182, onlineDateStr=2025-11-07, pubDate=1745078400000, pubDateStr=2025-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1762495748182, onlineIssueDateStr=2025-11-07, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1762495748182, creator=13701087609, updateTime=1762495748182, updator=13701087609, issue=Issue{id=1193556932167431095, tenantId=1146029695717560320, journalId=1149653034449285133, year='2025', volume='58', issue='4', pageStart='1', pageEnd='144', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1762495747843, creator=13701087609, updateTime=1762498255746, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1193567451108573868, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1193556932167431095, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1193567451112768173, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1193556932167431095, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=109, endPage=116, ext={EN=ArticleExt(id=1193556933853541319, articleId=1193556933585105862, tenantId=1146029695717560320, journalId=1149653034449285133, language=EN, title=Evaluation method for buffer layer ablation of high voltage cable based on gas stoichiometric characteristics, columnId=1192878364340924664, journalTitle=Insulating Materials, columnName=Test and Analysis, runingTitle=null, highlight=null, articleAbstract=
The ablation of the buffer layer of high-voltage cables is accompanied by the release of characteristic gas, so the characteristic gas can be used as an indicator for the detection and evaluation of ablation faults. However, the correlation between the type and concentration of released gas and the degree of ablation is still unclear. In this paper, a buffer layer ablation simulation experiment platform was established. After comprehensive consideration, C2H6, C2H4, C2H2, and CO were selected as the characteristic gases for buffer layer ablation evaluation, and the change law of their stoichiometric characteristics with buffer layer ablation degree and moisture content were analyzed. The results show that the average molar mass of characteristic gas decreases with the increase of moisture content in buffer layer, and the ratio of C to H atoms in characteristic gases under humid conditions is higher than that under dry conditions. The concentrations of C and H atoms continuously increase with the burning time, and with the increase of burning time, the concentrations of C and H atoms first decrease, then increase and then decreases, and finally monotonically increase with the increase of moisture degree. Analysis suggests that the differences of damage to the buffer layer structure under different conditions are the reasons for the change in the stoichiometric characteristics of the released gas.
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高压电缆缓冲层烧蚀伴随有特征气体逸出现象,故特征气体有望作为烧蚀故障检测评估指标,但目前逸出气体的种类和浓度与烧蚀程度的关联性仍不明确。本文搭建缓冲层烧蚀模拟实验平台,综合考虑后选择C2H6、C2H4、C2H2以及CO作为缓冲层烧蚀评估的特征气体,并分析其化学计量特征随缓冲层烧蚀程度和受潮程度的变化规律。结果表明:特征气体的平均摩尔质量随缓冲层含水率提高而降低,潮湿条件下的烃类特征气体中C与H原子数量之比高于干燥条件;C原子与H原子的浓度随烧蚀时间的增加而不断提高。且随着烧蚀时间的增加,C原子与H原子的浓度随潮湿程度的增大先减小,再增大再减小,最后单调增大。分析认为,不同条件下缓冲层材料结构烧蚀破坏的差异是导致逸出气体化学计量特征变化的原因。
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赵鸽(2002-),女(汉族),河南洛阳人,硕士生,主要从事高压电缆缓冲层烧蚀的检测与修复相关研究工作。
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任志刚(1983-),男(汉族),内蒙古赤峰人,高级工程师,主要从事高电压与绝缘技术、高压电缆的研究。
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任志刚(1983-),男(汉族),内蒙古赤峰人,高级工程师,主要从事高电压与绝缘技术、高压电缆的研究。
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2 西安交通大学 电工材料电气绝缘全国重点实验室,陕西 西安 710049)])], figs=[ArticleFig(id=1195072178862432529, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=EN, label=Fig.1, caption=
Schematic diagram of ablation simulation experimental platform, figureFileSmall=sY1PebRUcvvq64dV5j/eUg==, figureFileBig=s0hgf3z6qCAIvCEl/sVRzg==, tableContent=null), ArticleFig(id=1195072178929541394, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=CN, label=图1, caption=
模拟烧蚀实验平台示意图, figureFileSmall=sY1PebRUcvvq64dV5j/eUg==, figureFileBig=s0hgf3z6qCAIvCEl/sVRzg==, tableContent=null), ArticleFig(id=1195072179013427475, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=EN, label=Fig.2, caption=
Infrared spectrum results of ablative characteristic gas, figureFileSmall=IfSmJz/gKtBhe3iHwB1FiA==, figureFileBig=cbMo7SK96HxdBxPEJPYGww==, tableContent=null), ArticleFig(id=1195072179088924948, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=CN, label=图2, caption=
烧蚀特征气体的红外光谱检测结果, figureFileSmall=IfSmJz/gKtBhe3iHwB1FiA==, figureFileBig=cbMo7SK96HxdBxPEJPYGww==, tableContent=null), ArticleFig(id=1195072179147645205, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=EN, label=Fig.3, caption=
The change of the average molar mass M G of ablative characteristic gas and its decreasing rate with ablative time, figureFileSmall=9FDI38rnZK/afwPTkruE3g==, figureFileBig=ReyD2hgjBBKcPOeSTa2xRw==, tableContent=null), ArticleFig(id=1195072179206365462, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=CN, label=图3, caption=
烧蚀特征气体平均摩尔质量M G及其减小率随烧蚀时间的变化 (注:“减小率”指含水率为20%时相比干燥情况MG的减小率。)
, figureFileSmall=9FDI38rnZK/afwPTkruE3g==, figureFileBig=ReyD2hgjBBKcPOeSTa2xRw==, tableContent=null), ArticleFig(id=1195072179315417367, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=EN, label=Fig.4, caption=
The changes of hydrocarbon gas R C/H and its growth rate with ablation time, figureFileSmall=sCbDCliLhkKXlgZ8502Wjg==, figureFileBig=wl4X9upQohA5wUSdC+xIgA==, tableContent=null), ArticleFig(id=1195072179453829400, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=CN, label=图4, caption=
烃类气体R C/H及其增长率随烧蚀时间的变化 (注:“增长率”指含水率为20%时相比干燥情况RC/H的增长率。)
, figureFileSmall=sCbDCliLhkKXlgZ8502Wjg==, figureFileBig=wl4X9upQohA5wUSdC+xIgA==, tableContent=null), ArticleFig(id=1195072179520938265, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=EN, label=Fig.5, caption=
The changes of concentration of C and H atoms in the characteristic gas with ablation time, figureFileSmall=QPZR3cWjQe7KB5OaIcoxdw==, figureFileBig=H8vZjqYQZxvwGI8d/tKynQ==, tableContent=null), ArticleFig(id=1195072179588047130, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=CN, label=图5, caption=
特征气体中C原子与H原子浓度随烧蚀时间的变化, figureFileSmall=QPZR3cWjQe7KB5OaIcoxdw==, figureFileBig=H8vZjqYQZxvwGI8d/tKynQ==, tableContent=null), ArticleFig(id=1195072179646767387, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=EN, label=Fig.6, caption=
The white substance formed on the surface of the buffer layer, figureFileSmall=80RbSr6X8BGOliOeZP1TLw==, figureFileBig=pEL1ZNQik3WzhWKfeM2Z/A==, tableContent=null), ArticleFig(id=1195072179743236380, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=CN, label=图6, caption=
缓冲层表面生成的白色物质, figureFileSmall=80RbSr6X8BGOliOeZP1TLw==, figureFileBig=pEL1ZNQik3WzhWKfeM2Z/A==, tableContent=null), ArticleFig(id=1195072179843899677, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=EN, label=Fig.7, caption=
The change of voltage at both ends of the sample in simulated ablation experiment, figureFileSmall=/v2xcKx/PmhYTFbosTQgWA==, figureFileBig=zSqCcjqpQgLkj6Fsx0d0lQ==, tableContent=null), ArticleFig(id=1195072180003283230, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=CN, label=图7, caption=
模拟烧蚀实验中试样两端电压的变化, figureFileSmall=/v2xcKx/PmhYTFbosTQgWA==, figureFileBig=zSqCcjqpQgLkj6Fsx0d0lQ==, tableContent=null), ArticleFig(id=1195072180082975007, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=EN, label=Fig.8, caption=
Thermogravimetric analysis curves of PET and water-blocking powder, figureFileSmall=Nr7XnhzlMYkK+Gv3oFqvqA==, figureFileBig=2uitE5kNSavBHOilGVjQWA==, tableContent=null), ArticleFig(id=1195072180204609824, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=CN, label=图8, caption=
PET和聚丙烯酸钠的热重分析曲线, figureFileSmall=Nr7XnhzlMYkK+Gv3oFqvqA==, figureFileBig=2uitE5kNSavBHOilGVjQWA==, tableContent=null), ArticleFig(id=1195072180267524385, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=EN, label=Table 1, caption=
Molar mass of the ablative characteristic gas, figureFileSmall=null, figureFileBig=null, tableContent=
| 特征气体 | 摩尔质量/(g/mol) | 特征气体 | 摩尔质量/(g/mol) |
| C2H6 | 30.069 0 | C2H4 | 28.053 2 |
| C2H2 | 26.037 3 | CO | 28.010 1 |
), ArticleFig(id=1195072180363993378, tenantId=1146029695717560320, journalId=1149653034449285133, articleId=1193556933585105862, language=CN, label=表1, caption=
烧蚀特征气体的摩尔质量
, figureFileSmall=null, figureFileBig=null, tableContent=
| 特征气体 | 摩尔质量/(g/mol) | 特征气体 | 摩尔质量/(g/mol) |
| C2H6 | 30.069 0 | C2H4 | 28.053 2 |
| C2H2 | 26.037 3 | CO | 28.010 1 |
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