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Article(id=1210613546996593065, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1210613541111984320, articleNumber=null, orderNo=null, doi=10.16790/j.cnki.1009-9239.im.2024.11.007, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=research-article, receivedDate=1718208000000, receivedDateStr=2024-06-13, revisedDate=1722528000000, revisedDateStr=2024-08-02, acceptedDate=null, acceptedDateStr=null, onlineDate=1766562361716, onlineDateStr=2025-12-24, pubDate=1732032000000, pubDateStr=2024-11-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1766562361716, onlineIssueDateStr=2025-12-24, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1766562361716, creator=13701087609, updateTime=1766562361716, updator=13701087609, issue=Issue{id=1210613541111984320, tenantId=1146029695717560320, journalId=1149653034449285133, year='2024', volume='57', issue='11', pageStart='1', pageEnd='143', issueExtLink='null', onlineDate='null', pubDate='null', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1766562360313, creator=13701087609, updateTime=1766564044072, updator=13701087609, preIssue=null, nextIssue=null, ext={EN=IssueExt(id=1210620603392987671, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1210613541111984320, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1210620603392987672, tenantId=1146029695717560320, journalId=1149653034449285133, issueId=1210613541111984320, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null}, startPage=65, endPage=72, ext={EN=ArticleExt(id=1210613547323748796, articleId=1210613546996593065, tenantId=1146029695717560320, journalId=1149653034449285133, language=EN, title=High thermal conductive composite insulating paper prepared by boron nitride nanotubes and aramid nanofibers, columnId=1210613542542241998, journalTitle=Insulating Materials, columnName=Special Issue on Key Materials and Technology for New Energy Vehicles, runingTitle=null, highlight=null, articleAbstract=

With the development of modern electrical equipment toward miniaturization, high-degree integration, and multi-functionalization, a large amount of heat accumulation will lead to insulation failure of electrical equipment. In order to develop a composite that can achieve high thermal conductivity even with low filler content (mass fraction<50%) and meet the strict requirement of current electrical equipment for heat dissipation, a composite insulating paper composed of aramid nanofibers and hydroxylated boron nitride nanotubes （BNNT-OH） was synthesized in this paper, and the effects of BNNT-OH content on the properties of composite insulating paper were studied. The results show that when the mass fraction of boron nitride nanotubes is 20%, the thermal conductivity of composite insulating paper is as high as 15.92 W/(m·K). The excellent thermal conductivity is due to the high intrinsic thermal conductivity of boron nitride nanotubes, and that the strong interaction between hydroxylated boron nitride nanotubes and aramid nanofibers reduces the interfacial thermal resistance.

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随着现代电气设备向小型化、高度集成化和多功能化方向发展，大量的热量积累导致电气设备的绝缘失效。为了开发一种在低含量填料下（质量分数<50%）仍能实现高导热性能的复合材料，满足当前电气设备对散热的严格要求，本文合成了一种由芳纶纳米纤维和羟基化氮化硼纳米管（BNNT-OH）组成的复合绝缘纸，并研究了BNNT-OH含量对复合绝缘纸性能的影响。结果表明：当氮化硼纳米管质量分数为20%时，复合绝缘纸的热导率高达15.92 W/(m·K)。优异的导热性能归因于氮化硼纳米管固有的高热导率，以及羟基化氮化硼纳米管与芳纶纳米纤维之间的强相互作用降低了界面热阻。

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贾申利（1968-），男（汉族），陕西西安人，教授，博士，主要从事电力设备、电弧放电和电气绝缘的研究。
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任俊文（1987-），男（汉族），四川成都人，副研究员，主要从事高电压与绝缘技术的研究。

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任俊文（1987-），男（汉族），四川成都人，副研究员，主要从事高电压与绝缘技术的研究。

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任俊文（1987-），男（汉族），四川成都人，副研究员，主要从事高电压与绝缘技术的研究。

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氮化硼纳米管与芳纶纳米纤维复合制备高导热复合绝缘纸
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任俊文 1 , 卿湫惋喻 1 , 魏佳 1 , 卓然 2 , 滕富莉 1 , 高萌 2 , 卞超 1 , 贾申利 1
绝缘材料 | 新能源汽车用关键材料与技术专题 2024,57(11): 65-72
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绝缘材料 | 新能源汽车用关键材料与技术专题 2024, 57(11): 65-72
氮化硼纳米管与芳纶纳米纤维复合制备高导热复合绝缘纸
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任俊文1, 卿湫惋喻1, 魏佳1, 卓然2, 滕富莉1, 高萌2, 卞超1, 贾申利1
作者信息
  • 1四川大学 电气工程学院，四川 成都 610065
  • 2南方电网科学研究院有限责任公司，广东 广州 510623

    • 任俊文（1987-），男（汉族），四川成都人，副研究员，主要从事高电压与绝缘技术的研究。

通讯作者:

贾申利（1968-），男（汉族），陕西西安人，教授，博士，主要从事电力设备、电弧放电和电气绝缘的研究。
High thermal conductive composite insulating paper prepared by boron nitride nanotubes and aramid nanofibers
Junwen REN1, Qiuwanyu QING1, Jia WEI1, Ran ZHUO2, Fuli TENG1, Meng GAO2, Chao BIAN1, Shenli JIA1
Affiliations
  • 1College of Electrical Engineering, Sichuan University, Chengdu 610065, China
  • 2Electric Power Research Institute of CSG, Guangzhou 510623, China
出版时间: 2024-11-20 doi: 10.16790/j.cnki.1009-9239.im.2024.11.007
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摘要
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随着现代电气设备向小型化、高度集成化和多功能化方向发展，大量的热量积累导致电气设备的绝缘失效。为了开发一种在低含量填料下（质量分数<50%）仍能实现高导热性能的复合材料，满足当前电气设备对散热的严格要求，本文合成了一种由芳纶纳米纤维和羟基化氮化硼纳米管（BNNT-OH）组成的复合绝缘纸，并研究了BNNT-OH含量对复合绝缘纸性能的影响。结果表明：当氮化硼纳米管质量分数为20%时，复合绝缘纸的热导率高达15.92 W/(m·K)。优异的导热性能归因于氮化硼纳米管固有的高热导率，以及羟基化氮化硼纳米管与芳纶纳米纤维之间的强相互作用降低了界面热阻。

氮化硼纳米管  /  芳纶纳米纤维  /  绝缘纸  /  热导率  /  界面热阻

With the development of modern electrical equipment toward miniaturization, high-degree integration, and multi-functionalization, a large amount of heat accumulation will lead to insulation failure of electrical equipment. In order to develop a composite that can achieve high thermal conductivity even with low filler content (mass fraction<50%) and meet the strict requirement of current electrical equipment for heat dissipation, a composite insulating paper composed of aramid nanofibers and hydroxylated boron nitride nanotubes （BNNT-OH） was synthesized in this paper, and the effects of BNNT-OH content on the properties of composite insulating paper were studied. The results show that when the mass fraction of boron nitride nanotubes is 20%, the thermal conductivity of composite insulating paper is as high as 15.92 W/(m·K). The excellent thermal conductivity is due to the high intrinsic thermal conductivity of boron nitride nanotubes, and that the strong interaction between hydroxylated boron nitride nanotubes and aramid nanofibers reduces the interfacial thermal resistance.

boron nitride nanotubes  /  aramid nanofibers  /  insulating paper  /  thermal conductivity  /  interfacial thermal resistance
任俊文, 卿湫惋喻, 魏佳, 卓然, 滕富莉, 高萌, 卞超, 贾申利. 氮化硼纳米管与芳纶纳米纤维复合制备高导热复合绝缘纸. 绝缘材料, 2024 , 57 (11) : 65 -72 . DOI: 10.16790/j.cnki.1009-9239.im.2024.11.007
Junwen REN, Qiuwanyu QING, Jia WEI, Ran ZHUO, Fuli TENG, Meng GAO, Chao BIAN, Shenli JIA. High thermal conductive composite insulating paper prepared by boron nitride nanotubes and aramid nanofibers[J]. Insulating Materials, 2024 , 57 (11) : 65 -72 . DOI: 10.16790/j.cnki.1009-9239.im.2024.11.007
正文
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0 引言
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随着现代电气设备朝着高电压、高功率和小型化发展，热量的积累可能导致设备的热失效[1]。因此，热管理对电气设备的稳定运行变得至关重要[2]。聚合物基电介质材料已被证明是解决热量积累问题的有效热管理材料[3]。由于聚合物的热导率较低（0.1～0.5 W/(m·K)），通常将聚合物与具有高热导率的纳米颗粒复合来提高其导热性能。
近年来，陶瓷填料凭借其高导热、电绝缘和热稳定等特性，在聚合物基复合电介质领域被广泛 应用[3-6]。然而，这些复合电介质材料需要高负载 填料（质量分数＞50%），并且热导率仅为1～10 W/(m·K)[3-4]。此外，填料超载也会导致复合电介质材料的力学性能发生劣化。因此，在实现复合电介质材料高导热性能的同时最小化填料的添加量仍然是一个艰巨的挑战[7]。有研究表明，具有高散射比的填料，如一维纳米填料（纳米纤维[8]、纳米线[9-10]和纳米管[11]），有望克服这一挑战。因此，金属纳米线和碳纳米管（CNT）[12]常被用于制备高导热复合电介质材料。但是，金属纳米线和CNT的加入会导致复合电介质材料的电导率增大，从而限制这类复合电介质材料在电气绝缘领域的应用。
氮化硼纳米管（BNNT）是一种与CNT结构相似的一维高导热纳米材料，具有优异的电绝缘性能。BNNT凭借其高导热性、高热稳定性和高弹性模量[13-15]，在导热复合电介质材料中得到广泛应用。ZHI C Y[16-17]等制备了具有高热导率的聚合物/BNNT复合材料，然而该复合材料的热导率低于5 W/(m·K)，这是由于BNNT和聚合物之间的相互作用差，产生了高界面热阻[18-19]。尽管对BNNT进行表面功能化可改善其与基体间的相互作用，但往往伴随着BNNT晶体结构的退化[20]。XU Y S等[21]研究表明，对氮化硼（BN）进行表面处理能够增加环氧/BN复合材料的导热性能，然而只有填料含量较高时，复合材料的各项性能才显著提升。如何在不破坏BNNT晶体结构的前提下，添加低含量的填料来改善BNNT与聚合物的相互作用，获得更高的导热性能，仍然是一个具有挑战性的问题。
本研究通过水热反应接枝羟基修饰BNNT（BNNT-OH），从而在不破坏BNNT晶体结构的情况下加强其与聚合物基体间的相互作用，选用具有出色耐高温、绝缘性能和力学性能的芳纶纳米纤维（ANF）为基体，然后通过真空辅助抽滤制备ANF/BNNT-OH复合绝缘纸，研究BNNT-OH的添加量对复合绝缘纸性能的影响。
1 实验
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1.1 主要原材料
凯夫拉纤维（AF，黄色，400D，东莞市索维特特殊线带有限公司）、二甲基亚砜（DMSO，纯度≥99.55%，成都市科龙化工试剂厂）、丙酮（纯度≥99.8%，成都市科龙化工试剂厂）、氢氧化钾（KOH，纯度为95%，上海阿拉丁试剂有限公司）、氮化硼纳米管（BNNT，纯度>85%，密度为1.38 g/cm3，直径为30～50 nm，长度>10 μm，南京先锋纳米材料科技有限公司）。
1.2 ANF/BNNT-OH复合绝缘纸的制备
1.2.1 ANF的制备
本研究采用去质子化法制备ANF，具体步骤如下：
（1）将凯夫拉纤维剪成长度为0.5 cm左右的短纤维，然后浸泡在丙酮中辅以超声清洗，除去凯夫拉纤维表面杂质，同时疏松纤维结构。
（2）将超声处理后的凯夫拉纤维利用布氏漏斗滤出，置于60℃真空烘箱中干燥48 h。
（3）将1.6 g干燥的凯夫拉纤维和2.4 g KOH加入到500 mL的DMSO中。然后，将混合物在30℃、800 r/min的条件下避光磁力搅拌1周，得到透明的暗红色ANF/DMSO分散液。
1.2.2 羟基化BNNT（BNNT-OH）的制备
BNNT-OH采用水热反应法制备。首先，将1 g BNNT分散在100 mL的H2O中，在180℃下进行水热反应6 h，使BNNT表面成功附着羟基。然后，将得到的BNNT-OH水溶液过滤，并置于60℃真空烘箱中干燥48 h，最终收集BNNT-OH粉末，以备后续实验使用。
1.2.3 ANF/BNNT-OH复合绝缘纸的制备
（1）取25 mg的BNNT-OH粉末置于50 g的DMSO溶液中以500 W的功率超声分散20 min，加入用DMSO稀释3倍且部分质子化后的ANF/DMSO溶液，再超声10 min，以800 r/min的转速充分搅拌，得到均匀分散的ANF/BNNT-OH/DMSO溶液。
（2）将ANF/BNNT-OH/DMSO溶液快速注入500 mL的H2O中，得到ANF/BNNT-OH絮凝物，采用布氏漏斗反复过滤以除去金属离子和DMSO溶剂。
（3）将ANF/BNNT-OH絮凝物分散在400 mL H2O中以12 000 r/min的转速进行乳化剪切，获得分散稳定的ANF/BNNT-OH浆液，然后用PTFE膜（直径为50 mm，孔径为0.22 μm）真空抽滤8 h，再在15 MPa/100℃条件下压制5 min，得到柔性ANF/BNNT-OH复合绝缘纸。调整BNNT-OH的含量，制备出质量分数分别为0、5%、10%、15%、20%的ANF/BNNT复合绝缘纸。
1.3 表征与性能测试
采用日本电子株式会社生产的JEM2100F型透射电镜（TEM）和美国FEI公司生产的Quanta 250 FEG型扫描电镜（SEM）对ANF、BNNT和ANF/BNNT-OH复合绝缘纸的微观结构和形貌进行表征；采用香港岛津-KRATOS公司生产的Kratos AXIS Ultra DLD型X射线光电子能谱仪（XPS）表征改性前后BNNT的X射线光电子能谱；采用美国Thermo Fisher公司生产的Nicolet is50型傅里叶红外光谱仪（FT-IR）分析ANF与BNNT-OH之间的界面相互作用，测试波数为400～4 000 cm-1；采用德国耐驰公司生产的LFA 467型导热系数测试仪测定复合绝缘纸在室温下（25℃）的热扩散系数；采用美国TA公司生产的Q2000型差示扫描量热仪进行DSC 测试，氮气气氛，流速为20 mL/min，升温速率为10℃/min，测试温度为30～400℃；采用美国Instron公司生产的Instron 5967型万能材料试验机对复合绝缘纸进行室温力学性能测试；采用北京科朗测量仪器有限公司生产的DDJ-50 kV型电击穿测试仪在直流高压下测试复合绝缘纸的电击穿性能，升压速率为500 V/s。
2 结果与讨论
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2.1 微观结构
图1为AF和ANF的微观形貌图。从图1可以看出，AF单根纤维直径大于10 μm，且表面光滑无破损；ANF整体粗细均匀，长度为微米级，径向尺寸约为30 nm，表现出较高的长径比，表明本实验成功制备了结构完整的ANF。
图2为BNNT和BNNT-OH的微观形貌图。从图2可以看出，BNNT长度为5～10 μm，直径为30～50 nm，具有高长径比，并含有少量杂质；经高温高压水热反应和过滤处理后BNNT-OH仍然保持着完整的管状结构，且表面杂质明显减少。
图3为BNNT和BNNT-OH的XPS扫描光谱。从图3可以看到，BNNT和BNNT-OH在190 eV和398 eV均出现B1s和N1s两个强烈的特征峰。BNNT-OH的氧原子分数强度从1.69%提高到2.56%，表明BNNT成功接枝羟基[22-23]。这为界面氢键的形成提供了反应位点，为BNNT-OH与ANF之间强界面相互作用奠定了基础。
图4为ANF/BNNT-OH-20%复合绝缘纸的断面和平面SEM图像。从图4(a)可以看出，BNNT-OH沿平面方向排列，复合绝缘纸显示出有序的层状结构，这种有序结构是由真空辅助过滤过程以及一维BNNT-OH的剪切力作用形成的。从图4(b)可以看出，BNNT-OH均匀分散在ANF中，表明BNNT-OH具有较强的力学性能，这是由于BNNT-OH的高机械强度和BNNT-OH与ANF之间的强界面相互作用所决定的[24]。在质量分数为20%时，BNNT-OH与ANF紧密搭接，并填补了部分原始芳纶骨架中的孔隙，使声子通路得到了明显改善。
2.2 热学性能
将ANF/BNNT-OH复合绝缘纸与纯ANF纸和ANF/BNNT复合绝缘纸的热导率进行对比，结果如图5所示。从图5可以看出，纯ANF纸的热导率为1.98 W/(m·K)。当分别添加质量分数为5%的未功能化BNNT和BNNT-OH时，其复合绝缘纸的热导率分别为2.45 W/(m·K)和4.68 W/(m·K)，表明羟基化BNNT对复合绝缘纸的导热性能提升较为明显。
随着BNNT-OH含量的增加，复合绝缘纸的热导率不断增大。当BNNT-OH质量分数为5%时，复合绝缘纸的热导率相较于纯ANF纸提升了136.36%，可见少量的BNNT-OH就能实现对ANF绝缘纸导热性能的优化。图6为ANF/BNNT-OH-5%复合绝缘纸的平面SEM图像，从图中可以看出此时BNNT-OH数量非常有限，在ANF中各自独立存在，彼此之间不重叠，因此难以搭接出连贯的导热通路，对复合绝缘纸的导热性能贡献有限。
随着BNNT-OH含量的不断增加，ANF/BNNT-OH复合绝缘纸的热导率持续增大。当BNNT-OH质量分数为20%时，复合绝缘纸的热导率达到了15.92 W/(m·K)，相较于纯ANF纸的热导率提高了704.04%。一方面，BNNT自身具有相当高的热导率，其热导率可达到350 W/(m·K)；另一方面，BNNT经过羟基化改性后，与ANF之间形成了强烈的界面相互作用，降低了界面热阻效应，促使热流在复合绝缘纸内部可以连续输运，这一结果与ZENG X等[25]和FU C等[26]的研究结果一致。当BNNT-OH质量分数达到20%时，BNNT-OH的数量显著增多，尤其在平面SEM图像（如图3(b)所示）中可以观察到BNNT-OH之间发生重叠。此时BNNT-OH的含量足够使BNNT-OH之间达到真正意义上的接触和相互作用，实现管与管之间首尾相接，在ANF网络中形成多条导热链（如图7所示），大部分热量通过热导率较高的BNNT-OH进行传输，因此ANF/BNNT-OH复合绝缘纸的热导率得到显著提高。
采用DSC测试评估了复合绝缘纸的热稳定性，结果如图8所示。从图8可以看出，纯ANF纸和ANF/BNNT-OH-10%复合绝缘纸在400℃以内均未出现明显的吸收峰，表明所制备复合绝缘纸的玻璃化转变温度超过400℃。DSC结果证实了ANF/BNNT-OH复合绝缘纸优异的热稳定性，这确保了复合绝缘纸能够在高温环境下保持其机械强度和电气性能。
2.3 电气强度
电气设备的绝缘在运行中除受到长期工作电压作用外，还会受到电力系统中可能出现的各种过电压作用。为了分析ANF/BNNT-OH复合绝缘纸耐受高压的能力，对ANF/BNNT-OH复合绝缘纸进行了直流击穿测试。介质的电气强度满足Weibull概率分布，反映介质在一定电场下被击穿的概率。双参数的Weibull分布函数与介质电气强度关系式如式（1）所示。
P(E)=1-exp[-(Eb/E0)β]
式（1）中：Eb是材料的电气强度测试值，kV/mm；E0是尺度参数，即击穿概率为63.2%时的电气强度， kV/mm；β为形状参数，表征实验结果的分散程度。
根据直流击穿实验结果，作出Weibull分布如图9所示。从图9可以看出，相较于纯ANF纸，ANF/BNNT-OH复合绝缘纸的电气强度显著提升。
图10为纯ANF纸和ANF/BNNT-OH复合绝缘纸的特征电气强度。从图10可以看出，纯ANF纸的特征电气强度为212.33 kV/mm，而ANF/BNNT-OH-10%纸的特征电气强度为353.55 kV/mm，相较纯ANF纸提升了66.41%。复合绝缘纸电气强度的提升可以归因于BNNT-OH填补了ANF网络中的孔隙，使复合绝缘纸内部结构更加致密，从而促进了电荷的横向耗散，降低了电荷注入的可能性。此外，BNNT-OH的加入有利于应力在聚合物链上的分布，避免了聚合物链中最弱键的快速断裂，同时为电树传播提供了曲折的路径最终增大了复合绝缘纸的电气强度[27-28]。其余各BNNT-OH含量的复合绝缘纸特征电气强度也均高于300 kV/mm，表明高含量BNNT-OH对复合绝缘纸的结构影响较轻。因此，本文制备的ANF/BNNT-OH复合绝缘纸在紧凑、轻量化电气设备中具有良好的应用前景。
2.4 力学性能
图11为纯ANF纸以及ANF/BNNT-OH复合绝缘纸的力学性能测试结果。从图11可以看出，ANF/BNNT-OH复合绝缘纸表现出高抗张强度和高断裂伸长率。从图11(b)可以看出，纯ANF纸的抗张强度为152.6 MPa，断裂伸长率为8.53%。不同BNNT-OH含量的ANF/BNNT-OH复合绝缘纸的抗张强度均高于纯ANF纸。尤其是当BNNT-OH质量分数为10%时，ANF/BNNT-OH复合绝缘纸展现出优异的力学性能，其抗张强度和断裂伸长率分别达到了219.62 MPa和15.34%，相较于纯ANF绝缘纸分别提高了43.92%和79.84%。
采用FT-IR光谱图对ANF和BNNT-OH之间的界面相互作用进行表征，结果如图12所示。从图12可以看出，纯ANF纸和ANF/BNNT-OH-10%复合绝缘纸呈现出相似的光谱。纯ANF纸在波数为3 312 cm-1和1 641 cm-1处表现出典型的吸收峰，分别对应N-H和C=O键的拉伸振动。而ANF/BNNT-OH-10%复合绝缘纸N-H和C=O键的拉伸振动峰移动到较低的波数，分别为3 310 cm-1和1 639 cm-1。由于氢键的形成会降低N-H和C=O键的振动频率，因此这种明显的红移证实了ANF和BNNT-OH之间形成了强界面氢键相互作用。
由于未经处理的BNNT表面缺乏活性官能团，其难以与聚合物基体产生良好的界面接触与化学键合。通过在BNNT表面接枝羟基，使得BNNT-OH与ANF之间产生了强大的界面氢键相互作用，能够有效将外部载荷从ANF转移到坚固的BNNT-OH上，进而提高复合绝缘纸的力学性能[29]。P NAUITYAL等[15]的研究同样证实在外力拉伸作用下，BNNT的缠结使得裂纹发生偏转和桥接，从而可以有效防止局部应力集中，提高材料的抗失效性。尽管随着BNNT-OH含量的进一步增加，复合绝缘纸的力学性能相较于ANF/BNNT-OH-10%复合绝缘纸出现劣化，但凭借良好的界面氢键作用，抗张强度仍高于190 MPa，杨氏模量仍高于4 800 MPa。
3 结论
收起
（1）通过去质子化法剥离得到的ANF粗细均匀，表现出高长径比。
（2）通过水热反应成功在BNNT边缘接枝羟基，BNNT-OH保持完整的管状结构，且表面杂质明显减少。
（3）ANF/BNNT-OH-20%复合绝缘纸的热导率为15.92 W/(m·K)，相较于纯ANF纸的热导率提高了704.04%。
（4）ANF/BNNT-OH-10%复合绝缘纸的直流电气强度为353.55 kV/mm，相较于纯ANF纸提升了66.41%。
（5）ANF/BNNT-OH复合绝缘纸的力学性能相较于纯ANF纸也有所提升，其中ANF/BNNT-OH-10%复合绝缘纸的抗张强度达到了219.62 MPa，相较纯ANF纸提高了43.92%。
基金
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  • 国家自然科学基金资助项目(52107020)
  • 四川省重点研发项目(2023YFG0236)
  • 电力设备电气绝缘国家重点实验室开放基金资助项目(EIPE23210)
文献
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2024年第57卷第11期
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doi: 10.16790/j.cnki.1009-9239.im.2024.11.007
  • 接收时间：2024-06-13
  • 首发时间：2025-12-24
  • 出版时间：2024-11-20
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  • 收稿日期：2024-06-13
  • 修回日期：2024-08-02
基金
国家自然科学基金资助项目(52107020)
四川省重点研发项目(2023YFG0236)
电力设备电气绝缘国家重点实验室开放基金资助项目(EIPE23210)
作者信息
    1四川大学 电气工程学院，四川 成都 610065
    2南方电网科学研究院有限责任公司，广东 广州 510623

通讯作者:

贾申利（1968-），男（汉族），陕西西安人，教授，博士，主要从事电力设备、电弧放电和电气绝缘的研究。
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2种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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